Fine yellow pigment combination, pigment dispersion having the combination and manufacturing method of the fine yellow combination
A yellow pigment and composition technology, applied in the directions of pigment paste, chemical instruments and methods, azo dyes, etc., to achieve the effect of improving the contrast ratio and being easy to manufacture
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manufacture example 1
[0090] (Production Example 1) Preparation of Triazine Pigment Derivative (A)
[0091] Add 7.3 g of cyanuric chloride and 6.8 g of p-aminobenzenesulfonic acid (trade name: ASA p-sulfanilic acid, manufactured by Sugai Chemical Industry Co., Ltd. ), reacted at 20°C for 1 hour. Then add 10 g of 4,4'-methylene-di-2,6-xylaniline (trade name: KAYABOND C-200S, manufactured by Nippon Kayaku) in an amount reacted with 1 C1 of the reactant, at 70 °C for 1 hour. The obtained reactant was filtered, and the residue was washed with water, and then left to stand overnight in a thermostat at 80°C for drying to obtain 17.0 g of a triazine derivative (A) represented by the following formula (9).
[0092] Formula (9)
[0093]
manufacture example 2
[0094] (Production Example 2) Preparation of Triazine Pigment Derivative (B)
[0095] 10 g of 3,3'-dichlorobenzidine was added to 100 g of water to disperse it, and 7.3 g of cyanuric chloride in an amount reacting with one amino group was added and reacted at 20°C for 1 hour. Then, 13.7 g of p-aminobenzenesulfonic acid was added and reacted at 90° C. for 1 hour to obtain 26.6 g of a triazine pigment derivative (B) having a structure of the following formula (10).
[0096] Formula (10)
[0097]
Embodiment 1
[0099] In a high-speed mixer (manufactured by KAWATA Company, Super Mixer SMV-20), 500 g of Yellow 138 (trade name "Paliotol Yellow L0960HD, manufactured by BASF Company) as a quinophthalone pigment, anhydrous Glauber's salt as a water-soluble inorganic salt ( The average particle diameter is about 5 μm, 5000 g of anhydrous Glauber's salt described in Japanese Patent Laid-Open No. 2009-263501, 1045 g of ethylene glycol as a water-soluble organic solvent, 50 g of sulfonated pigment derivatives represented by the following formula (11), and manufactured 25 g of the triazine pigment derivative (A) of Example 1 was pre-mixed for about 2 minutes, and mixed uniformly.
[0100] This mixture was supplied to a continuous kneader (Miracle KCK32 manufactured by Asada Iron Works Co., Ltd.). The kneading conditions were an extrusion rate of 6.6 kg / h, a rotational speed of 90 rpm, and grinding and kneading while controlling the temperature so that the temperature of the kneaded product was ...
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