A kind of composite ceramic diaphragm for lithium ion battery and preparation method thereof
A technology of lithium-ion batteries and composite ceramics, which is applied to battery components, circuits, electrical components, etc., can solve the problems of reducing ceramic grafting rate, reducing reaction rate, low grafting rate, etc., and can improve high temperature thermal stability , Improve grafting efficiency, improve cycle performance
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
preparation example Construction
[0049] A preparation method for a ceramic diaphragm for a lithium-ion battery, comprising the steps of:
[0050](1) Ceramic surface grafting modification: Under the action of appropriate solvent and dehydrating agent, weakly acidic or neutral ceramic powder (mainly nanometer or submicron oxide powder, such as Al 2 o 3 , SiO 2 、TiO 2 , ferrite and other oxides) and organic monomers or polymers with active hydroxyl, carboxyl sodium sulfonate or sodium carboxylate groups in the side chain or end group, under the action of a dehydrating agent, the "grafting to" method is obtained. Branched ceramic powder; or organic monomers with no active groups in the side chains, under the action of coupling agents, polymerize on the surface of ceramics through the "grafting on" method to achieve the purpose of grafting and modifying ceramics, and The grafted ceramic powder is washed to obtain the grafted modified ceramic powder.
[0051] The dehydrating agent is mainly N, N-dicyclohexylcar...
Embodiment 1
[0061] A preparation method for a lithium-ion battery composite diaphragm, comprising the steps of:
[0062] a. Ceramic surface graft modification
[0063] The graft monomer structure is as follows:
[0064]
[0065] Add 10 g of submicron aluminum oxide powder (ceramic powder), 5-40 g of sodium isethionate (SHES), preferably 10-20 g, and 2 g of N,N-bicyclo Hexylcarbodiimide (DCC), HMPS and DCC need to be dissolved in 300 mL isopropanol in advance. N 2 Heat and reflux in a water bath under atmosphere for 4-6 hours to carry out the grafting reaction. After the grafting reaction is completed, the product is centrifugally washed with ethanol and acetone for 3 to 4 times, and then vacuum-dried to constant weight to obtain the grafted modified ceramic Al 2 o 3 .
[0066] b. Preparation of ceramic coating slurry
[0067] Mix the mixed solvent composed of sodium isethionate (SHES) modified ceramics, binder sodium polyacrylate, ethanol and water in a mass ratio of 6:1:5 in a ...
Embodiment 2
[0071] a. Ceramic surface graft modification
[0072] The graft monomer structure is as follows:
[0073]
[0074] Add 10 g of submicron aluminum oxide powder (ceramic powder), 5-40 g of hydroxypropyl sodium methacrylate (HMPS) (preferably 10-20 g) and 2 g of N into the three-necked flask, N-dicyclohexylcarbodiimide (DCC), HMPS and DCC need to be dissolved in 300 mL isopropanol in advance. N 2 Heat and reflux in a water bath under atmosphere for 4-6 hours to carry out the grafting reaction. After the grafting reaction is completed, the product is centrifugally washed with ethanol and acetone for 3 to 4 times, and then vacuum-dried to constant weight to obtain the grafted modified ceramic Al 2 o 3 .
[0075] b. Preparation of ceramic coating slurry
[0076] Stir and mix the mixed solvent composed of hydroxypropyl sodium methacrylate (HMPS) modified ceramics, binder sodium polyacrylate, ethanol and water at a mass ratio of 6:3:20 in a stirring tank or a ball milling tan...
PUM
Property | Measurement | Unit |
---|---|---|
melting point | aaaaa | aaaaa |
thickness | aaaaa | aaaaa |
thickness | aaaaa | aaaaa |
Abstract
Description
Claims
Application Information
- R&D Engineer
- R&D Manager
- IP Professional
- Industry Leading Data Capabilities
- Powerful AI technology
- Patent DNA Extraction
Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.
© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com