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Preparation method and product of elastic cement gum material of elastic cement gum bumper core

A technology of elastic mastic and buffer, which is applied in the direction of buffer, railway car body parts, transportation and packaging, etc. It can solve the problems of unstable performance, unsatisfactory flexibility and resilience, and low efficiency of elastic mastic materials, and achieve The effect of molecular chain suppleness

Active Publication Date: 2010-05-12
ZHUZHOU TIMES NEW MATERIALS TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there are still some deficiencies in the existing elastic mastic materials. The main reason is that the production process of elastic mastic materials is still not very mature, resulting in low production efficiency and unstable performance of elastic mastic materials, especially the control of viscosity and electrical insulation properties. And the flexibility and resilience are not ideal, so it is necessary to further study and improve this

Method used

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  • Preparation method and product of elastic cement gum material of elastic cement gum bumper core

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Experimental program
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Effect test

Embodiment 1

[0019] A method for manufacturing elastic mastic core body elastic mastic used in elastic mastic buffer, select methyl siloxane and phenyl siloxane to mix together, carry out pre-polymerization modification after adding catalyst, then add neutralizer and end-capping agent to carry out End capping, and finally remove the low molecular substances to make the core resin product.

[0020] The composition and proportioning of core resin of the present invention are as follows (proportioning by weight):

[0021] Cyclomethicone: 80 parts; Cyclic polydiphenylsiloxane: 20 parts;

[0022] Basic catalyst: 0.05 parts; Neutralizer: 1.0 parts;

[0023] Inert blocking agent: 0.20 parts;

[0024] The entire polysiloxane molecule of the core resin exhibits a non-polar structure.

[0025] Described cyclic methyl siloxane is decamethyl cyclopentasiloxane, also can be hexamethyl cyclotrisiloxane, octamethyl cyclotetrasiloxane, tetramethyltetravinyl cyclotetrasiloxane Oxane, tetramethyltetraph...

Embodiment 2

[0032] The principle of embodiment two is the same as that of embodiment one, except that the composition and proportioning of the core resin of the present invention are as follows (proportioning by weight):

[0033] Cyclic methyl phenyl siloxane: 90 parts Cyclic methyl phenyl siloxane: 10 parts

[0034] Basic catalyst: 0.025 parts Neutralizer: 0.5 parts

[0035] Active blocking agent: 0.1 part;

[0036] The entire polysiloxane molecule of the core resin exhibits a non-polar structure.

[0037] Described cyclic methyl phenyl siloxane is octamethyl cyclotetrasiloxane, also can be hexamethyl cyclotrisiloxane, octamethyl cyclotetrasiloxane, tetramethyl tetravinyl ring Tetrasiloxane, tetramethyltetraphenylcyclotetrasiloxane, tetramethylhydrogensiloxane or any mixture of two, purity greater than 99.0%, industrial grade;

[0038] The cyclic methyl phenyl siloxane is hexaphenyl cyclotrisiloxane, it can also be hexaphenyl cyclotrisiloxane, decaphenyl cyclopentasiloxane, tetramethy...

Embodiment 3

[0044] The principle of embodiment three is the same as that of embodiment one, except that the composition and proportioning of the core resin of the present invention are as follows (proportioning by weight):

[0045] Cyclic methyl vinyl siloxane: 95 parts Cyclic polydiphenyl siloxane: 5 parts

[0046] Basic catalyst: 0.005 parts Neutralizer: 0.05 parts

[0047] Active blocking agent: 0.5 part;

[0048] The cyclic methyl vinyl siloxane is hexamethylcyclotrisiloxane;

[0049] The cyclic polydiphenylsiloxane is decaphenylcyclopentasiloxane;

[0050] Described basic catalyst is siloxanol tetramethylammonium;

[0051] Described neutralizing agent is carbon dioxide;

[0052] The active end-capping agent is tetramethyl vinyl disiloxane.

[0053] The preparation process of the core resin of the present invention is as follows: add hexamethylcyclotrisiloxane and decaphenylcyclopentasiloxane into the reaction kettle, start stirring, heat up to 110°C, add tetramethylsiloxanol ba...

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Abstract

The invention discloses a preparation method and a product of an elastic cement gum of an elastic cement gum bumper core. The preparation method comprises the following steps: selecting and mixing methyl siloxane and phenyl siloxane, carrying out pre-polymerizing modification after adding catalyst, adding a neutralizer and a blocking agent again for blocking, and finally removing low-molecular substances to prepare a core resin product. The whole polysiloxane molecule of the core resin is in a non-polar structure. The core resin comprises the following components in parts by weight: 80-95 parts of methyl siloxane; 5-20 parts of phenyl siloxane; 0.005-0.05 part of catalyst; 0.005-0.1 part of neutralizer; and 0.1-1.0 part of blocking agent. In the invention, the resin has various excellent performances, such as cold resistance, heat resistance, elasticity and the like and can be applied to materials of the elastic cement gum bumper core for trucks or rolling stocks, and also applied to cold-resistant resin for preparing various molded and extruded products for aviation industry as well as sealing rings, spacers, tube materials and bar materials for the use of ablative resistant, aging-resistant or radiation-resistant parts.

Description

technical field [0001] The invention relates to a manufacturing method and product of an elastic resin, in particular to a manufacturing method and a product of a core elastic mastic material for an elastic mastic buffer. It belongs to the field of polymer material production. Background technique [0002] The buffer is one of the important parts of the rail transit vehicle. Its function is to ease the impact of the vehicle and reduce the longitudinal impulse of the vehicle. It can protect the vehicle during shunting operations, train starting, braking, speed regulation, and collision accidents. and the role of goods. The performance of the buffer directly affects the driving safety and passenger comfort, so all countries in the world pay attention to the development and research of buffers with good performance. Hydraulic oil, metal spring, and rubber are three commonly used buffering and damping media or materials, and the buffering and damping products made of them are ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G77/06C08G77/08C08G77/20B61G11/08
Inventor 王楷李鸿学衷敬和黎勇李儒剑廖波
Owner ZHUZHOU TIMES NEW MATERIALS TECH
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