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Multilayer adhesive article and adhesive sheet

An adhesive and article technology, applied in the direction of layered products, adhesive types, ester copolymer adhesives, etc., can solve the problems of easy peeling and weak bonding, and achieve the effect of inhibiting interlayer peeling

Inactive Publication Date: 2014-03-12
NITTO DENKO CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] However, the pressure-sensitive adhesive tape in which the adhesive layer is formed into a multilayer structure as described above has the following disadvantages: the bonding force between the layers is weak, and the layers are easily peeled off due to external stress such as shear force.

Method used

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  • Multilayer adhesive article and adhesive sheet
  • Multilayer adhesive article and adhesive sheet
  • Multilayer adhesive article and adhesive sheet

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1-1

[0230] (Synthesis of Acrylic Polymer (a))

[0231] Put 229 parts of ethyl acetate, 0.2 parts of azobisisobutyronitrile, 95 parts of n-butyl acrylate and 5 parts of acrylic acid into a reactor with a thermometer, a stirrer, a nitrogen gas inlet tube and a reflux condenser tube, and carry out at 60 ° C. Solution polymerization was carried out to obtain an acrylic polymer solution A having a concentration of the acrylic polymer (a) of 30% by weight. The weight average molecular weight of the said acrylic polymer (a) was 750,000.

[0232] (Synthesis of Acrylic Polymer (b))

[0233] In the reactor with thermometer, stirrer, nitrogen inlet pipe and reflux condenser, drop 146 parts of ethyl acetate, 0.2 part of azobisisobutyronitrile, 95 parts of 2-ethylhexyl acrylate and 5 parts of acrylic acid, Solution polymerization was performed at 60° C. to obtain an acrylic polymer solution B having a concentration of the acrylic polymer (b) of 40% by weight. The weight average molecular we...

Embodiment 1-2～1-14

[0240] [Examples 1-2 to 1-14, Comparative Example 1-1]

[0241] The types and amounts of the monomers used in the synthesis of the acrylic polymers (a) to (c), the amount of the crosslinking agent, and the thickness of each adhesive layer were changed to the values ​​described in Table 1 and Table 2 , except that, the same operation as in Example 1-1 was carried out, and each pressure-sensitive adhesive tape was produced.

Embodiment 1-15

[0243] (Synthesis of Acrylic Polymer (a))

[0244] Put 229 parts of ethyl acetate, 0.2 parts of azobisisobutyronitrile, 95 parts of n-butyl acrylate and 5 parts of acrylic acid into a reactor with a thermometer, a stirrer, a nitrogen gas inlet tube and a reflux condenser tube, and carry out at 60 ° C. Solution polymerization was carried out to obtain an acrylic polymer solution A having a concentration of the acrylic polymer (a) of 30% by weight. The weight average molecular weight of the said acrylic polymer (a) was 750,000.

[0245] (Synthesis of Acrylic Polymer (b))

[0246] In the reactor with thermometer, stirrer, nitrogen inlet pipe and reflux condenser, drop 146 parts of ethyl acetate, 0.2 part of azobisisobutyronitrile, 95 parts of 2-ethylhexyl acrylate and 5 parts of acrylic acid, Solution polymerization was performed at 60° C. to obtain an acrylic polymer solution B having a concentration of the acrylic polymer (b) of 40% by weight. The weight average molecular we...

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PUM

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Abstract

A multilayer adhesive article with a higher interlayer adhesive strength is provided. This multilayer adhesive article is provided with: an adhesive layer (A) formed from an adhesive composition (a) containing, as the main component, an acrylic polymer (a); an adhesive layer (B) formed from an adhesive composition (b) that contains, as the main component, an acrylic polymer (b); and an intermediate layer (C) that is positioned between the adhesive layer (A) and the adhesive layer (B). The adhesive composition (a) and the adhesive composition (b) each further contain a compound having two or more functional groups capable of reacting with active hydrogen in a molecule. The intermediate layer (C) is formed from an intermediate layer composition (c) that contains a polymer (c) obtained by polymerizing a monomer composition (c) that includes a monomer containing active hydrogen.

Description

technical field [0001] The present invention relates to a multilayer adhesive article and an adhesive sheet obtained by forming the multilayer adhesive article into a sheet shape. This application claims priority based on Japanese Patent Application No. 2011-147390 filed on July 1, 2011 and Japanese Patent Application No. 2011-147445 filed on July 1, 2011, the entire contents of which are incorporated herein by reference middle. Background technique [0002] Conventionally, pressure-sensitive adhesive tapes such as double-sided adhesive tapes have been required to have contradictory properties such as high wettability to adherends, adhesiveness, and high cohesion at the same time. In addition, when bonding two adherends with different surface properties, it is difficult for a pressure-sensitive adhesive composed of the same composition to exert good adhesive properties on either of the two adherends. It is handled in a balanced way between the characteristics. [0003] In...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J7/02B32B27/00B32B27/30C09J133/00C09J7/38C09J7/22C09J7/24
CPCB32B27/308C09J133/00B32B27/00C09J7/0217C09J7/0267B32B7/12B32B27/30C09J7/0246C09J133/14C09J2201/134C09J2433/006C09J7/02C09J2433/00C09J7/38C09J7/22C09J7/24Y10T428/2848C09J2301/1242
Inventor 白井光义船津绘里子每川英利
Owner NITTO DENKO CORP