Toner, image forming method, and image forming apparatus
一种调色剂、平均粒径的技术,应用在调色剂领域,能够解决成膜危险、凹部大小、深度、形状和排列方式不均匀、调色剂粒子带电不良等问题,达到带电均匀性优异的效果
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preparation example Construction
[0089] The following shows preparation examples of polyester resins, various physical properties, and preparation examples of toner mother particles. In addition, unless otherwise indicated, parts means parts by mass, and water means deionized water.
[0090] (Synthesis example of polyester resin)
[0091] Each molar combination ratio shown in Table 1 below uses terephthalic acid (TPA) and isophthalic acid (IPA) as dicarboxylic acids, and polyoxypropylene (2.4)-2,2-bis(4-hydroxybenzene) Base) propane (BPA-PO) and polyoxyethylene (2.4)-2,2-bis(4-hydroxyphenyl)propane (BPA-EO) as aromatic diols, and ethylene glycol (EG) as aliphatic Diol, trimethylolpropane (TMP) was used as aliphatic triol, and tetrabutyl titanate as a polymerization catalyst was 0.3% by mass relative to the total monomer content, and was added to a separable flask, and a thermometer was installed on the upper part of the flask , Stirring rod, condenser and nitrogen introduction tube, in an electric heating mantle...
Embodiment 1
[0201] After putting 2 kg of toner mother particles obtained by the above reverse emulsification method into a Henschel mixer (20L), the amount added per 100 g of toner mother particles (average volume particle diameter 2.9μm) is calculated (the same below ), except for the small particle size silica ("RX200" manufactured by Japan Aerosil Co., Ltd., primary particle size 12nm, HMDS (hexamethylsilazane) treated product) 2.0g, large particle size silica (made by Nippon Shokubai Co., Ltd.) "KEP10S", the primary particle size is 100nm, silicone oil treated product) 0.5g, further added θ-alumina particles "made by Damei Chemical Co., TAIMICRON TM-100, primary particle size 14nm, BET specific surface area 132m 2 / g" 1.0g, processed at a peripheral speed of 40 m / s for 2 minutes. After the treatment, coarse particles were removed with a sonic sieve using a 63 μm mesh metal mesh to obtain a toner.
Embodiment 2
[0203] In addition to replacing the θ-alumina particles in Example 1, γ-alumina particles "manufactured by Damei Chemical Co., Ltd., TM-300, primary particle size 7nm, BET specific surface area 225m" 2 A toner was prepared in the same manner as in Example 1 except for 1.0 g.
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