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Low-fluorine environment-friendly type aqueous film-forming foam fire extinguishing agent and preparation method thereof

A foam fire extinguishing agent, an environmentally friendly technology, applied in fire protection equipment and other directions, can solve the problem of less research on the combination of fluorocarbon surfactants and silicon-containing surfactants

Inactive Publication Date: 2014-12-10
INST OF ADVANCED TECH UNIV OF SCI & TECH OF CHINA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there are few studies on the compounding of fluorocarbon surfactants and silicon-containing surfactants. There are domestic and foreign reports on the compounding of fluorocarbon surfactants, hydrocarbon surfactants and silicon-containing surfactants. less

Method used

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  • Low-fluorine environment-friendly type aqueous film-forming foam fire extinguishing agent and preparation method thereof
  • Low-fluorine environment-friendly type aqueous film-forming foam fire extinguishing agent and preparation method thereof
  • Low-fluorine environment-friendly type aqueous film-forming foam fire extinguishing agent and preparation method thereof

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Effect test

Embodiment 1

[0017] The raw material composition and preparation method of the present invention can be summarized as follows:

[0018] The raw material composition of the invention includes: fluorocarbon surfactant, hydrocarbon surfactant, silicon-containing surfactant, organic solvent, anti-burning agent, foam stabilizer, preservative and water.

[0019] The combined formula of the present invention is calculated by weight percentage:

[0020]

[0021] The fluorocarbon surfactant used in the present invention is cationic perfluoroalkyl quaternary ammonium iodide FC-911 or non-ionic perfluoroalkylene oxide surfactant FC-001 or zwitterionic fluorocarbon surfactant Ee607 The function is to reduce the surface tension of the water, so that the foam solution can form a water film on the oil surface and spread quickly, sealing the oil surface, so as to achieve rapid fire extinguishing.

[0022] The hydrocarbon surfactant used in the present invention is an amphoteric imidazoline or betaine with 12-18 c...

Embodiment 2

[0031] Weigh FC-911 1kg, Ee607 1kg, ethylene glycol 20kg, diethylene glycol monobutyl ether 5kg, and mix well to form Mixture A; weigh 30kg of imidazoline, 3kg of water-soluble silicone oil, and 30kg of water and mix well to form Mixture B ; Add B to A and stir; Weigh 3kg of urea, 0.3kg of xanthan gum and dry mix evenly, slowly add to A, add 0.5kg of sodium benzoate, and finally add water to 100kg, and mix well.

Embodiment 3

[0033] Weigh 2kg of FC-911, 20kg of ethylene glycol, and 5kg of diethylene glycol monobutyl ether, and mix them to form mixture A; weigh 30kg of betaine BS-12, 2kg of water-soluble silicone oil, and 30kg of water to form mixture B; Add to A and stir; weigh 5 kg of urea, 0.2 kg of xanthan gum and dry mix evenly, slowly add to A, add 0.3 kg of potassium sorbate, and finally add water to 100 kg, and stir evenly.

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Abstract

The invention provides a low-fluorine environment-friendly type aqueous film-forming foam fire extinguishing agent and a preparation method thereof. The fire extinguishing agent is composed of the following components in percentage by weight: 1%-2% of a fluorocarbon surfactant, 10%-40% of a hydrocarbon surfactant, 1%-10% of a silicon-containing surfactant, 20%-30% of an organic solvent, 0.1%-1% of a foam stabilizer, 2%-8% of a burning-resisting agent, 0.1%-1% of a preservative and a proper amount of water. The preparation method of the fire extinguishing agent comprises the following steps: mixing and agitating the fluorocarbon surfactant with the organic solvent to form a component A; mixing the hydrocarbon surfactant with the silicon-containing surfactant and water to form a component B; uniformly mixing the burning-resisting agent, the foam stabilizer and the preservative to form a component C; adding the component B into the component A and slowly adding the component C into the component A; and agitating uniformly. According to the low-fluorine environment-friendly type aqueous film-forming foam fire extinguishing agent, the three surfactants are compounded so that the use amount of the fluorocarbon surfactant is reduced to be less than 2% and the low surface tension is still kept; and the cost of the aqueous film-forming foam fire extinguishing agent can be reduced and the damages to the environment caused by fluorine compounds can be reduced.

Description

Technical field [0001] The invention belongs to the field of fire extinguishing materials, and specifically relates to an aqueous film-forming foam fire extinguishing agent, and more specifically to an environmentally-friendly aqueous film-forming foam fire extinguishing agent with low fluorine content and a preparation method thereof. Background technique [0002] Aqueous Film Forming Foam (AFFF) fire extinguishing agent, also known as "light water" foam fire extinguishing agent, is an efficient fire extinguishing agent developed abroad in the 1960s. The aqueous film-forming foam solution uses fluorocarbon surfactants as the main raw material, and at the same time includes hydrocarbon surfactants, foam stabilizers, antifreeze agents and other additives. With its high surface activity, AFFF can spread around the surface of the flammable liquid during the fire extinguishing process, and the liquid separated from the foam forms a water film to separate the foam and the flammable li...

Claims

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Application Information

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IPC IPC(8): A62D1/04
Inventor 盛友杰赵传文陆守香
Owner INST OF ADVANCED TECH UNIV OF SCI & TECH OF CHINA
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