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A kind of carbon nanotube conductive paste and preparation method thereof

A carbon nanotube and conductive paste technology, applied in the field of electrochemical materials, can solve the problems of truncated carbon nanotubes, low efficiency, poor dispersion effect, etc., and achieve the effects of stable and uniform properties, excellent electrical conductivity and stable performance

Inactive Publication Date: 2016-04-27
FUDAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although chemical methods such as strong oxidizing acid treatment methods can obtain carbon nanotubes with good dispersion properties, strong acids will also destroy the structure of carbon nanotubes and shorten carbon nanotubes, thereby affecting the conductivity of carbon nanotubes and their use as electrical conductors. agent performance
Physical methods such as the use of more ultrasonic treatment methods have low efficiency, poor dispersion effect, and stability, and the concentration of the obtained carbon nanotube dispersion is lower than 5mg / mL, so it is difficult to prepare carbon nanotube dispersion slurry on a large scale

Method used

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  • A kind of carbon nanotube conductive paste and preparation method thereof
  • A kind of carbon nanotube conductive paste and preparation method thereof
  • A kind of carbon nanotube conductive paste and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] Example 1: 9.25kg of N-methylpyrrolidone was added into a 20-liter container as a solvent carrier, and 0.15kg of polyvinylpyrrolidone was added thereto as an auxiliary agent. Fully dissolve the polyvinylpyrrolidone in the N-methylpyrrolidone under the mechanical stirring condition of 6000rpm. Then, 0.6 kg of multi-walled carbon nanotubes are added in batches to the solution, and the rest of the carbon nanotubes are added after the added solid powder is fully wetted by the solvent. After all the additions were completed, mechanical stirring was continued for 15 minutes to obtain a pre-dispersed slurry. The carbon nanotube pre-dispersed slurry was transferred to a nano sand mill, and zirconia balls with a diameter of 1 mm were used to grind at 2400 rpm for 2 hours to obtain the carbon nanotube slurry.

[0026] Carbon nanotube pre-dispersion slurry and hourly grinding slurry are coated on glass slides and dried. The photo is as follows image 3 shown. The stability of t...

Embodiment 2

[0027] Example 2: 9.4kg of water was added into a 20-liter container as a solvent carrier, and 0.1kg of hydroxymethylcellulose was added thereto as an auxiliary agent. Fully dissolve the hydroxymethylcellulose in water under the condition of 5000rpm mechanical stirring. Then add 0.17kg Super-p nano-acetylene black conductive agent and 0.33kg single-walled carbon nanotubes to the solution in batches, and then add the rest of the composite conductive agent after the added solid powder is fully wetted by the solvent. After all the additions were completed, mechanical stirring was continued for 15 minutes to obtain a pre-dispersed slurry. The carbon nanotube pre-dispersed slurry was transferred to a sand mill, and zirconia balls with a diameter of 0.3 mm were used to grind at 1800 rpm for 5 hours to obtain a carbon nanotube composite conductive slurry.

Embodiment 3

[0028] Example 3: 9.4 kg of deionized water was weighed in a 20-liter container as a solvent carrier, and 0.1 kg of polyvinylpyrrolidone was added therein as an auxiliary agent. Fully dissolve the polyvinylpyrrolidone in water under the condition of 3000rpm mechanical stirring. Then add 0.5 kg of multi-walled carbon nanotubes in batches to the solution, and add the rest of the carbon nanotubes after the added solid powder is fully wetted by the solvent. After all the additions were completed, mechanical stirring was continued for 15 minutes to obtain a pre-dispersed slurry. The carbon nanotube pre-dispersed slurry was transferred to a sand mill, and zirconia balls with a diameter of 0.6 mm were used to grind at 1500 rpm for 0.5 hour to obtain a carbon nanotube composite conductive slurry.

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Abstract

The invention belongs to the technical field of electrochemical materials, and particularly relates to carbon nanotube conductive slurry and a method for preparing the carbon nanotube conductive slurry. The carbon nanotube conductive slurry is mainly composed of carbon nanotubes, other conductive fillers, dispersing auxiliaries and a solvent, and the carbon nanotube conductive slurry comprises the components, by mass, 0.5-15% of the carbon nanotubes, 0.1-2% of the other conductive substances, 0.1-5% of the dispersing auxiliaries and the balance being solvent. The method for preparing the carbon nanotube conductive slurry includes the steps that firstly the dispersing auxiliaries are dissolved in the solvent, then, the carbon nanotubes and the other conductive fillers are added under the stirring condition, after the carbon nanotubes and the other conductive fillers are fully immersed, a sand mill is utilized to grind the slurry, and the stable and dispersing carbon nanotube conductive slurry can be obtained after the slurry is grinded for a few hours. The method is simple and free of damaging the structures and the electrical conductivity of the carbon nanotubes, the prepared carbon nanotube conductive slurry has good electrical conductivity and is stable and uniform in property, and the stability of the slurry is larger than 90% after standing for 3 months.

Description

technical field [0001] The invention belongs to the technical field of electrochemical materials, and in particular relates to a carbon nanotube conductive slurry and a preparation method thereof. The material can be used as a conductive agent in the positive or negative electrodes of lithium-ion secondary batteries and capacitors. Background technique [0002] In the preparation process of lithium-ion secondary batteries and capacitors, it is often necessary to add a certain amount of conductive agent to the positive and negative electrode ingredients. The conductive agent can effectively contact with the positive and negative active materials to form a good conductive network, thereby improving the rate performance of the battery. However, adding too much conductive agent will inevitably reduce the content of electrode active materials and reduce the capacity and energy density of the battery. For high-performance electronic devices, it is particularly important to choose...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01B1/24H01B13/00
Inventor 胡建华杨东张晓鸿王淞旸李瀚文李金阳
Owner FUDAN UNIV
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