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Polyether amine, production method thereof and application of polyether amine in methanol gasoline

A technology of methanol gasoline and polyether amine, which is applied in chemical instruments and methods, petroleum industry, preparation of organic compounds, etc. It can solve the problems of complex production process, high cost, low efficiency, etc., and achieve the improvement of market competitiveness and performance , the effect of preventing air resistance

Inactive Publication Date: 2011-01-19
张延涵 +3
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In production, each type of compound is compounded by multiple components, which will lead to complicated production process, low efficiency and high cost

Method used

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  • Polyether amine, production method thereof and application of polyether amine in methanol gasoline
  • Polyether amine, production method thereof and application of polyether amine in methanol gasoline
  • Polyether amine, production method thereof and application of polyether amine in methanol gasoline

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0064] Embodiment 1 M10 methanol gasoline

[0065] Under normal temperature, normal pressure, non-spark static electricity, explosion-proof operating conditions:

[0066] Will meet the national standard "GB / T 23510-2009" vehicle fuel methanol standard (according to weight) methanol 10%, 90# national standard gasoline 80.7%, butanol 2%, 200# solvent naphtha 7%, the polymer of the present invention 0.2% ether amine, 0.1% compound additive containing a small amount of MMT, anti-corrosion agent, anti-swelling agent, antioxidant, and detergent. After mixing, the pump circulates for 2 hours, and it can be used after standing for 48 hours.

[0067] After testing:

[0068] 1. Octane number 94.2.

[0069] 2. Reid method saturated vapor pressure 64kPa.

[0070] 3. The ability of miscibility and water resistance (under the temperature of 30°C in summer) is: adding 1% water will not be turbid or stratified, and the required goal will be achieved.

[0071] 4. After six months of storag...

Embodiment 2

[0072] Embodiment 2 M15 methanol gasoline

[0073] Under normal temperature, normal pressure, non-spark static electricity, explosion-proof operating conditions:

[0074] Will meet the national standard "GB / T 23510-2009" vehicle fuel methanol standard (according to weight) methanol 15%, 90# national standard gasoline 74.41%, butanol 2.2%, 200# solvent naphtha 8%, the polymer of the present invention Ether amine 0.29%, compound additive containing a small amount of MMT, anti-corrosion agent, anti-swelling agent, antioxidant, and detergent 0.1%, after mixing, the pump circulates for 2 hours, and it can be used after standing for 48 hours.

[0075] After testing:

[0076] 1. Octane number 94.7.

[0077] 2. Reid method saturated vapor pressure 63kPa.

[0078] 3. The ability of miscibility and water resistance (at 30°C) is: add 1.2% water without turbidity or stratification, and meet the required goals.

[0079] 4. After six months of storage, no acidic substances were detected...

Embodiment 3

[0080] Example 3 M20 methanol gasoline

[0081] Under normal temperature, normal pressure, non-spark static electricity, explosion-proof operating conditions:

[0082] 20% methanol, 69.85% 90# national standard gasoline, 2.7% butanol, C 9 7% aromatic hydrocarbons, 0.35% polyetheramine according to the present invention, 0.1% compound additives containing a small amount of MMT, anti-corrosion agent, anti-swelling agent, antioxidant, and detergent. After mixing, the pump circulates for 2 hours and stands still for 48 hours. use.

[0083] After testing:

[0084] 1. Octane number 95.1.

[0085] 2. Reid method saturated vapor pressure 62kPa.

[0086] 3. The ability of miscibility and water resistance (at 30°C) is: add 1.3% water without turbidity or stratification, and meet the required goals.

[0087] 4. After six months of storage, no acidic substances were detected.

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Abstract

The invention discloses polyether amine, a production method thereof, and application of the polyether amine in methanol gasoline. The polyether amine can improve intersolubility, water resistance, air resistance, acid-neutralizing capacity of the methanol gasoline simultaneously and simplify an additive formula and the production process of the methanol gasoline. The polyether amine is prepared by addition of hexylamine and ethylene oxide. Experiments prove that: when the polyether amine is used together with butanol or octanol which accounts for 2 to 3 percent of the total weight, the waterresistance of the methanol gasoline is 1 to 2 percent, and when the polyether amine is used together with No.200 solvent oil or C9 aromatic hydrocarbon which accounts for 7 to 8 percent of the total weight, the saturated vapor pressure is less than 65kPa, and the methanol gasoline has the advantages of acid-neutralizing capacity and obvious improvement of a plurality of indexes. Due to the application of the polyether amine, the invention provides a method for producing the methanol gasoline, which has the advantages of simpleness, convenience, high efficiency and lower cost.

Description

technical field [0001] The present invention relates to a kind of polyetheramine and its production method and the application of the polyetheramine prepared by said method in methanol gasoline, especially relate to the method that this polyetheramine simplifies the additive formulation and production process of methanol gasoline, The invention also relates to a method for improving multiple indexes of methanol gasoline. Background technique [0002] In the methanol gasoline technology, the development status of the existing technologies is as follows: [0003] 1. Miscibility and water resistance [0004] With regard to realizing miscible water resistance, many known oxygen-containing compounds, such as the composition of ethers, higher alcohols, ketones and esters, can play an effective role. Patents offer some options for this. [0005] Commonly used co-solvents are C 3 ~C 8 Alcohols, which have hydroxyl groups (OH), can form hydrogen bonds with methanol, and have hyd...

Claims

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Application Information

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IPC IPC(8): C07C217/28C07C213/04C10L1/222
Inventor 李治陈瑛
Owner 张延涵
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