Two-component mortar composition suitable for construction purposes, its use and cured structures obtained therefrom
A composition, two-component technology, applied in the direction of foundation structure engineering, sheet pile wall, construction, etc., can solve the problems of weak system, high sensitivity to changes in reactive diluent content, etc., achieve long gel time, shrinkage Low rate, fast curing effect
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[0051] A) Synthesis of resins containing norbornene groups
[0052] A 2 L reactor equipped with a mechanical stirrer and Dean Stark apparatus was charged with 402 g trimethylolpropane, 147 g maleic anhydride and 1.1 g dibutylhydroquinone. After heating the mixture to 100° C. during 2 h, 218 g of toluene, 10.9 g of p-toluenesulfonic acid and 541 g of crotonic acid were added. The reaction mixture was heated to reflux and water was removed azeotropically over 28 hours. A further 7.7 g of trimethylolpropane oxetane were added and the mixture was stirred at 100°C for a further 1 hour. Toluene and excess crotonic acid were then distilled off, resulting in the formation of a yellowish resin. The resin was heated to 165°C and 550 g of DCPD were slowly added over a period of 8 hours while maintaining the reaction temperature between 165 and 180°C. After the addition was complete, the reaction mixture was kept at 170° C. for more than 2 hours, t...
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