Unlock instant, AI-driven research and patent intelligence for your innovation.

Catalyst for purifying exhaust gas

一种排气净化、催化剂的技术,应用在排气净化用催化剂领域,能够解决贵金属浪费、对NOx净化性能不充分等问题,达到净化性能提高、成本的增大抑制的效果

Inactive Publication Date: 2009-07-22
TOYOTA JIDOSHA KK
View PDF3 Cites 1 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, even if the loading density of the noble metal on the upstream side is increased, the purification performance after the temperature of the catalyst rises to the activation temperature range of the noble metal (hereinafter referred to as "after warm-up") is basically not affected, so the noble metal is wasted.
Moreover, there is also a pair of NO after warming up x The problem of insufficient purification performance

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Catalyst for purifying exhaust gas
  • Catalyst for purifying exhaust gas
  • Catalyst for purifying exhaust gas

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0044] figure 1 A schematic cross-sectional view showing the exhaust gas purification catalyst of this embodiment. This exhaust gas purification catalyst includes a cordierite honeycomb substrate 1 (130 mm in length), an upstream coating 2 formed in a range of 65 mm from the upstream end face of the honeycomb substrate 1, and a The downstream-side coating layer 3 is formed in a range of 65 mm from the downstream-side end surface. On the upstream coating layer 2 and the downstream coating layer 3, Pt and Ph are loaded at different loading densities, respectively. A method for producing the exhaust gas purification catalyst will be described below instead of a detailed description of the configuration.

[0045] Use the specified concentration of dinitrodiamine platinum solution to adsorb and load on CeO 2 -ZrO 2 Solid solution powder (by weight, CeO 2 :ZrO 2 =60:40), dried at 120°C and fired at 500°C for 2 hours to prepare Pt / CeO loaded with 1.6% by weight of Pt 2 -ZrO 2...

Embodiment 2~5、 comparative example 1~10

[0054] Using the same CeO as in Example 1 2 -ZrO 2 The same catalyst powder as in Example 1 was prepared except that Pt or Rh was loaded on the solid solution powder, and the loading amount was different. Then, a coating layer was formed on the same honeycomb substrate as in Example 1, and catalysts having different supported amounts and supported distributions of Pt and Rh as shown in Table 1 were prepared. In any case, 1.5 g / L of Pt and 0.4 g / L of Rh were supported on the entire catalyst.

[0055] (conventional example)

[0056] Using the same CeO as in Example 1 2 -ZrO 2 The same catalyst powder as in Example 1 was prepared except that Pt or Rh was loaded on the solid solution powder, and the loading amount was different. Then, a coating layer was formed on the same honeycomb substrate as in Example 1, and as shown in Table 1, 1.5 g / L of Pt was uniformly loaded as a whole, and Pt was uniformly loaded as a whole as shown in Table 1. 0.4g / L Rh catalyst.

Embodiment 6

[0057] (Example 6, Comparative Examples 11-18)

[0058] Using the same CeO as in Example 1 2 -ZrO 2 The same catalyst powder as in Example 1 was prepared except that Pt or Rh was loaded on the solid solution powder, and the loading amount was different. Then, form the upstream side coating layer 2 in the range of 30 mm from the upstream side end surface of the same honeycomb substrate as in Example 1, and form the downstream side coating layer in the remaining 100 mm range, in the same manner as in Example 1 Coatings were formed in such a way that catalysts with different supported amounts and supported distributions of Pt and Rh as shown in Table 2 were prepared. In either case, 1.5 g / L of Pt and 0.4 g / L of Rh were supported on the entire catalyst, respectively.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

In the present invention, it is an assignment to optimize a loading density of noble metal on catalyst. Pt is loaded in such an amount that a loading amount per 1 liter of a support substrate exceeds 0. 75 g on an exhaust-gas upstream side of a coating layer, and a loading density of Rh in the coating layer is made so that it becomes higher on an exhaust-gas downstream side than on the exhaust-gas upstream side. The purifying performance after warming up improves by loading Rh with high density on the exhaust-gas downstream side that is likely to become rich atmosphere.

Description

technical field [0001] The present invention relates to an exhaust gas purification catalyst capable of efficiently purifying harmful components in exhaust gas from an internal combustion engine or the like from a low temperature range to a high temperature range. Background technique [0002] Conventionally, as a catalyst for exhaust purification of automobiles, a catalyst that simultaneously oxidizes CO and HC in the exhaust gas and NO x A three-way catalyst for purification by reduction. As such a three-way catalyst, it is well known to form a coating of a porous oxide such as γ-alumina on a heat-resistant substrate made of, for example, cordierite, and to carry platinum (Pt ), rhodium (Rh) and other precious metals made of three-way catalyst. [0003] This three-way catalyst mainly functions as an oxidation catalyst in a lean atmosphere, and functions as a reduction catalyst in a stoichiometric to rich atmosphere, and can reduce NO by utilizing CO and HC in the exhaust...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): B01J23/63B01D53/94H01J35/04
CPCB01J23/63B01D2255/1021B01J23/464B01D53/9477B01J35/0006B01D53/945B01J37/0248B01J23/42B01D2255/1025Y02T10/22Y02T10/12B01J35/19B01D53/94F01N3/10
Inventor 大和正宪久野央志
Owner TOYOTA JIDOSHA KK