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Iron-rich nickel slag glass-ceramic and preparation method

A technology of iron-rich nickel slag and glass ceramics, which is applied in the field of iron-rich nickel slag glass ceramics and its preparation, can solve the problems of high cost and high energy consumption of glass ceramics, and achieve good flexural strength, corrosion resistance, The effect of good physical properties and simple process flow

Inactive Publication Date: 2016-03-30
WUHAN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there is a process of iron removal in this process, which requires an additional reduction furnace, which consumes a lot of energy. In addition, the glass-ceramic corresponding to this method uses relatively expensive Cr in the melting process. 2 o 3 、TiO 2 As a crystal nucleating agent, the cost of glass-ceramic is higher

Method used

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  • Iron-rich nickel slag glass-ceramic and preparation method
  • Iron-rich nickel slag glass-ceramic and preparation method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] 1. A kind of iron-rich nickel slag glass-ceramics:

[0036] The composition of the iron-rich nickel slag glass ceramics: nickel slag 90.27±0.02wt%, KNO 3 2.11±0.01wt%, Sb 2 o 3 7.62±0.01wt%, the crystallization temperature is 860°C, and the crystallization time is 10min. The flexural strength, acid resistance, alkali resistance, density, water absorption, etc. of the iron-nickel slag glass-ceramics were tested respectively, and compared with the national standard.

[0037] See Sample 1 in Attached Table 1 for specific results.

[0038] It can be seen from Table 1 that the iron-rich nickel slag glass-ceramics has good corrosion resistance, especially alkali resistance, and the quality change is small after being corroded by acid-base solution for 24 hours; the flexural strength has reached 56.87MPa, and all indicators meet the requirements of the national standard .

[0039] 2. Preparation of the above-mentioned iron-rich nickel slag glass-ceramics:

[0040] 1) Wei...

Embodiment 2

[0044] 1. A kind of iron-rich nickel slag glass-ceramics:

[0045] The composition of the iron-rich nickel slag glass ceramics: nickel slag 90.27±0.02wt%, KNO 3 2.11±0.01wt%, Sb 2 o 37.62±0.01wt%, the crystallization temperature is 860°C, and the crystallization time is 20min. The flexural strength, acid resistance, alkali resistance, density, water absorption, etc. of the iron-nickel slag glass-ceramics were tested respectively, and compared with the national standard. See sample 2 in Table 1 for specific results.

[0046] It can be seen from Table 1 that the iron-rich nickel slag glass-ceramics has good corrosion resistance, and the quality change is small after being corroded by NaOH and HCl solutions for 24 hours; the flexural strength is as high as 65.87MPa, far greater than the 30MPa required by the national standard, and all indicators meet the national standard Require.

[0047] 2. Preparation of the above-mentioned iron-rich nickel slag glass-ceramics:

[0048] ...

Embodiment 3

[0050] 1. A kind of iron-rich nickel slag glass-ceramics:

[0051] The composition of the iron-rich nickel slag glass ceramics: nickel slag 90.27±0.02wt%, KNO 3 2.11±0.01wt%, Sb 2 o 3 7.62±0.01wt%, the crystallization temperature is 860°C, and the crystallization time is 30min. The flexural strength, acid resistance, alkali resistance, density, water absorption, etc. of the iron-nickel slag glass-ceramics were tested respectively, and compared with the national standard. See sample 3 in the attached table for specific results.

[0052] It can be seen from Table 1 that the iron-nickel slag glass-ceramics has good corrosion resistance and excellent mechanical properties, and the quality basically does not change after 24 hours of corrosion; the flexural strength is as high as 69.84MPa, and all indicators meet the requirements of the national standard.

[0053] 2. Preparation of the above-mentioned iron-rich nickel slag glass-ceramics:

[0054] Its melting method is substant...

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Abstract

The invention discloses microcrystalline glass rich in iron-nickel slag. The microcrystalline glass consists of the following components in percentage by weight: 90.27+ / -0.02% of nickel slag, 2.11+ / -0.01% of KNO3 and 7.62+ / -0.01% of Sb2O3. The invention also provides a preparation method of the microcrystalline glass rich in iron-nickel slag. According to the preparation method, the nickel slag does not need to be reduced for iron removal, and only a certain mount of oxidant and clarifying agent are needed to be additionally added to perform high-temperature melting so as to obtain base glass. The preparation method provided by the invention has the advantages that the utilization ratio of the nickel slag which serves as an industrial waste is high, the prepared microcrystalline glass rich in iron-nickel slag is good in physical property and corrosion resistance, the preparation process is simple and the like.

Description

technical field [0001] The invention belongs to the field of glass-ceramic materials, and in particular relates to an iron-nickel slag glass-ceramic and a preparation method thereof. Background technique [0002] Nickel slag is a kind of industrial waste produced during the metal nickel smelting process. The annual output of nickel slag in my country has reached 5 million tons, and the accumulated nickel slag has reached more than 40 million tons, but the comprehensive utilization rate of nickel slag is only 15% to 25%. Due to the lack of reasonable utilization methods, the discarded nickel slag occupies a large amount of land and has a negative impact on the environment. Therefore, how to utilize nickel slag efficiently and highly has become a problem urgently needed to be solved by current major nickel ore smelting enterprises. [0003] At present, there are three main treatment methods for nickel slag: [0004] 1) Extract Ni, Co, Cu and other elements from nickel slag....

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C03C6/10C03C10/04
Inventor 赵青林万利康俊峰张玉琳
Owner WUHAN UNIV OF TECH