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Metal catalyst composition modified by nitrogen-containing compound

A technology of metal catalysts and nitrogen compounds, applied in battery electrodes, circuits, electrical components, etc., can solve problems such as activity decline, cathode catalyst poisoning, and discharge voltage reduction, so as to reduce reaction overpotential, improve reaction activity, and steric hindrance increased effect

Active Publication Date: 2012-07-11
IND TECH RES INST
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] Generally speaking, in a direct methanol fuel cell device, if methanol penetrates into the cathode, it will cause the poisoning of the cathode catalyst. At the same time, the direct methanol fuel cell has the problem of anode over-potential, which leads to a decrease in discharge voltage and a decline in activity, especially is more significant when using high concentrations of methanol as fuel

Method used

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  • Metal catalyst composition modified by nitrogen-containing compound
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  • Metal catalyst composition modified by nitrogen-containing compound

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Embodiment Construction

[0051] The invention relates to a metal catalyst modified by a nitrogen-containing compound. The lone pair (lone pair) of nitrogen in the nitrogen-containing compound is used to coordinate with the d orbital of the metal catalyst to occupy the position where the metal catalyst combines with carbon monoxide (CO) to prevent Or reduce the possibility of catalyst being poisoned.

[0052] In addition, after the metal catalyst is combined with nitrogen-containing compounds, its steric hindrance increases, which can improve the dispersion effect of catalyst particles, reduce the activity loss caused by aggregation, and improve the reaction activity. In addition, the nitrogen-containing compound-modified metal catalyst of the present invention can also reduce its overpotential when used as an anode.

[0053] The invention relates to a novel metal catalyst composition modified by a nitrogen-containing compound, which comprises a metal catalyst and at least one nitrogen-containing compo...

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Abstract

The present invention relates to a metal catalyst composition modified by a nitrogen-containing compound, which effectively reduces cathode catalyst poisoning. The catalyst composition applied on the anode also lowers the over-potential. The catalyst coupled with the nitrogen-containing compound has increased three-dimensional hindrance, which improves the distribution of the catalyst particles and improves the reaction activity.

Description

technical field [0001] The invention relates to a catalyst and a membrane electrode group, in particular to a metal catalyst and a membrane electrode group applied to a fuel cell. Background technique [0002] Due to the demand for clean energy, fuel cells have been mass-produced and used in different fields such as industry, housing, and transportation. Direct methanol fuel cell (Direct methanol fuel cell; DMFC), also known as micro fuel cell. Direct Methanol Fuel Cells convert methanol gas into electricity, providing portable power that enables laptops or other handheld electronic devices to last longer. [0003] Generally speaking, in a direct methanol fuel cell device, if methanol penetrates into the cathode, it will cause the poisoning of the cathode catalyst. At the same time, the direct methanol fuel cell has the problem of anode over-potential, which leads to a decrease in discharge voltage and a decline in activity, especially It is more significant when using hig...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/90H01M4/86
CPCY02E60/523Y02E60/50
Inventor 蔡丽端张嵩骏蔡惠雯康济云林俊男
Owner IND TECH RES INST
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