Polymeric composition and sealant layer with same
A technology of polymers and compositions, applied in synthetic resin layered products, layered products, transportation and packaging, etc., can solve the problems of unqualified products, increased costs, waste generation, etc., achieve low heat sealing initiation temperature, improve heat The effect of sealing properties, high hot tack strength
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[0211] 1. Polymer composition
[0212] The block composite, component (C), was prepared as described at pages 82-91 of co-pending US Patent Application 61 / 248,160, filed October 2, 2009, which is incorporated herein by reference in its entirety.
[0213] The polymerization conditions used to produce block composite Examples 02, 03 and 14 are provided in Table 3 below. The physical properties of the resulting block composites 02, 03 and 14 are provided in Table 4.
[0214] The catalyst system includes the catalyst ([[rel-2',2'''-[(1R,2R)-1,2-cyclohexanediylbis(methyleneoxy-κO)]bis[3-(9H -carbazol-9-yl)-5-methyl[1,1'-biphenyl]-2-olato-κO]](2-)]dimethyl-hafnium) and cocatalyst, tetrakis(pentafluorobenzene base) methyl di(C of boronic acid 14-18 Alkyl) ammonium salt mixture, by long chain trialkylamine (Armeen TM M2HT, available from Akzo-Nobel, Inc.), HCl and Li[B(C 6 f 5 ) 4 ] was prepared by reaction, basically as disclosed in Example 2 of USP5,919,9883, purchased from B...
Embodiment 02、03 and 14
[0219] Each block composite example 02, 03 and 14 contains
[0220] (i) crystalline isotactic propylene homopolymer (iPP);
[0221] (ii) ethylene / propylene polymers (EP); and
[0222] (iii) Block copolymers (diblocks) comprising iPP-blocks and EP-blocks.
[0223] Table 4 provides a summary of the analysis of block composite Examples 02, 03 and 14. Properties in Table 4 are for block composite (C) unless otherwise stated.
[0224] Table 4 Analytical Summary of Block Composites, Component (C) - Examples
[0225]
[0226] 2. Membrane
[0227] A polymer composition comprising (A) propylene / α-olefin interpolymer, (B) ethylene-based polymer, and (C) block composite was coextruded into a film structure. Components (A), (B) and (C) were dry blended before being added to the feed hopper of the extruder.
[0228] Three-layer coextruded films were produced using a Colin Extrusion Blown Film Line with three extruders. Film production conditions are shown in Table 5 below. Nylon...
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