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Hydrogenation catalyst for C5 petroleum resin, and preparation method and application thereof

A petroleum resin and catalyst technology, which is applied in the field of C5 petroleum resin hydrogenation catalyst and its preparation, to achieve the effects of high low-temperature hydrogenation activity, good resistance to impurities and stability

Active Publication Date: 2013-02-20
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] my country vs. C 5 The research on petroleum resin hydrogenation catalyst started relatively late, and currently domestic C 5 Petroleum resin hydrogenation uses imported palladium catalysts; therefore, there is an urgent need for C 5 Innovative Research on Petroleum Resin Hydrogenation Catalysts

Method used

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  • Hydrogenation catalyst for C5 petroleum resin, and preparation method and application thereof
  • Hydrogenation catalyst for C5 petroleum resin, and preparation method and application thereof
  • Hydrogenation catalyst for C5 petroleum resin, and preparation method and application thereof

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Experimental program
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Effect test

Embodiment 1

[0029] Preparation of the carrier: the specific surface area of ​​180g is 178m 2 / g and clover-shaped alumina with a pore volume of 0.76ml / g was impregnated with 142ml cyclohexane solution containing tetraethyl titanate 1.25g / ml for 4 hours, dried at 110°C for 6 hours, and then dried at 700°C Calcined at high temperature for 5 hours; 240 g of alumina-titania composite carrier was obtained, wherein the weight ratio of alumina and titania was 3:1.

[0030] Preparation of the catalyst: Add 3.44g of nickel nitrate into 5mL of water, stir to dissolve, add 1.31g of magnesium nitrate under stirring, adjust the pH value to 5 with dilute nitric acid, immerse 10g of alumina-titania composite carrier in it for 3 hours, The impregnated composite support was filtered off, dried at 110°C for 6 hours, and calcined at 600°C for 5 hours. 11.76 g of Catalyst 1A were obtained with a specific surface area of ​​156 m 2 / g, the pore volume is 0.58ml / g. The content of nickel oxide is 12% based on...

Embodiment 2

[0033] Preparation of the catalyst: Add 3.54g of nickel nitrate to 5mL of water, stir to dissolve, add 2.24g of magnesium nitrate under stirring, adjust the pH value to 5 with dilute nitric acid, immerse 10g of alumina-titania composite carrier in it for 4 hours, The impregnated composite support was filtered off, dried at 120°C for 5 hours, and calcined at 500°C for 7 hours. 12.1 g of catalyst 1B were obtained with a specific surface area of ​​160 m 2 / g, the pore volume is 0.61ml / g. The content of nickel oxide is 12% based on the weight of the catalyst, and the content of magnesium oxide is 5% based on the weight of the catalyst.

Embodiment 3

[0035] Catalyst preparation: Add 3.62g of nickel nitrate to 5mL of water, stir to dissolve, add 2.03g of copper nitrate under stirring, adjust the pH value to 4 with dilute nitric acid, immerse 10g of alumina-titania composite carrier in it for 4 hours, The impregnated composite support was filtered off, dried at a temperature of 110°C for 6 hours, and calcined at a temperature of 600°C for 6 hours. Obtained 12.35g catalyst 1C, its specific surface area is 162m 2 / g, the pore volume is 0.62ml / g. The content of nickel oxide is 12% based on the weight of the catalyst, and the content of copper oxide is 7% based on the weight of the catalyst.

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Abstract

The invention provides a nickel hydrogenation catalyst for a C5 petroleum resin. The catalyst comprises an alumina-titanium oxide compounded carrier and an active component of nickel oxide and an auxiliary agent of magnesium oxide or copper oxide which are loaded on the compounded carrier. The weight ratio of alumina to titanium oxide in the compounded carrier is 3 : 1 -6 : 1; the content of nickel oxide is 12-18% based on the weight of the catalyst; and the content of magnesium oxide or copper oxide is 3-7% based on the weight of the catalyst. The catalyst has good low temperature hydrogenation activity and good stability in the hydrogenation process of the C5 petroleum resin. The invention also provides a preparation method of the catalyst and an application of the catalyst in catalytic hydrogenation of the C5 petroleum resin.

Description

technical field [0001] The present invention relates to a C 5 A petroleum resin hydrogenation catalyst and a preparation method thereof, in particular to a nickel-based hydrogenation catalyst and a preparation method thereof. Background technique [0002] With the continuous development of my country's petrochemical industry, the production capacity of ethylene is also increasing year by year. C 5 Petroleum resin is a by-product of ethylene plant C 5 The distillate is the main raw material, and it is a solid or viscous polymer with a relatively low molecular weight that is polymerized in the presence of a catalyst, and its average relative molecular weight is generally between 1000-3000. The resin is cheap and has excellent properties such as acid resistance, alkali resistance and aging resistance, so it is widely used in adhesive tapes, hot melt adhesives, road coatings, inks and rubbers. Existing C 5 Petroleum resin is generally reddish-brown, with a softening point o...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J23/755C08F240/00C08F8/04
Inventor 季静柴忠义纪玉国任玉梅杜周
Owner CHINA PETROLEUM & CHEM CORP
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