Reducibility solidification stabilization method of processing soil polluted by toxic organics
A technology of stabilization treatment and organic matter, applied in the restoration of polluted soil, etc., can solve the problems of potential environmental damage, inability to destroy and remove pollutants, etc., and achieve the effect of strong adaptability and simple operation.
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Embodiment 1
[0022] (1) Determination of the concentration of toxic organic substances in polluted soil;
[0023] (2) Add ferrous salt equivalent to 2-3 times the mass of toxic organic substances to the soil polluted by toxic organic substances, and water 2-2.5 times the mass of the polluted soil, and turn on the agitator to stir for 40-60 minutes;
[0024] (3) After an interval of 5-24 hours, add the inorganic binder curing agent according to the mass ratio of the inorganic binder curing agent to the soil polluted by toxic organic substances at a ratio of 1: (1-1.5), and stir again for 5-10 minutes to make the material well mixed;
[0025] (4) After the above-mentioned mixed materials are formed through the molding process, the solidified blocks with regular shapes are stacked in situ or put into the landfill, so as to complete the reductive solidification and stabilization of the soil polluted by toxic organic substances.
[0026] The working reducing agent involved in the method provid...
Embodiment 2
[0032] Prepare soil contaminated with trichlorethylene (PCE) at a concentration of 293 mg / kg; add ferrous sulfate solution with ferrous iron content equivalent to 3 times the mass of PCE to the above soil, and keep the water-to-soil mass ratio at 1.5:1. Stir at 50°C for 60 minutes; test results: PCE 134.2 mg / kg, the product is low-toxic dichlorethylene; add Portland cement after 24 hours, the amount is 2 / 3 of the soil mass, and stir again for 10 minutes. Test results: PCE 120.2 mg / kg, the product is low-toxic dichlorethylene. After curing for 1d, 5d, 10d, and 20d, the curing / stabilization rates of PCE were 94.08%, 96.75%, 99.26%, and 99.28%, respectively.
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