Method for controlling semiconducting speed and degree of metal oxide material surface
A technology of oxides and metals, which is applied in the field of controlling the surface semiconducting speed and degree of high resistivity metal oxide materials, which can solve the problems of unfavorable expected products, difficult control of semiconducting speed and degree, and achieve easy operation , the effect is obvious
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Embodiment 1
[0012] Select 10 sintered nickel-copper-zinc ferrite ceramic discs with a diameter of 1 cm and a thickness of 1 mm, and the ferrite composition is Ni 0.3 Zn 0.5 Cu 0.2 Fe 2 o 4 , the molar percentage of iron element is 28.6%. Put the nickel-copper-zinc ferrite ceramic disk and the steel ball with a diameter of 0.5mm in the hanging basket, immerse the hanging basket in the sodium sulfate aqueous solution, use the titanium basket as the anode, and electrolyze the aqueous solution under the condition of vibration. The surface of the bulk material is modified by atomic hydrogen conductance to make the surface semiconducting. The process parameters are as follows:
[0013] Sodium Sulfate (Na 2 SO 4 ) aqueous solution 41.7 g / L
[0014] Na 2 EDTA aqueous solution 1.86 g / L
[0015] Cathode current density 2 amps / square decimeter
[0016] Temperature 20°C
[0017] After processing for 5 minutes, 10 minutes, 15 minutes, 20 minutes and 30 minutes respectively, take out the fe...
Embodiment 2
[0019] Select 10 sintered nickel-copper-zinc ferrite ceramic discs with a diameter of 1 cm and a thickness of 1 mm, and the ferrite composition is Ni 0.3 Zn 0.5 Cu 0.2 Fe 2 o 4 , the molar percentage of iron element is 28.6%. Put the nickel-copper-zinc ferrite ceramic disk and the steel ball with a diameter of 0.5mm in the hanging basket, immerse the hanging basket in the sodium sulfate aqueous solution, use the titanium basket as the anode, and electrolyze the aqueous solution under the condition of vibration. The surface of the bulk material is modified by atomic hydrogen conductance to make the surface semiconducting. The process parameters are as follows:
[0020] Sodium Sulfate (Na 2 SO 4 ) aqueous solution 41.7 g / L
[0021] Na 2 EDTA aqueous solution 3.73 g / L
[0022] Cathode current density 2 amps / square decimeter
[0023] Temperature 20°C
[0024] After processing for 5 minutes, 10 minutes, 15 minutes, 20 minutes, 30 minutes, and 40 minutes, take out the fe...
Embodiment 3
[0026] As mentioned above, select 10 sintered nickel-copper-zinc ferrite ceramic discs, the diameter is 1 cm, the thickness is 1 mm, and the ferrite composition is Ni 0.3 Zn 0.5 Cu 0.2 Fe 2 o 4 , the molar percentage of iron element is 28.6%. Put the nickel-copper-zinc ferrite ceramic disk and the steel ball with a diameter of 0.5mm in the hanging basket, immerse the hanging basket in the sodium sulfate aqueous solution, use the titanium basket as the anode, and electrolyze the aqueous solution under the condition of vibration. The surface of the bulk material is modified by atomic hydrogen conductance to make the surface semiconducting. The process parameters are as follows:
[0027] Sodium Sulfate (Na 2 SO 4 ) aqueous solution 41.7 g / L
[0028] Na 2 EDTA aqueous solution 11.16 g / L
[0029] Cathode current density 2 amps / square decimeter
[0030] Temperature 20°C
[0031] After processing for 5 minutes, 10 minutes, 15 minutes, 20 minutes, 30 minutes, and 40 minute...
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