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Metal complex pigment, photoelectric conversion element and photoelectrochemical cell

A technology for photoelectric conversion elements and metal complexes, applied in electrical components, platinum group organic compounds without C-metal bonds, 1/11 group organic compounds without C-metal bonds, etc., can solve the problem of photoelectric conversion elements. Insufficient and other issues

Inactive Publication Date: 2016-04-27
FUJIFILM CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, in terms of durability, the photoelectric conversion element described in Patent Document 2 is not yet sufficient.

Method used

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  • Metal complex pigment, photoelectric conversion element and photoelectrochemical cell
  • Metal complex pigment, photoelectric conversion element and photoelectrochemical cell
  • Metal complex pigment, photoelectric conversion element and photoelectrochemical cell

Examples

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example

[0333] Hereinafter, the present invention will be described in more detail based on examples, but the present invention is not limited to these examples.

[0334] (preparation of pigment)

[0335] The following YA-1 to YA-10 and XA-23 were prepared as multinuclear metal complex dyes of the present invention, and YB-1 to YB-3 were prepared as comparative dyes.

[0336] [chem 36]

[0337]

[0338] [chem 37]

[0339]

[0340] [chem 38]

[0341]

[0342] [chem 39]

[0343]

[0344] Among them, the production methods of YA-4 and YA-9 are shown.

[0345] 1. Preparation of YA-4

[0346] YA-4a, YA-4b, YA-4c, and YA-4d were sequentially prepared to obtain YA-4. [chemical 40]

[0347]

[0348] (1) Preparation of YA-4a

[0349] Dissolve 3.9 g of B-4a and 2.5 g of B-4b in quinoline, and add 2.4 g of VCl 3 Then, it was stirred at 150° C. for 10 hours. After cooling, water was added and filtered to obtain 6.0 g of YA-4a.

[0350] (2) Preparation of YA-4b

[0351] ...

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Abstract

The present invention relates to a metal complex dye, a photoelectric conversion element and a photoelectrochemical cell. The metal complex dye has a structure defined by the following general formula (1) and has one or two acidic groups. In the general formula (1), A and C have the structure of the general formula (2), and A and C may be the same as or different from each other. B represents a linking group, and n represents an integer of 1 or more. In addition, the bond of A and B and the bond of B and C may each be divalent or more. In addition, a double bond may be contained in order to maintain the resonance structure of the compound.

Description

technical field [0001] The invention relates to a metal complex pigment with high conversion efficiency and excellent durability, a photoelectric conversion element and a photoelectrochemical cell. Background technique [0002] Photoelectric conversion elements are used in various optical sensors, copiers, solar cells, and the like. Among the photoelectric conversion elements, various forms such as photoelectric conversion elements using metals, photoelectric conversion elements using semiconductors, photoelectric conversion elements using organic pigments or dyes, or combinations thereof have been put into practical use. Among them, solar cells using non-exhaustible solar energy are highly anticipated for their true practical use as inexhaustible clean energy sources that do not require fuel. Among them, research and development of silicon-based solar cells has been conducted for a long time. It is also being popularized with the policy considerations of various countries...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09B47/06H01G9/20H01L51/00
CPCC09B47/0673C09B47/0678H01G9/2013H01G9/2031H01G9/2059C07F15/0013C07F1/005C07F3/003C07F5/003C07F7/003C07F9/005Y02E10/542H10K85/311
Inventor 佐藤宽敬薄达也小林克木村桂三
Owner FUJIFILM CORP
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