Cyanine compound and optical recording materials
一种化合物、花青的技术,应用在记录载体材料、光学记录载体、用光学方法记录/重现等方向,能够解决放热大、光学记录介质性能变差等问题
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[0056] [Example 1] Production of Phosphorus Hexafluoride Salt of Compound No.4
[0057] According to the following synthetic route and synthetic steps, the phosphorus hexafluoride salt of compound No.4 was obtained with a yield of 72%.
[0058] synthetic route
[0059]
[0060] (synthetic steps)
[0061] 0.003 mol of (A), 0.06 mol of (D) and 0.0042 mol of (C) shown in the above synthesis scheme were added to a reaction flask and stirred. 0.003 mol of (B) was added thereto, and after stirring at 45°C for 2.5 hours, 0.0045 mol of (E) and 10 g of methanol were added, followed by stirring at 55°C for 1 hour. After standing still for 12 hours, the obtained crystals were filtered, washed with methanol and water, and vacuum-dried at 180° C. for 35 hours.
[0062] The crystals after drying were analyzed, and it was confirmed that the crystals were the phosphorus hexafluoride salt of the target compound No. 4. The analysis results are shown below.
[0063] · Optical properties ...
PUM
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