Adhensive sheet
An adhesive sheet and adhesive layer technology, applied in the direction of adhesives, film/sheet adhesives, etc., can solve the problems of easy intrusion into adhesive sheets and semiconductor wafers, contamination of semiconductor wafers, etc.
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Embodiment 1
[0072] As a material for forming the adhesive layer, an amorphous propylene-(1-butene) copolymer (manufactured by Sumitomo Chemical Co., Ltd., trade name "TAFTHREN H5002", propylene-derived structural unit 90) polymerized with a metallocene catalyst was used. mol% / constituent unit derived from 1-butene 10 mol%, Mw=230000, Mw / Mn=1.8) 80 parts and a propylene-ethylene copolymer polymerized using a metallocene catalyst (manufactured by Nippon Polypropylene Co., Ltd., commercial product Name "WINTEC WFX4", 96 mol% of structural units derived from propylene / 4 mol% of structural units derived from ethylene, melting point: 125°C, softening point: 115°C) 20 parts of mixture. The mixture of amorphous propylene-(1-butene) copolymer and polypropylene-ethylene copolymer is supplied from a single hopper to the extruder by feeding the mixture of resin pellets blended in a pellet state, and is molded by melt extrusion When making it mixed method to carry out.
[0073] As the intermediate la...
Embodiment 2~12
[0076] [Examples 2-12, Comparative Examples 1-7, Reference Example 1]
[0077] The resin constituting the resin layer, the resin constituting the intermediate layer, the film forming speed in co-extrusion molding, and the temperature of the touch roll in co-extrusion molding were set as shown in Table 1. In addition, the same as in Examples 1 in the same manner to obtain an adhesive sheet.
[0078] In addition, the details of the resin described in Table 1 are as follows.
[0079] "WK307": Ethylene-methyl methacrylate copolymer (manufactured by Sumitomo Chemical Co., Ltd., trade name "WK307")
[0080] "H6822S": Resin mixture containing propylene-(1-butene) copolymer, styrene-based polymer, ethylene-based polymer, and butadiene-based polymer (manufactured by Sumitomo Chemical Co., Ltd., trade name "TAFTHREN H6822S")
[0081] "Vistamaxx6202": Amorphous propylene-ethylene copolymer (manufactured by ExxonMobil Chemical, trade name "Vistamaxx6202", 78 mol% of structural units der...
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