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Method for producing high octane rating low olefin gasoline

A technology of petroleum hydrocarbon and agent-to-oil ratio, applied in the field of catalytic conversion, which can solve the problems of large changes in fluidization state, large changes in oil gas velocity and catalyst density, failure to guarantee fluidization state, mass transfer rate and uniform temperature distribution, etc. , to achieve the effects of small changes in oil and gas velocity and catalyst density, reduced olefin content in gasoline, and stable fluidized state

Active Publication Date: 2012-03-07
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0011] The above-mentioned prior art supplements part of the regenerated catalyst during the reaction process of the riser reactor in an effort to improve the catalyst cracking activity at the rear of the traditional riser reactor, but there are still large changes in the oil and gas velocity and catalyst density, and the fluidization state in the reactor is relatively large. Disadvantages of large changes, can not guarantee a relatively stable fluidized state, mass transfer rate and uniform temperature distribution

Method used

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  • Method for producing high octane rating low olefin gasoline
  • Method for producing high octane rating low olefin gasoline
  • Method for producing high octane rating low olefin gasoline

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Embodiment 1

[0045] The reaction system of reactor 1 and reactor 2 used in Example 1 in series, the size of reactor 1 is shown in Table 1, and the size of reactor 2 is shown in Table 2. The reaction process is attached figure 1 Shown: The high-temperature regenerated catalyst from the regenerator contacts the feedstock oil at the bottom of reactor 1 and reacts upwards along the riser reactor, and part of the regenerated catalyst is replenished at the bottom of reactor 2, and the reacted oil gas and catalyst are separated in the settler, separated out The catalyst is stripped by steam and enters the regenerator to burn off the coke carried on it and restore the activity of the catalyst. The regenerated catalyst then enters the bottom of the riser to participate in the reaction. The oil and gas separated in the settler are separated into oil slurry and other oil and gas through the fractionation tower, and the oil slurry is returned to the reactor for re-refining, and the other oil and gas a...

Embodiment 2

[0047] Embodiment 2 adopts the reaction system identical with embodiment 1, and raw material and catalyzer are with embodiment 1, and reaction process is as attached figure 1 Shown, with embodiment 1. Oil products are weighed and analyzed by simulated distillation to calculate the yield of gasoline and diesel. The volume of gas is measured by a gas meter, and the yield is calculated after gas chromatographic analysis. And samples were taken at different positions in the reactor to analyze the composition of the reaction products. The properties of the raw materials used are shown in Table 3, the properties of the catalyst are shown in Table 4, and the operating conditions and product distribution are shown in Table 5.

[0048] As can be seen from Table 5, compared with the comparative example, the dry gas yield decreased by 0.3 percentage points, the liquefied gas yield increased by 1.0 percentage points, the gasoline yield increased by 3.0 percentage points, and the diesel y...

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Abstract

The invention discloses a production method for high-octane low-olefin gasoline. The catalytic cracking catalyst is risen by a pre-lift medium and then is reacted with raw material in a reactor, product and spent catalyst obtained after the reaction are draw from the reactor to be separated, the reaction system comprises at least two reactors, the change range of the density of the catalyst in each reactor is between +-1 and 20 percent, the change range of gas velocity of a non-catalyst hollow tower is between +-1 and 18 percent, any reactor is imported with the semi-generated catalyst or a generated catalyst. With the method provided by the invention, the oil gas speed and the catalyst density in the reactor have small changes, the fluidized state is relatively steady, the mass transfer speed and the temperature are evenly distributed in the reactor, so the method provided by the invention has high heavy raw material catalytic cracking conversion rate, reduces the olefin content of the gasoline, and improves the octane value of the gasoline.

Description

technical field [0001] The present invention relates to a method for catalytic conversion of hydrocarbon oil in the absence of hydrogen, more specifically, a method for catalytic cracking of heavy feedstock to produce gasoline with high octane number and low olefins. Background technique [0002] In the process of fluidized catalytic cracking or fluidized catalytic cracking, the high-temperature regenerated catalyst contacts and reacts with raw oil. The main products are gasoline and diesel, and a part of liquefied gas, dry gas, oil slurry and coke are also produced. The coke is deposited on the spent catalyst and enters the regenerator together with the spent catalyst to be burnt to restore activity, and the regenerated catalyst whose activity has been restored enters the reactor for recycling. [0003] In recent years, environmental protection regulations have stricter requirements on the olefin content and aromatic content of gasoline; at the same time, the requirements o...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10G11/18
Inventor 谢朝钢张久顺龙军张执刚
Owner CHINA PETROLEUM & CHEM CORP
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