Temperature-sensitive color-changing coating
A temperature-sensitive discoloration and coating technology, applied in the field of building exterior wall materials, can solve the problems of difficult realization of discoloration, inability to use large-scale construction industry, high raw material cost, and achieve the effect of maintaining comfortable temperature, reducing use and saving energy.
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Embodiment 1
[0021] Macromolecular polyoxyethylene-polyoxypropylene-polyoxyethylene block copolymer, its molecular weight M n about 1x10 5 g / mol, 100 parts;
[0022] Film-forming agent, 8 parts;
[0023] Thickener, 1 part;
[0024] Dispersant, 2 parts;
[0025] Defoamer, 1 part;
[0026] Solvent water, 200 parts.
[0027] The above materials were dissolved and stirred for 90 minutes.
[0028] Polyoxyethylene-polyoxypropylene-polyoxyethylene block copolymer (PEO-PPO-PEO or EOn-POm-EOn) uses covalent bonds to link the hydrophilic PEO segment and the hydrophobic PPO segment together The polymer compound is used as a block copolymer (temperature-sensitive polymer) containing polyoxyethylene in this embodiment, which forms an emulsion or a solution in a certain solution under temperature control. In other embodiments, polyoxyethylene-polyoxybutylene-polyoxyethylene block copolymers or polyoxyethylene-polyoxypentene-polyoxyethylene block copolymers may also be used. In the example, the c...
Embodiment 2
[0029] Macromolecular polyethylene glycol-polyglycolide lactide-polyethylene glycol block copolymer, its molecular weight M n about 5x10 4 g / mol, 100 parts;
[0030] Film-forming agent, 8 parts;
[0031] Thickener, 1 part;
[0032] Dispersant, 2 parts;
[0033] Defoamer, 1 part;
[0034] Solvent water, 200 parts.
[0035] The above materials were dissolved and stirred for 90 minutes.
[0036] In the example, the color change temperature of the paint is about 40°C. When the temperature is above 40°C, the paint is white; when the temperature is below 40°C, the paint is colorless and transparent. When the temperature scanning rate of 0.5°C / min reaches 40°C, the color change time is about 5 minutes. After repeated discoloration 500 times, its discoloration performance is still stable.
[0037] In the present embodiment, macromolecular polyethylene glycol-polyglycolide lactide-polyethylene glycol block copolymer is used as a block copolymer (temperature-sensitive polymer) c...
Embodiment 3
[0039] Polymer N, N-diethylacrylamide, its molecular weight M n about 1x10 5 g / mol, 100 parts;
[0040] Film-forming agent, 8 parts;
[0041] Thickener, 1 part;
[0042] Dispersant, 2 parts;
[0043] Defoamer, 1 part;
[0044] Solvent water, 200 parts.
[0045] The above materials were dissolved and stirred for 90 minutes.
[0046] In the example, the color change temperature of the paint is about 38°C. When the temperature is above 38°C, the paint is white; when the temperature is below 38°C, the paint is colorless and transparent. When the temperature scanning rate of 0.5°C / min reaches 38°C, the color change time is about 1 minute. After repeated discoloration 500 times, its discoloration performance is still stable.
[0047] In this embodiment, the polymer poly-N,N-diethylacrylamide is used as a polyacrylamide polymer (temperature-sensitive polymer), which forms an emulsion or a solution in a certain solution under temperature control. In other embodiments, poly-N,...
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