Optical information recording medium and optical information recording method
A technology of optical information and recording media, applied in the direction of optical recording carrier, temperature recording method, recording carrier material, etc.
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Embodiment 1-1 to 1-15
[0224]
[0225] (manufacturing of substrate)
[0226] An extruded polycarbonate resin substrate was prepared, which had a thickness of 1.1 mm, an outer diameter of 120 mm, and an inner diameter of 15 mm, and had a spiral pregroove (track pitch: 320 nm, groove width: groove upper width 120 nm, groove Depth: 35nm, groove inclination: 65°, swing amplitude: 20nm). Control of dies used in extrusion with laser cutting (351nm).
[0227] (Formation of light reflection layer)
[0228] An APC light reflective layer (Ag: 98.1% by mass, Pd: 0.9% by mass, Cu: 1.0% by mass) was formed on the substrate as vacuum deposition with a thickness of 100 nm by DC sputtering by Unaxis Cube in an Ar atmosphere Floor. The thickness of the light reflection layer is adjusted by controlling the sputtering time.
[0229] (Formation of write-once recording layer)
[0230] Each of the compounds (S-1) to (S-15) shown in Table 1 was added in an amount of 2 g to 100 ml of 2,2,3,3-tetrafluoropropanol and di...
Embodiment 2-1 to 2-10
[0238] Optical discs were prepared in the same manner as in Examples 1-1 to 1-15, except that compounds (S-1') to (S-10') shown in Table 2 were used instead of compound (S-1 ) to (S-15).
Embodiment 1-16 to 1-30
[0246]
[0247] (manufacturing of substrate)
[0248] An extruded polycarbonate resin substrate was prepared having a thickness of 0.6 mm, an outer diameter of 120 mm, an inner diameter of 15 mm, and a spiral pregroove (track pitch: 400 nm, groove width: 170 nm, groove depth: 100 nm , Groove inclination: 65°C, swing amplitude: 20nm). Control of dies used in extrusion with laser cutting (351nm).
[0249] (Formation of write-once recording layer)
[0250] Each of the compounds (S-1) to (S-15) shown in Table 1 was added in an amount of 2 g to 100 ml of 2,2,3,3-tetrafluoropropanol and dissolved therein, Thus, a dye-containing coating solution was prepared. The dye-containing coating solution thus prepared was coated on a substrate using a spin coating technique under the condition of 23° C.-50% RH as the number of rotations was increased from 300 rpm to 4,000 rpm. By allowing the applied coating solution to stand at 23° C. and 50% RH for 1 hour, a write-once recording layer ...
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