A rare earth uniformly doped optical fiber preform core rod and its preparation method

An optical fiber preform and uniform doping technology, applied in the field of optical fiber manufacturing, can solve the problem of uneven doping of preforms, fluorine-doped cladding outer cladding technology and rare-earth-doped optical fiber technology have not been realized, and can not meet the requirements of one-rod multi-fiber design and Optical fiber implementation technology requirements and other issues, to achieve the effects of flexible selection, easy control of concentration allocation, and low background absorption loss

Active Publication Date: 2015-09-30
YANGTZE OPTICAL FIBRE & CABLE CO LTD
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] In summary, there are still a series of problems in the commonly used rare earth-doped optical fiber technology. The preform rod technology based on the MCVD method has the problem of inhomogeneity in the radial or axial direction of the preform rod, which cannot meet the requirements of one-rod multi-fiber design and The requirements of optical fiber realization technology; Yb-doped bulk materials prepared by sintering method have not yet successfully realized the preparation of Yb-doped optical fibers with single-mode characteristics, good bending properties, and high laser slope efficiency; prepared by powder sintering method. Yb body material, outer cladding technology and rare earth doped optical fiber technology other than fluorine-doped cladding have not been realized

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  • A rare earth uniformly doped optical fiber preform core rod and its preparation method
  • A rare earth uniformly doped optical fiber preform core rod and its preparation method
  • A rare earth uniformly doped optical fiber preform core rod and its preparation method

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Effect test

Embodiment 1

[0026] Mandrel embodiment 1: Add nanoporous SiO2 powder with a particle size of 10 to 200 nm into the chloride aqueous solution of rare earth and co-doped ions, the ratio of the molar concentration of dopant ions Al3+ to the molar concentration of rare earth ions Yb3+ in the solution is 5 to 6, and then Adjust the pH value of the solution to 10-11 with ammonia water, stir continuously to form a suspension; then perform high-speed centrifugation to separate solid particles and liquids, then dry, dehydrate, and granulate to form ion-adsorbed SiO2 particles; After static pressure molding, Cl2 dehydration and purification are carried out; then in the atmosphere furnace, high-temperature sintering is dense, the sintering temperature is 1500-1600 °C, and the sintering time is 5-20 hours; after that, the surface processing and chemical cleaning are carried out to obtain Cylindrical rare earth doped silicon oxide core rod; finally, a thin layer of SiO2 without rare earth ion doping i...

Embodiment 2

[0027] Mandrel embodiment 2: The nanoporous SiO2 powder with a particle size of 10-200 nm is added to the chloride ethanol solution of rare earth and co-doped ions. The ratio of the molar concentration of dopant ions Al3+ in the solution to the sum of the molar concentrations of rare earth ions Yb3+ and Er3+ is 9 to 12, then adjust the pH value of the solution to 7 to 9 with ammonia water, and continue to stir to form a suspension; then perform high-speed centrifugation to separate solid particles and liquids, then dry, dehydrate, and granulate to form ion-adsorbed SiO2 particles; ion adsorption After the SiO2 particles are formed by isostatic pressing, they are dehydrated and purified by Cl2; then in the atmosphere furnace, they are sintered and dense at high temperature, the sintering temperature is 1200-1600 °C, and the sintering time is 2-10 hours; after that, the surface processing is carried out. and chemical cleaning to obtain a cylindrical rare-earth-doped silicon oxi...

Embodiment 3

[0028] Mandrel embodiment 3: The nanoporous SiO2 powder with a particle size of 10-200 nm is added to the hydrogen phosphate aqueous solution of rare earth and co-doped ions, and the ratio of the sum of the molar concentrations of the dopant ions Al3+ and PO33- to the molar concentration of the rare earth ions Er3+ Adjust the pH value of the solution to 25-30 to 7-8, stir continuously to form a suspension; then perform high-speed centrifugation to separate solid particles and liquids, then dry, dehydrate, and granulate to form ion-adsorbed SiO2 particles; ion-adsorbed SiO2 particles After isostatic pressing, Cl2 dehydration and purification are carried out; then in the atmosphere furnace, high-temperature sintering is dense, the sintering temperature is 1000-1400 °C, and the sintering time is 1-8 hours; after that, the surface processing and chemical cleaning are carried out , to obtain a cylindrical rare-earth-doped silicon oxide core rod; finally, a thin layer of SiO2 witho...

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Abstract

The invention relates to a rare-earth uniformly-doped fiber perform core rod and a preparation method thereof. The core rod adopts silicon dioxide used as a matrix and is at least doped with a rare earth ion and a co-doping ion, wherein the doping concentration of the rare earth element is calculated in the oxide form; the concentration of the doped rare earth oxide is 0.05-0.5mol%; the co-doping ion is at least one of Al and P elements; the co-doping agent concentration is calculated in the oxide form; and the concentration of the co-doping agent oxide is 0.4-10mol%. The core rod is prepared by adopting a powder forming-sintering method. The core rod disclosed by the invention has the advantages that the fiber core has high doping uniformity in the axial direction and the radial direction; the refractive index profile of the fiber core has high flatness; the numerical aperture (NA) of the fiber core is accurate and adjustable; and the optical fiber has high slope efficiency. Based on the rare earth doped core rod, various rare-earth doped optical fibers with different structures can be manufactured by using a core rod through the external cladding technology, i.e., the manufacturing requirements of rare earth doped optical fibers with different structures such as single cladding single mode, double cladding single mode, polarization-maintaining double cladding, large-mode field area air hole double cladding and the like are satisfied.

Description

technical field [0001] The invention relates to a rare earth uniformly doped optical fiber preform core rod and a preparation method thereof, belonging to the technical field of optical fiber manufacturing. Background technique [0002] As early as the early 1970s, people began to study rare earth-doped silica optical fibers (Appl. Phys. Lett., 1973, 23(7): 388-389). Optical fiber preparation technology generally includes preform rod preparation technology and optical fiber design and implementation technology. The same is true for rare earth doped fibers. However, since the rare earth-doped optical fiber has a wide range of application fields, and the functions and application requirements are also different, the preparation of the rare earth-doped optical fiber is more complicated than that. In terms of preform technology, the MCVD method is widely used. In terms of rare earth doping technology, based on the MCVD process, the doping technology includes high-temperature ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C03B37/014
CPCC03B2201/34C03B2203/42C03B2201/28C03B19/06C03B2203/14C03B2203/12C03B2203/22C03B2203/23C03B2203/36C03B19/1085C03B2201/36C03B37/01282C03B2203/30
Inventor 熊良明李江罗杰成煜邓涛韦会峰胡鹏
Owner YANGTZE OPTICAL FIBRE & CABLE CO LTD
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