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Multifunctional black master batch for polypropylene resin and preparation method thereof

A black masterbatch, polypropylene technology, applied in the field of plastic coloring, can solve the problems of high consumption of antioxidants, complex process, many components, etc., and achieve low consumption, low dosage, and downstream material forming processing technology. simple effect

Active Publication Date: 2012-06-13
NANHUA UNIV +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The method of adding a single masterbatch makes it necessary to use a large amount of carrier resin when the comprehensive performance of polypropylene resin is high, and thus leads to high consumption of antioxidants during processing, and many components for downstream molding processing. Disadvantages such as complex process

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] Example 1. Preparation of 100Kg multifunctional black masterbatch, the weight of each component is: pigment carbon black: 30kg; carbon nanotube: 2kg; polypropylene grafted maleic anhydride copolymer: 3kg; antioxidant 1010: 1.5kg ; Antioxidant 1076: 1kg; Auxiliary Antioxidant DSTP: 1.5kg; Metal Passivator GI-09-367: 1kg; Diethylene Stearamide: 15kg; Zinc Stearate: 5kg; Linear Low Density Ethylene: 40kg.

[0021] Its preparation method is as follows:

[0022] The pigment carbon black, carbon nanotubes, polypropylene grafted maleic anhydride copolymer, antioxidant 1010, antioxidant 1076, auxiliary antioxidant DSTP, metal passivator GI-09-367, diethylene stearin Acid amide, zinc stearate and linear low density polyethylene resin are added to a high-speed mixer and mixed for 20-30 minutes, then the mixture is added to a twin-screw extruder to extrude, cooled, dried, cut into pellets and packaged into the desired masterbatch.

[0023] Forming and testing of polypropylene pl...

Embodiment 2

[0025] Example 2. Preparation of 100Kg multifunctional black masterbatch, the weight of each component is: pigment carbon black: 26kg; carbon nanotube: 2.5kg; polypropylene grafted maleic anhydride copolymer: 2.5kg; antioxidant 1010: 1.5kg; Antioxidant 1076: 1kg; Auxiliary Antioxidant DSTP: 1.5kg; Metal Passivator GI-09-367: 1kg; Diethylene Stearamide: 18kg; Zinc Stearate: 6kg; Polypropylene Resin: 40kg.

[0026] Its preparation method is as follows:

[0027] The pigment carbon black, carbon nanotubes, polypropylene grafted maleic anhydride copolymer, antioxidant 1010, antioxidant 1076, auxiliary antioxidant DSTP, metal passivator GI-09-367, diethylene stearin Acid amide, zinc stearate and polypropylene resin are added to a high-speed mixer and mixed for 20-30 minutes, then the mixture is added to a twin-screw extruder for extrusion, cooled, dried, cut into pellets and packaged into the desired masterbatch.

[0028] Forming and testing of polypropylene plastic samples:

[0...

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Abstract

The invention discloses a multifunctional black master batch for polypropylene resin. The multifunctional black master batch comprises the following components in percentage by weight: 25-35 percent of pigment carbon black, 1-4 percent of a carbon nanotube, 2-6 percent of a compatilizer, 2-8 percent of an aging-proof agent, 15-25 percent of a dispersing lubricating agent and 35-45 percent of carrier resin, wherein the carbon nanotube and the pigment carbon black construct an anti-static system together; and the aging-proof agent and the pigment carbon black construct an aging-proof system together. Polypropylene is effectively prevented from aging, and the requirements of coloring, color retention and dust pollution prevention on a one-step molded polypropylene external decorative part for black electrical appliances are met. The preparation method comprises the following steps of: adding the pigment carbon black, the carbon nanotube, the compatilizer, the aging-proof agent, the dispersing lubricating agent and the carrier resin into a high-speed mixer for mixing; feeding into a dual-screw extruder for extruding; and cooling, drying, granulating and packing to obtain a needed master batch. The multifunctional black master batch has the characteristics of small using amount of the carrier resin, low consumption of a master batch molding antioxidant and simple feeding in a molding process of downstream materials, and can be widely applied to colorization of polypropylene resin.

Description

technical field [0001] The invention relates to the technical field of plastic coloring, in particular to a multifunctional black masterbatch for polypropylene resins and a preparation method. Background technique [0002] Polypropylene (PP) has the advantages of abundant raw material sources, low price, easy molding and processing, good rigidity and excellent mechanical properties, heat resistance, chemical resistance, excellent comprehensive performance, non-toxicity, and recyclability. Widely used in the automotive industry, household appliances, industrial supporting materials, packaging, office supplies, medical supplies and daily necessities and other industries, it has become the fastest growing variety of general plastics. In plastic products, especially black home appliances, one-shot polypropylene outer trim parts are more energy-efficient and material-saving than traditional metal outer trim parts. [0003] Polypropylene, on the other hand, has high electrical in...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/06C08L23/12C08L51/06C08K13/02C08K3/04C08K5/20C08K5/098C08J3/22
Inventor 刘芝芳王孟杜勇吴红枚陈鑫陈仲清
Owner NANHUA UNIV
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