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A kind of etchant for displaying intergranular cracks of continuous casting billet and preparation method thereof

An intergranular crack and etchant technology is applied in the field of etchant for displaying intergranular cracks in continuous casting billets and its preparation, which can solve the problem of not being able to display silicon steel completely and clearly, and achieve the effects of clear expansion pattern, easy operation and wide applicability.

Active Publication Date: 2015-10-07
ANGANG STEEL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Solve the problem that the general acid etching and other methods cannot completely and clearly display the shape of the columnar grain area and the triangular grain area of ​​the continuous casting billet such as silicon steel.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] It is used to show the intergranular crack morphology of silicon steel continuous casting slabs containing C 0.04%; Si 1.45; Mn 0.65%; Cr 0.033%; Nb 0.01%; Ti 0.015%.

[0021] Take 3 grams of picric acid and add it to 1000 ml of distilled water, add 500 ml of absolute ethanol to the aqueous solution of picric acid, and then add 150 ml of hydrochloric acid to the aqueous solution of picric acid in absolute ethanol. Take another 1000 ml of distilled water, add 40 ml of nitric acid, slowly pour the aqueous solution of nitric acid into the aqueous solution of picric acid anhydrous ethanol hydrochloric acid and mix well. Take 20 milliliters of sodium alkylbenzene sulfonate and add it to the mixed solvent, and stir thoroughly to form the cold acid etching solution 1 of the present invention.

[0022] Wipe the surface of the sample with cotton wool dipped in corrosion solution 1, and corrode for 3-5 minutes evenly. When the cracks at the grain boundaries on the test surface ar...

Embodiment 2

[0024] Used to display C 0.0026%; Si 1.26%; Mn 0.52%; Cr 0.015%; Nb 0.004%;

[0025] Ti 0.016%; V0.004% silicon steel continuous casting slab intergranular crack morphology.

[0026] Take 4 grams of picric acid and add it to 1000 ml of distilled water, add 600 ml of absolute ethanol to the aqueous solution of picric acid, and then add 180 ml of salt to the aqueous solution of picric acid in absolute ethanol. Take another 1000 ml of distilled water, add 50 ml of nitric acid, slowly pour the nitric acid aqueous solution into the picric acid anhydrous ethanol hydrochloric acid aqueous solution and mix evenly. Take 20 milliliters of sodium alkylbenzene sulfonate and add it to the mixed solvent, and stir thoroughly to form the cold acid etching solution 2 of the present invention.

[0027] Wipe the surface of the sample with cotton wool dipped in corrosion solution 2, and corrode for 3-5 minutes evenly. When the cracks at the grain boundaries on the test surface are clearly observ...

Embodiment 3

[0029] It is used to display the intergranular crack morphology of low-alloy high-strength steel continuous casting slabs containing C 0.003%; Si 0.03-0.05%; Mn 0.18%; Ti 0.1%.

[0030] Take 4 grams of picric acid and add it to 1000 ml of distilled water, add 800 ml of absolute ethanol to the aqueous solution of picric acid, and then add 200 ml of salt to the aqueous solution of picric acid in absolute ethanol. Take another 1000 ml of distilled water, add 60 ml of nitric acid, slowly pour the nitric acid aqueous solution into the picric acid anhydrous ethanol hydrochloric acid aqueous solution and mix evenly. Take 20 milliliters of sodium alkylbenzene sulfonate and add it to the mixed solvent, and stir thoroughly to form the cold acid etching solution 3 of the present invention.

[0031] Wipe the surface of the sample with cotton wool dipped in corrosion solution 3, and corrode evenly for 5-7 minutes. When the cracks at the grain boundaries on the test surface are clearly obse...

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PUM

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Abstract

The invention discloses a corrosion agent for displaying intercrystalline crack defects of a continuous casting steel billet, and the corrosion agent comprises the following chemical compositions: 3-4g of picric acid; 10-20ml of sodium alkyl benzene sulfonate, 500-800ml of absolute ethyl alcohol, 150-300ml of hydrochloric acid and 40-60ml of nitric acid. A preparation method of the corrosion agent is as follows: the quantitative solid picric acid medicament is put in a glass container, 2000ml of the distilled water is taken and divided into two parts, one part is added to the solid picric acid medicament, the absolute ethyl alcohol is added into the picric acid aqueous solution, then the hydrochloric acid is added into the picric acid solution; a specified amount of the nitric acid is added to the ready distilled water, the nitric acid aqueous solution is poured into the aqueous solution of the picric acid and the hydrochloric acid for mixing and evenly stirring, finally, the quantitative sodium alkyl benzene sulfonate is poured into the previously prepared solution for fully stirring. The corrosion agent has the characteristics of safety, reliability, easy storage, rapid corrosion speed, less pollution, energy saving, convenient operation and the like, and has wide applicability to silicon steel, niobium, vanadium and titanium microalloyed steel.

Description

technical field [0001] The patent of the invention relates to the field of material inspection in the field of metallurgical analysis, in particular to a corrosive agent for displaying intergranular cracks in continuous casting slabs and a preparation method thereof. Background technique [0002] The inspection methods for low-magnification structural defects of continuous casting billet mainly include hot acid etching method, cold acid etching method, sulfur printing inspection method, and dendritic corrosion method. These methods show their own characteristics in practical application. The hot acid etching method has strong corrosion ability and is used to display the low-magnification structural defects of steel. Because it is heated and corroded by strong acid aqueous solution, the defects are completely exposed, but another effect of strong corrosion It is to etch away the edges of small defects, coarsen the cracks, destroy the expansion form, and the acid mist will ser...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): G01N1/32C23F1/28
Inventor 隋晓红张鹏远李平高玉明
Owner ANGANG STEEL CO LTD