Method for fermentation production of butyl alcohol by utilizing cellulose and hemicellulose in bamboos
A technology of hemicellulose and cellulose, applied in the field of bioenergy, can solve problems such as unseen butanol, and achieve the effect of cheap raw materials
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Embodiment 1
[0036] Bamboo (Ph. pubescens, Jiangxi Moso) was pulverized by ultrafine airflow, and 5g of bamboo powder was pulverized by ultrafine airflow to a particle size of 2000 mesh, and 50mL, 0.5% (w / w) sulfuric acid solution (solid-liquid ratio was added) 1:10), react at 160°C for 20 minutes, adjust the pH of the hydrolysate to 4.8, add 1.0IU / g xylanase substrate (purchased from Novozymes), cellulase 20FPU / g substrate (purchased from Novi The product, β-glucosidase 1CBU / g substrate (purchased from Novozymes), enzymatically digested at 50°C for 48h, and the shaker speed is 100r / min. Add 1% (w / v) activated carbon to 50℃ detoxify the enzymolysis solution for 1h, detoxify the speed at 100rpm, add 1.0% (w / v) corn steep liquor to the clear solution, connect with NCIMB8052 strain, anaerobic culture at 37℃ for 48h, fermentation product Among them, butanol is 9.86g / L, and the total solvent is 11.63g / L.
Embodiment 2
[0038] Weigh 5g of bamboo powder crushed by ultra-fine airflow to a particle size of 1500 mesh, add 40mL, 2% (w / w) sulfuric acid solution (solid-liquid ratio 1:8), react at 170°C for 10 minutes, adjust the pH of the hydrolysate 5.0, add 0.5IU / g substrate of xylanase, 30FPU / g substrate of cellulase, 10IU / g substrate of β-glucosidase, enzymolysis at 50℃ for 48h, and shaker speed 120r / min. Add 1.5% (w / v) activated carbon to detoxify the enzymolysis solution at 60°C for 0.5h, add 0.3%(w / v) ammonium sulfate to the clear solution, shake the rotation speed of 200rpm, connect to the NCIMB8052 strain, and culture at 35°C for 50h. The butanol in the fermentation product is 7.64 g / L, and the total solvent is 9.08 g / L.
Embodiment 3
[0040] Weigh 5g of bamboo powder that has been pulverized to a particle size of 100 mesh, add 60mL, 1.5% (w / w) sulfuric acid solution (solid-liquid ratio 1:12), react at 140°C for 30 minutes, adjust the pH of the hydrolyzate to 4.5, Add xylanase 0.1IU / g substrate, cellulase 30FPU / g substrate, β-glucosidase 10CBU / g substrate, enzymatically digest at 55°C for 45h, and shaker speed at 180r / min. Add 3% (w / v) activated carbon to detoxify the enzymatic hydrolysate at 40°C for 3 hours, add 0.1% (w / v) corn steep liquor to the clear solution, connect with NCIMB8052 strain, and culture at 38°C for 40 hours anaerobic. The fermented product contains 6.33g / L butanol and 8.06g / L total solvent.
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