Fe-based nanocrystalline soft magnetic alloy with strong amorphous forming ability and preparing method of Fe-based nanocrystalline soft magnetic alloy

A technology of iron-based nanocrystals and soft magnetic alloys, which is applied in the direction of magnetic materials, magnetic objects, electrical components, etc., and can solve problems such as extremely strict requirements for process and heat treatment processes, restrictions on the application field of nanocrystals, and difficulties in the production and preparation of nanocrystals.

Active Publication Date: 2015-09-23
ADVANCED TECHNOLOGY & MATERIALS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, the amorphous formation ability of this component is very poor, and high-density nanocrystalline nuclei are produced during the preparation process. The subsequent crystallization heat treatment must be rapidly annealed to obtain a nano-double phase structure with excellent performance. Therefore, the annealing process of this component is difficult to control and difficult to industrialize. Production
[0009] In summary, nanocry

Method used

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  • Fe-based nanocrystalline soft magnetic alloy with strong amorphous forming ability and preparing method of Fe-based nanocrystalline soft magnetic alloy
  • Fe-based nanocrystalline soft magnetic alloy with strong amorphous forming ability and preparing method of Fe-based nanocrystalline soft magnetic alloy
  • Fe-based nanocrystalline soft magnetic alloy with strong amorphous forming ability and preparing method of Fe-based nanocrystalline soft magnetic alloy

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Effect test

Embodiment 1

[0059] According to the composition range of the iron-based nanocrystalline alloy of the present invention, we have done a series of experiments. Dosing according to the composition of the present invention, see Table 1 (serial number 1-20) for the specific composition and atomic percentage content, put the raw materials with good ratio into induction melting furnace or electric arc melting furnace, and vacuumize to 5×10 -3Below Pa, then fill with argon atmosphere to protect, completely melt and then keep warm for 30 minutes to melt the alloy raw materials into a uniform molten steel, pour into the mold to cool to obtain a master alloy ingot with uniform composition; then break the master alloy ingot; Put it into a quartz tube and melt it into molten steel. The melting temperature is about 1300°C. Spray the tape at a speed of 35m / s in the air. The temperature of the spray tape is 1200°C. is 1mPas, the cooling rate is 10 2 °C / s, the amorphous alloy strips with a width of 1mm a...

Embodiment 2

[0070] According to the composition range of the iron-based nanocrystalline alloy of the present invention, we have done a series of experiments. Fe with high saturation magnetic induction of the present invention x Si a B b P c Nb d Cu e An alloy in which Cu is partially or completely replaced by at least 3 atomic % of at least one element among Ag and Au. Table 2 is according to the composition of the present invention to carry out batching, and the raw material of proportioning is put into induction melting furnace or electric arc melting furnace, and vacuumizes to 5 * 10 -3 Pa below, then filled with nitrogen atmosphere protection, after melting, keep warm for 30 minutes to melt the alloy raw materials into a uniform molten steel, pour into the mold to cool down to obtain an alloy ingot with uniform composition; break the master alloy ingot; put small pieces of master alloy into a quartz tube and melt it into a For molten steel, the melting temperature is about 1500°...

Embodiment 3

[0076] According to the composition range of the iron-based nanocrystalline alloy of the present invention, we have done a series of experiments. Fe with high saturation magnetic induction of the present invention x Si a B b P c Nb d Cu e An alloy, wherein Nb is partially or completely replaced by at least 3 atomic % of at least one element among Zr, Ti, Ta, Hf, V, W, Mo, Mn, Cr, and Zn. Table 3 carries out batching according to the composition of the present invention, puts the raw material of ratio into induction melting furnace or electric arc melting furnace, vacuumizes to 5 * 10 -3 Pa below, then filled with nitrogen atmosphere protection, after melting, keep warm for 30 minutes to melt the alloy raw materials into a uniform molten steel, pour into the mold to cool down to obtain an alloy ingot with uniform composition; break the master alloy ingot; put small pieces of master alloy into a quartz tube and melt it into a Molten steel, the melting temperature is about ...

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Abstract

The invention discloses a Fe-based nanocrystalline soft magnetic alloy with strong amorphous forming ability and a preparing method of the Fe-based nanocrystalline soft magnetic alloy. The alloy has an expression of Fe<x>SiBP<c>Nb<d>Cu<e>, wherein in the expression, each of the x, the a, the b, the c, the d and the e shows the atomic percentage content of the corresponding ingredient, and meets the following conditions that the a is greater than or equal to 0.5 but smaller than or equal to 12; the b is greater than or equal to 0.5 but is smaller than or equal to 15; the c is greater than or equal to 0.5 but smaller than or equal to 12; the d is greater than or equal to 0.1 but smaller than or equal to 3; the e is greater than or equal to 0.1 but smaller than or equal to 3; the x is greater than or equal 70 but smaller than or equal to 85; and the sum of the x, the a, the b, the c, the d and the e is 100 percent. The soft magnetic alloy has the advantages that an ordinary copper mold casting method can be used for preparing a Fe-based amorphous alloy with the critical dimension being 3.5mm; after the annealing; the saturation flux density is greater than 1.5T; and the coercive force value is smaller than 1A/m.

Description

technical field [0001] The invention relates to the field of magnetic functional materials, in particular to an iron-based nanocrystalline soft magnetic alloy with strong amorphous forming ability and a preparation method thereof. The alloy has strong amorphous forming ability, high thermal stability and excellent soft magnetic performance. Background technique [0002] Fe nanocrystalline alloy has the advantages of high resistivity, low loss, high strength and toughness, high magnetic permeability, and high saturation magnetization. At the same time, the preparation process is short, and the product is energy-saving and environmentally friendly. Therefore, it is considered to be the core of switching power supply and pulse transformer. , Ideal materials for power and electronic equipment such as transformers, magnetic amplifiers, spike suppressors, differential mode inductor cores and reactor cores. [0003] However, compared with commercial silicon steel sheets, the satura...

Claims

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Application Information

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IPC IPC(8): H01F1/153C22C45/02C21D1/26
Inventor 周少雄李宗臻常春涛王安定董帮少张广强刘国栋王新敏向睿李润伟
Owner ADVANCED TECHNOLOGY & MATERIALS CO LTD
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