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High brightness mechanical luminescent material and preparation method thereof

A mechanoluminescent, high-brightness technology, applied in the direction of luminescent materials, chemical instruments and methods, etc., can solve the problems of single luminescent color and single system, and achieve the effect of simple preparation method, low cost, and stable physical and chemical properties

Inactive Publication Date: 2013-11-27
CHANGCHUN INST OF OPTICS FINE MECHANICS & PHYSICS CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The purpose of the present invention is to provide a high-brightness mechanical luminescent material and its preparation method in order to solve the problem of single and single luminous color of the existing aluminate system mechanical luminescent material system

Method used

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  • High brightness mechanical luminescent material and preparation method thereof
  • High brightness mechanical luminescent material and preparation method thereof
  • High brightness mechanical luminescent material and preparation method thereof

Examples

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preparation example Construction

[0015] A method for preparing a high-brightness mechanical luminescence material, the method is realized by the following steps:

[0016] (1) The general formula of the material is M 2-x-y-z-w Zn w P 2 o 7 :Eu x , Mn y , Ln z The oxides, halides, carbonates or hydrogen phosphates of the elements are used as raw materials, weighed according to the stoichiometric ratio, thoroughly ground and mixed and pressed into tablets to obtain a mixture sample; the M represents one of Ca and Sr Or its combination, or any combination of Ca, Sr and Mg, or any combination of Ca, Sr and Ba; Ln represents La, Ce, Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er, Tm, Yb, One or any combination of Lu; the value range of x is: 0.0001≤x≤0.20, the value range of y is: 0.001≤y≤0.30, the value range of z is: 0<z≤0.20, the value range of w The value range is: 0<w≤0.20;

[0017] (2) Put the mixture sample obtained in step (1) into a crucible, put it into a high-temperature muffle furnace for roasting under reducin...

Embodiment 1

[0026] A high-brightness mechanical luminescent material whose general formula is M 2-x-y-z-w Zn w P 2 o 7 :Eu x , Mn y , Ln z , wherein when M=Ca, Ln=La, x=0.001, y=0.001, z=0.001, w=0.20 in the general chemical formula, the prepared molecular formula is Ca 1.797 Zn 0.20 P 2 o 7 :Eu 0.001 , Mn 0.001 , La 0.001 mechanoluminescent materials.

[0027] Weigh 2.4440g CaHPO according to stoichiometric ratio 4 , 0.2680g (NH 4 ) 2 HPO 4 , 0.0035gEu 2 o 3 , 0.0012g MnCO 3 , 0.0035g La 2 o 3 , 0.1628g ZnO, after the weighed raw materials are fully ground and mixed, pressed into tablets, placed in a high-purity corundum crucible, and roasted in a high-temperature muffle furnace under a carbon monoxide reducing atmosphere, roasted at 1150 ° C for 4 hours, cooled , grinding and washing to obtain the yellow photomechanical luminescent material Ca 1.797 Zn 0.20 P 2 o 7 :Eu 0.001 , Mn 0.001 , La 0.001 .

Embodiment 2

[0029] A high-brightness mechanical luminescent material whose general formula is M 2-x-y-z-w Zn w P 2 o 7 :Eu x , Mn y , Ln z , wherein when M=Ca, Ln=Ce, x=0.005, y=0.008, z=0.005, w=0.18 in the general chemical formula, the prepared molecular formula is Ca 1.802 Zn 0.18 P 2 o 7 :Eu 0.005 , Mn 0.008 , Ce 0.005 mechanoluminescent materials.

[0030] Weigh 2.4507g CaHPO according to stoichiometric ratio 4 , 0.2614g (NH 4 ) 2 HPO 4 , 0.0176gEu 2 o 3 , 0.0092g MnCO 3 , 0.0086g CeO 2, 0.1465g ZnO, after the weighed raw materials are thoroughly ground and mixed, pressed into tablets, placed in a platinum crucible, and roasted in a high-temperature muffle furnace under an ammonia reducing atmosphere, roasted at 1150°C for 4 hours, cooled, After grinding and washing, the yellow photomechanical luminescence material Ca 1.802 Zn 0.18 P 2 o 7 :Eu 0.005 , Mn 0.008 , Ce 0.005 .

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Abstract

The invention discloses a high brightness mechanical luminescent material and a preparation method thereof, and relates to a mechanical luminescent material capable of emitting bright yellow and orange light under the action of mechanical force such as friction force, pressure and impact force, and a preparation method thereof. The invention solves the problem that the conventional aluminate system mechanical luminescent material has a single system and a single color of emitted light. The material has the general formula of M2-x-y-z-wZnwP2O7:Eux,Mny,Lnz, wherein M refers to one or a combination of Ca and Sr, an arbitrary combination of Ca, Sr and Mg, or an arbitrary combination of Ca, Sr and Ba; Ln refers to one or an arbitrary combination of La, Ce, Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu; and x is more than or equal to 0.0001 and less than or equal to 0.20, y is more than or equal to 0.001 and less than or equal to 0.30, z is more than 0 and less than or equal to 0.20, and w is more than 0 and less than or equal to 0.20. The preparation process for the luminescent material is simple, low in cost and pollution-free.

Description

technical field [0001] The invention relates to a high-brightness mechanical luminescent material and a preparation method thereof, in particular to a mechanical luminescent material capable of emitting bright yellow-orange light under mechanical forces such as friction, pressure or impact, and a preparation method thereof. Background technique [0002] Mechanoluminescent materials are a general term for a class of materials that can convert mechanical energy into light energy. Such materials can be used in triboluminescent anti-counterfeiting inks, pressure-sensitive luminous bodies, pressure detection sensors, ultra-precision processing image monitoring systems, stress flaw detection and earthquake early warning and other fields. At present, mechanoluminescent materials mainly include inorganic and organic materials. Although there are many types of organic complex materials, their luminous brightness, stability and practicability are poor. Phosphoric luminescent material...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09K11/71
Inventor 张家骅郝振东张霞
Owner CHANGCHUN INST OF OPTICS FINE MECHANICS & PHYSICS CHINESE ACAD OF SCI
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