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Method and device for realizing optimal modulation factor of multi-gas spectral line detection

A technology of modulation coefficient and realization method, applied in the measurement of gas concentration, pressure or flow velocity, and temperature field, can solve the problems of inability to take into account spectral line parameters, multi-gas spectral line sensitivity and low accuracy, and achieve the effect of improving accuracy

Inactive Publication Date: 2014-03-05
TIANJIN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, the existing signal generator and TDLAS system composition method are realized by superposition of the sawtooth wave and sine wave respectively generated by the signal generator, and a certain fixed sine wave amplitude is adopted. In one sawtooth wave scanning cycle, all the signals cannot be considered. Spectral line parameters, resulting in low sensitivity and precision of multi-gas spectral line detection

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  • Method and device for realizing optimal modulation factor of multi-gas spectral line detection
  • Method and device for realizing optimal modulation factor of multi-gas spectral line detection
  • Method and device for realizing optimal modulation factor of multi-gas spectral line detection

Examples

Experimental program
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Effect test

Embodiment 1

[0055] Example 1: (measure the concentration of three gases near 1580nm)

[0056] In the wavelength range of 1580.5nm ~ 1581.0nm, CO can be measured 2 , CO, C 2 h 2 For the three gases, the parameters of the absorption lines can be obtained from the HITRAN database. Using DFB laser, the concentration of these three gases can be covered and measured in one wavelength scan period. However, the three spectral lines to be measured have different spectral line parameters, as shown in Table 1.

[0057] Table 1.CO 2 , CO, C 2 h 2 The parameters of the absorption line around 1580nm (T=296K, P=1atm, x CO2 =x CO =x C2H2 =1%, 97% air)

[0058] serial number

gas molecule

Spectral line wavelength / nm

Absorption line strength / cm / molecule

Spectral line width / nm

[0059] 1.

CO 2

1580.993

1.13E-23

0.0359

2.

CO

1580.828

1.57E-23

0.0319

3.

C 2 h 2

1581.129

9.08E-25

0.0385

...

Embodiment 2

[0070] Example 2: (1.395um temperature measurement, open optical path)

[0071] Measure temperature by measuring multiple absorption lines of water molecules, H around 1395.6nm 2 The absorption spectrum parameters of O can be obtained from the HITRAN database, as shown in Table 2. Using a DFB laser, one wavelength scan cycle can cover two H2O absorption lines. However, since the two spectral lines to be measured have different spectral line widths, they are:

[0072] Table 2.H 2 The parameters of the absorption line of O around 1395.6nm (T=296K, P=1atm, x H2O =10%, 90% air)

[0073] serial number

Spectral line wavelength / nm

wave number / cm -1

Absorption line strength / cm / molecule

Spectral line width / nm

1.

1395.693

7164.90

1.47E-22

0.0202

2.

1395.514

7165.82

5.93E-21

0.0505

[0074] The use of DFB lasers can cover these two spectral lines within a wavelength scanning period. In the current existi...

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Abstract

The invention belongs to the technical field of gas concentration, temperature, pressure or flow viscosity, and particularly relates to a method and a device which are capable of meeting multi-gas spectral line detection and enables each spectral line to realize optimal detection. The detection sensitivity of concentrations, pressures, temperatures or flow velocities of multiple gases of a TDLAS (Tunable Diode Laser Absorption Spectroscopy) system can be improved. The method and the device are suitable for online, in situ or offline detection or monitoring application of trace gases. Thus, according to the technical scheme of the invention, the method for realizing an optimal modulation factor of multi-gas spectral line detection comprises the steps: detecting absorption spectral lines of gases to laser, and measuring parameters of the gases, including concentrations, pressures, temperatures and flow velocities, wherein in a scanning period of laser wavelength, a wavelength modulation coefficient of the laser is variable, namely, two or more sine wave amplitudes are adopted in the one scanning period. The method and device are mainly applied to gas detection.

Description

technical field [0001] The invention belongs to the technical field of gas concentration, temperature, pressure or flow rate measurement, and relates to the simultaneous detection of multiple gas components or the simultaneous detection of multiple absorption lines of a single gas. By optimizing the modulation coefficients of all spectral lines to be measured, A method and device for improving the sensitivity of multi-gas spectral line detection, specifically, a method and device for realizing the optimal modulation coefficient of multi-gas spectral line detection. Background technique [0002] Tunable diode laser absorption spectroscopy (TDLAS) is a gas detection technology with high sensitivity, high resolution and fast response, which is widely used in gas monitoring in industrial processes, environmental atmospheric detection and scientific research, etc. field. It uses the wavelength tuning characteristics of diode lasers, that is, the output wavelength of the laser ca...

Claims

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Application Information

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IPC IPC(8): G01N21/39
Inventor 杜振辉李金义刘翰蔚
Owner TIANJIN UNIV