Conductive fine particles, method for manufacturing same, conductive resin composition, conductive sheet, and electromagnetic shielding sheet
A technology of conductive resin and manufacturing method, which is applied in the field of conductive sheets, electromagnetic wave shielding sheets, and conductive resin compositions, which can solve problems such as inability to maintain conductivity, achieve excellent conductive properties, and reduce costs
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manufacture example 1
[0062] First, dendritic silver-plated copper powder in which silver plating was applied to copper powder was prepared. The silver-plated copper powder and the solid medium are put into a closed container, and the solid medium is allowed to collide with the silver-plated copper powder in the closed container, so that the dendritic silver-plated copper powder is deformed into the conductive particles of the present invention. By colliding the solid medium with the branches of the silver-plated copper powder, the conductive particles having the scaly leaves or branched leaves of the present invention can be obtained. Among them, at the timing of adding the silver-plated copper powder, additives such as heavy metal inactivator and / or resin used in the conductive resin composition may also be added. By adding the conductive resin composition and additives, the conductive resin composition described later can be produced simultaneously with the production of conductive fine particle...
manufacture example 2
[0064]First, prepare dendritic copper powder. Put the copper powder and solid medium into an airtight container, let the solid medium collide with the copper powder in the airtight container, and transform the dendritic copper powder into the shape of the conductive particles of the present invention. Copper powder with scaly leaves or branched leaves can be obtained by letting the solid medium touch the branch part of the copper powder. Next, by coating silver on the obtained copper powder having scales or branches by plating, the conductive fine particles having scales or branches of the present invention can be obtained.
[0065] (conductive resin composition)
[0066] Next, the conductive resin composition of the present invention will be described. The conductive resin composition of the present invention includes the conductive fine particles and resin of the present invention. On the other hand, the conductive resin composition of the present invention may contain co...
Embodiment
[0096] Hereinafter, the present invention will be described in more detail with examples, but the present invention is not limited thereto. In addition, the following "parts" and "%" are values based on "parts by weight" and "% by weight", respectively.
[0097] Table 1 shows the non-leaf-shaped conductive fine particles used as raw materials. Dendritic silver-plated copper powders of conductive fine particles 1 to 7 were manufactured by Mitsui Metal Mining Co., Ltd. In addition, the dendritic copper powder of the conductive fine particles 8, the spherical silver-plated copper powder of the conductive fine particles 9, and the scaly silver powder of the conductive fine particles 11 were those manufactured by Fukuda Metal Foil Powder Industry Co., Ltd. In addition, as the scaly silver-plated copper powder of the electroconductive fine particle 10, the product manufactured by Mitsui Metal Mining Co., Ltd. was used. Here, the average particle diameter (D50) of the conductive ...
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