Selective insecticides based on anthranilic acid diamides and safeners
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An aminobenzamide and active technology, applied in the direction of chemicals, biocides, biocides, etc. for biological control
Inactive Publication Date: 2013-03-06
BAYER CROPSCIENCE AG
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However, the activity of these mixtures is not always optimal
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[0182] In the definitions above and below, a saturated or unsaturated hydrocarbon group such as an alkyl, alkenyl or alkanediyl group - including in combination with a heteroatom as in an alkoxy group - may each be straight-chain or branched.
[0183] Unless stated otherwise, optionally substituted radicals can be monosubstituted or polysubstituted, where in the case of multiple substitution the substituents can be identical or different.
[0184] C 1 -C 20 The definition of alkyl includes the widest range of alkyl groups defined herein. Specifically, this definition includes methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, sec-butyl, tert-butyl, n-pentyl, 1-methylbutyl, 2-methyl butylbutyl, 3-methylbutyl, 1-ethylpropyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 2,2-dimethylpropyl, and each All isomeric hexyl groups (such as n-hexyl, 1-methylpentyl, 2-methylpentyl, 3-methylpentyl, 4-methylpentyl, 1,2-dimethylbutyl , 1,3-dimethylbutyl, 2,3-dimethylbutyl, 1,1-dimethylbut...
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Abstract
Compositions contain (A) haloalkyl-nicotinic acid derivative(s) (I), phthalic acid diamide derivative(s) (II) or anthranilamide derivative(s) (III) and (B) safener(s) selected from about 60 specific compounds (e.g. cloquintocet-mexyl, isoxadifen-ethyl, fenclorim or mefenpyr-diethyl) and 4 general classes of azole, quinoline, alkanamide or N-(phenylsulfonyl)-benzamide compounds (IVa)-(IVd). Compositions comprise: (1) at least one haloalkyl-nicotinic acid derivative of formula (I), phthalic acid diamide derivative of formula (II) or anthranilamide derivative of formula (III) (optionally in N-oxide or salt form) as active agent (A); and (2) at least one safener (B) selected from e.g. azole derivatives of formula (IV-a), quinoline derivatives of formula (IV-b), alkanamides of formula R 10d>-CO-NR 11d>R 12d> (IV-c) and N-(phenylsulfonyl)-benzamide compounds of formula (IV-d). A a>C(W a>)-NR 2a>R 3a>, C(W a>)-N=SR 9a>R 10a> or Het; R 1a>haloalkyl; R 2a>, R 3a>e.g. U-cycloalkyl (optionally substituted (os) by R 4a> or Q a>), C(X a>)-Y a>; or CH 2-heterocyclyl (os by R 5a>); or NR 2a>R 3a>e.g. heteroaryl os by R 4a>, U' or Q a>; Q a>hydrazono (os); R 4a>e.g. S(O) n-U'; X a>, W a>O or S; Y a>e.g. R 6a> or NR 7a>R 8a>; R 6a>e.g. -U-cycloalkyl (os); R 7a>e.g. U-cycloalkyl (os); R 8a>e.g. aryl (os by R 5a>); R 9a>, R 10a>e.g. C(X a>)-Y a>; or R 9a>R 10a>heterocycle; Het : e.g. heterocycle os by R 4a>, U' or Q a>; X b>e.g. haloalkoxy; R 1b>-R 3b>e.g. M 1b>-Q b>; or R 1b>+R 2b>e.g. complete ring; M 1b>e.g. os alkylene; Q b>e.g. T b>-R 4b>; T b>e.g. S(O) m or N(R 5b>); R 4b>e.g. T-heteroaryl (os); R 5b>e.g. CO-O-T-Ph (os); k : 1-4; m : 0-2; L 1b>, L 3b>e.g. S(O) m-U; L 2b>e.g. M 2b>-R 6b>; or L 1b>+L 3b>e.g. complete ring; M 2b>e.g. S(O) m; R 6b>e.g. heteroaryl (os); A 1c>, A 2c>e.g. S; X c>e.g. CR 10c>; R 1c>e.g. V (os by R 6c> or R 11c>); R 2c>e.g. H; R 3c>e.g. R 11c> or heteroaryl (os by 1-3 W c> or R 12c>)); or R 2c>+R 3c>complete ring M c>; R 4c>e.g. OT' (os); R 5c>, R 8c>e.g. G c>, J c> or S(O) p-Ph (all os by e.g. V (os by e.g. Ph (os by W or R 12c>))); G c>e.g. carbocycle; J c>e.g. heteroaryl (os); R 6c>e.g. C(E c>)-R 19c>, OP(Q c>)(OR 19c>) 2, SO 2L c>R 18c> or L c>SO 2L c>R 19c>; E 1c>e.g. NR 19c>; R 7c>e.g. SO 2T'; R 9c>e.g. halo; R 10c>e.g. T'; R 11>e.g. phenylsulfenyl (os by W c>, S(O) n(R 16c>) 2 or S(O) nNR 13c>SO 2L c>R 14c>); L c>e.g. NR 18c>; R 12c>e.g. B(OR 17c>) 2; Q c>O or S; R 13c>e.g. V (os); R 14c>e.g. Cyc (os by e.g. R 6>); R 15c>U' (os by e.g. SOT' or Ph (os by 1-3 W c> or R 12c>); R 16c>e.g. haloalkyl; or N(R 15c>) 2 or N(R 16c>) 2M c>; R 17c>e.g. T; R 18c>e.g. U'; or NR 13c>R 18c>M c>; R 19c>e.g. U (os) M c>e.g. ring W c>e.g. T; n : 0 or 1; p : 0-2; A 12>group of formula (a)-(c); r, s : 0-5; A 11d>e.g. N; A 2d>e.g. alkanediyl (os); R 8d>e.g. NT 2; R 9d>e.g. NT 2; R 10d>T (os); R 11d>, R 12d>e.g. V (os); or R 11d>+R 12d>e.g. alkanediyl; R 13d>, R 15d>e.g. halo; R 14d>e.g. U (os); X 1d>e.g. T'; X 2d>, X 3d>e.g. H; Q : N(R 17d>)-COR 18d> or CO-NR 19d>R 20d>; t : 0-5; v : 0-4; R 16d>, R 17d>e.g. T; R 18d>e.g. NT 2 (os); R 19d>e.g. U (os); R 20d>e.g. phenyl (os by e.g.T' or OT'); or R 19d>+R 20d>e.g. 3-6C alkanediyl ( os); X 4d>, X 5d>e.g. T'; T : 1-4C alkyl, U : 1-6C alkyl; T' : T or 1-4C haloalkyl; U' : U or 1-6C haloalkyl; V : 2-6C alkenyl or 2-6C alkynyl; Cyc : 3-6C cycloalkyl; and with provisos. Full Definitions are given in Definitions (Full Definitions) Field. An independent claim is included for controlling insects and / or acarina, involving applying the composition to insects and / or acarina and / or their habitat. [Image] [Image] [Image] [Image] - ACTIVITY : Insecticide; acaricide; safener; nematocide. In pre-tests for control of Aphis gosspii aphids on cotton plants, mortality after 2 days was 0% using 120 g / ha N-cyanomethyl-4-trifluoromethyl-nicotinamide (flonicamid) (A'), 0% using 50 g / ha isoxadifen-ethyl (B') and 50% using a combination of 120 g / ha (A') and 50 g / ha (B'). - MECHANISM OF ACTION : None given.
Description
[0001] This application is a divisional application of the No. 200580024810.X invention patent application submitted on July 18, 2005. technical field [0002] The present invention relates to a compound combination (combination) having selective insecticidal and / or acaricidal effects, said combination comprising, first, a halogenated alkyl nicotinic acid derivative, phthalamide or anthranilamide ( anthranililic acid diamide), and, secondly, at least one compound that improves the compatibility of crop plants, and also relates to the use of said combination for the selective control of insects and / or spider mites (spider mite) in various beneficial crop plants )the use of. Background technique [0003] Certain haloalkylnicotinic acid derivatives are known to have insecticidal properties (EP-A 058037, JP-A 7-010841, JP-A 7-025853, JP-A 10-101648, JP-A 10-195072, JP-A A 11-180957, JP-A 2002-205991, JP-A 2003-113179, JP-A 2004-035439, JP-A 2004-083415, WO 98 / 57969, WO 99 / 59993...
Claims
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