Method for adjusting work function of metal gate applied to N-channel metal oxide semiconductor (NMOS) device
An adjustment method and metal gate technology, applied in semiconductor devices, semiconductor/solid-state device manufacturing, electrical components, etc., to achieve good thermal stability, good adjustment of metal gate work function, and easy industrialization
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[0025] The present invention utilizes the physical vapor deposition (PVD) method to deposit a layer of metal nitride film or metal film on high-K medium such as HfLaOH, HfSiON, etc., as the metal gate electrode, and then adopts the ion implantation method to carry out the metal gate electrode Doping, for NMOS devices, the selected ion implantation elements are Tb, or Er, or Yb, or Sr and other elements, and then the doped metal ions are driven into the interface between the metal gate electrode and the high-K gate dielectric by high-temperature thermal annealing Stacks are formed on the substrate or dipoles are formed on the interface between the high-K gate dielectric and SiO2 through interfacial reactions, resulting in changes in the gate work function. The amount of change is related to the metal gate material and the type of dopant ions, the profile distribution of the concentration and the reaction with the interface. Optimizing the energy, dose, and heat treatment condit...
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