Gate insulating film, radiation-sensitive composition, cured film, semiconductor element, manufacturing method of semiconductor element, and display device
A gate insulating film and semiconductor technology, which is applied in the fields of semiconductor/solid-state device manufacturing, semiconductor devices, electrical components, etc., can solve the problems of reduced productivity of semiconductor element production display devices and increased number of gate insulating film manufacturing processes, etc.
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[0225]
[0226] The composition according to the embodiment of the present invention is prepared by mixing the [A] hydrolysis condensate and [B] metal oxide particles, and optionally [C] a radiation-sensitive acid generator or a radiation-sensitive base. The generator, [D] dispersant, and other optional components are mixed in a predetermined ratio. Usually, with regard to the composition of the present embodiment, after mixing [B] metal oxide particles, [D] dispersant, and [E] dispersion medium in a predetermined ratio to prepare a dispersion liquid, the dispersion liquid can be mixed with [A] ] the hydrolysis condensate, and if necessary, [C] a radiation-sensitive acid generator or a radiation-sensitive base generator or optional components are mixed to prepare the composition of this embodiment in a dispersion state.
[0227] In addition, the dispersion at the time of preparing the dispersion liquid may be carried out by using a paint shaker (paint shaker), SC mill (SC mi...
Embodiment
[0280] Hereinafter, embodiments of the present invention will be described in detail based on examples, but the present invention should not be interpreted limitedly by these examples.
[0281] The number average molecular weight (Mn) and weight average molecular weight (Mw) of the hydrolysis-condensation product obtained by the following synthesis example were measured with the gel permeation chromatography (GPC) of the following specification.
[0282] Device: GPC-101 (manufactured by Showa Denko Co., Ltd.)
[0283] Column: Combining GPC-KF-801, GPC-KF-802, GPC-KF-803 and GPC-KF-804 (manufactured by Showa Denko Co., Ltd.)
[0284] Mobile phase: tetrahydrofuran
[0285] [A] Synthesis of hydrolysis condensate
Synthetic example 1
[0287] In a container with a stirrer, add 144 parts by mass of propylene glycol monomethyl ether, then add 21 parts by mass of tetrabutoxytitanium (TBT), 19 parts by mass of methyltrimethoxysilane (MTMS), and heat until the solution temperature reaches 60 until ℃. After the solution temperature reached 60° C., 7 parts by mass of ion-exchanged water was added, heated to 75° C., and maintained for 3 hours. Then, 25 parts by mass of methyl orthoformate was added as a dehydrating agent, and stirred for 1 hour. Furthermore, the temperature of the solution was set at 40° C., and the solution was evaporated while maintaining the temperature, whereby water and alcohol generated by hydrolytic condensation were removed. The hydrolysis-condensation product (A-1) was obtained by the above operation. The number average molecular weight (Mn) of the obtained hydrolysis-condensation product was 2500, and the molecular weight distribution (Mw / Mn) was 2.
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