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Manufacturing process of antibacterial bamboo pulp used for high-wet-modulus fibre

A high wet modulus fiber and manufacturing process technology, which is applied in the post-processing of cellulose pulp, pulping with inorganic alkali, and fiber raw material processing, etc., can solve the problem of short reaction time, unstable bamboo pulp quality, and poor pulp quality. Stability and other issues to achieve the effect of improving responsiveness

Active Publication Date: 2012-09-19
YIBIN GRACE GROUP CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Higher reaction temperature will cause the pulp produced to have the following defects: 1. The fiber molecular weight distribution range is wider; 2. The content of α-cellulose fluctuates greatly, which leads to unstable quality of bamboo pulp (higher reaction temperature It makes the reaction violent, makes it difficult to control the degree of reaction, and the reaction time is short, and some fibers are excessively degraded, resulting in an increase in hemicellulose, which also leads to a wide range of cellulose molecular weight distribution, so that the pulp quality is unstable); 3. Pulp There are more short and medium fibers of 0.05-0.3 mm (higher reaction temperature leads to violent reaction and shorter reaction time, some fibers will be excessively degraded and the fiber length will be shortened, so there are more short fibers of 0.05-0.3 mm in pulp); 4 , pulp ash, S 10 , S 18 , high content of impurities such as pentose sugar; 5. The low reactivity cannot meet the requirements of raw materials for high wet modulus fiber production; 6. The natural characteristics of bamboo fiber are destroyed during the processing of dissolved pulp, and the deodorization and antibacterial properties of the fiber , Anti-ultraviolet function is significantly reduced

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] A. Material preparation: Cut the bamboo material into required specifications and screen and wash to remove the dust and bamboo shavings.

[0034]B. Pre-hydrolysis: Carry out in a digester (steamer, steamer or continuous cooker), the technical conditions are: liquid ratio=1:4.0, the amount of hydrolysis aid is 0.05% of the weight of the dry bamboo material, and the water , bamboo material, and hydrolysis aids are mixed and cooked in a digester, and kept at 135°C for 2 hours, and the end point of the heat preservation is PH=3.2, and the treatment solution is removed after completion. The hydrolysis aids are biological enzymes, cellulose-decomposing enzymes, and sulfurous acid A mixture of sodium hydrogen, in which biological enzymes: cellulolytic enzymes: sodium bisulfite = 70%: 20%: 10%. .

[0035] C. Sulphate cooking: the total amount of alkali used is Na 2 In terms of O, it is 22% of the absolute dry bamboo material; the degree of vulcanization is 25%; the cooking a...

Embodiment 2

[0054] A. Material preparation, D. Oxygen delignification, E. Vibrating frame sieve screening, F. First washing, G. Sand removal, H. First concentration, I. Hydrogen peroxide bleaching, J. Second washing , L, pressure sieve screening to remove short fibers (less than 0.3mm), M, second concentration, N, sodium hypochlorite bleaching, O, third washing, P, acid treatment, Q, fourth washing, R, removal Sand and carry out operations such as papermaking process technology are all identical with embodiment 1. The difference is that:

[0055] B. Pre-hydrolysis: heat preservation at 130°C for 2.5 hours, and the end point of heat preservation is PH=3.4.

[0056] C. Sulphate cooking: heat preservation at 158°C for 4.0 hours.

[0057] K, hot alkali refining: the alkali used is NaOH, the consumption is 2.5% of the absolute dry pulp, the temperature is 85° C., and the time is 80 minutes.

[0058] The quality index of the dissolving pulp made through the above process is:

[0059] ...

Embodiment 3

[0061] A. Material preparation, D. Oxygen delignification, E. Vibrating frame sieve screening, F. First washing, G. Sand removal, H. First concentration, I. Hydrogen peroxide bleaching, J. Second washing , L, pressure sieve screening to remove short fibers (less than 0.3mm), M, second concentration, N, sodium hypochlorite bleaching, O, third washing, P, acid treatment, Q, fourth washing, R, removal Sand and carry out operations such as papermaking process technology are all identical with embodiment 1. The difference is that:

[0062] B. Pre-hydrolysis: heat preservation at 125°C for 3.5 hours, and the end point of heat preservation is PH=3.0.

[0063] C. Sulphate cooking: heat preservation at 156°C for 4.5 hours.

[0064] K, hot alkali refining: the alkali used is NaOH, the consumption is 3.0% of the absolute dry pulp, the temperature is 80°C, and the time is 90 minutes.

[0065] The quality index of the dissolving pulp made through the above process is:

[0066] ...

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Abstract

The invention discloses a manufacturing process of antibacterial bamboo pulp used for high-wet-modulus fibre. The manufacturing process comprises prehydrolysis, cooking, oxygen delignification, vibration frame screen screening, first washing, sand removal, first concentration, bleaching, second washing, thermal basic refining, pressurized screen preliminary sizing, second concentration, sodium hypochlorite bleaching, third washing, acid treatment, fourth washing, sand removal and manufacture, wherein a hydrolysis accessory ingredient is added in a cooker in prehydrolysis. The hydrolysis accessory ingredient is added in the prehydrolysis, so that the reaction temperature of the prehydrolysis and cooking processes is reduced, thus the content fluctuation of alpha-cellulose is small, the quality is stable, the indexes can meet the pulp requirement of high-wet-modulus fibre, and the natural deodorization, antibacterial and ultraviolet resistance functions of the bamboo fiber can be furthest remained.

Description

technical field [0001] The invention belongs to the field of chemical fiber pulp production, and in particular relates to a production process for preparing antibacterial bamboo pulp for high wet modulus fibers by adopting bamboo. Background technique [0002] High wet modulus fiber is a new generation of fiber with high strength, low elongation and swelling, high wet strength and wet modulus, which overcomes the poor wet strength and easy Disadvantages such as deformation. High wet modulus fiber pulp quality requirements are very high, and impurities such as lignin, semi-fiber, resin and ash must be fully removed, and the content of methyl fiber should usually be above 96%. demanding. Insufficient lignin removal and high hemifiber content in pulp greatly hinder the removal of hemifiber during the impregnation and pressing process of viscose preparation, which will affect the filterability of viscose and bring great negative impact on production and product quality. The e...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D21C1/00D21C3/02D21C9/02D21C9/18D21C9/16D21C9/12D21C9/00
Inventor 薛勤徐发祥于渭东刘爱兵蒲运龙张良
Owner YIBIN GRACE GROUP CO LTD
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