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Green brick of monofired glass ceramic composite plate

A technology of glass-ceramic and glass-ceramic frit, which is applied in the field of architectural ceramics, can solve the problems of low yield, low flatness, affecting the quality and aesthetics of glass-ceramic composite panels, and achieves no color effect. Influence, the effect of high yield

Active Publication Date: 2014-12-31
张家港和智珅知识产权有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Then send the above into the kiln for firing. When transported into the kiln, it will pass through a low negative pressure pre-tropical zone. Some small glass-ceramic frit particles that are placed on the top layer are easily sucked away due to their light weight. , resulting in the lack of a lot of glass-ceramic frit particles on the surface layer, the flatness of the adobe is not high after firing, and pinholes or dissolution holes appear, which greatly affects the quality and aesthetics of the glass-ceramic composite board. The yield rate is not high

Method used

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  • Green brick of monofired glass ceramic composite plate
  • Green brick of monofired glass ceramic composite plate
  • Green brick of monofired glass ceramic composite plate

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1-1

[0026] The glass-ceramic frit particle of 375kg silver-white ice crystal effect (purchase from Quincy Caroby Glaze Company, fineness 70 orders) is added in the frit particle binder of 125kg that embodiment group 1 makes, mix homogeneously , to obtain glass-ceramic frit particle suspension, the solid content of glass-ceramic frit particles is 75%, no visible bubbles, the flow rate is 46.2s (30 ℃, coated with -4 cups), and there is still no stratification after the suspension is placed for 5 days , it can be seen that the frit particle binder of the present invention still has good stability after mixing with the glass-ceramic frit particles. It should be noted that the glass-ceramic frit particles with silver-white ice crystal effect selected in Example 1-1 spread during the sintering process, forming the effect of silver-white ice crystal flowers on the glaze layer, and the glass-ceramic frit particles It can be purchased through the color glaze company, and similar frit produ...

Embodiment 3

[0046] Components of per 100kg frit particle binder: nonionic polyurethane associative thickener (Nae Woi Korea., Ltd. company, model HIRESOL85) 7.5kg, white carbon black content is added as shown in Table 3, polyether type GPE defoamer (purchased from Hangzhou Feier Chemical Industry Co., Ltd.) 1.3kg, sodium tripolyphosphate 1kg, and the balance is 13-15% ethanol aqueous solution.

[0047] The frit granules of 375kg green ice crystal effect (purchase from Quincy Carroby Glaze Company, fineness 100 orders) are added in the 125kg frit granule binder that embodiment 3 makes, mix uniformly, get frit granule Suspension, frit particle solid content 75%, no visible bubbles, left for 5 days, flow rate and stratification phenomenon are shown in Table 3.

Embodiment 3-00

[0049] Add 375kg of frit granules of green ice crystal effect (purchased from Quincy Carloby Glaze Company, fineness 80 mesh) into 125kg of viscous water slurry prepared by sodium carboxymethyl cellulose, mix well to get frit granules Suspension, frit particle solid content 75%, left for 5 days, flow rate and stratification phenomenon are shown in Table 3.

[0050] Table 3 Effect of silica content on the stratification of suspension

[0051]

[0052] It can be obtained from Table 3 that the viscosity value of the viscous water slurry formulated with sodium carboxymethyl cellulose is not high, which cannot effectively prevent the glass-ceramic frit particles from being sucked away by low negative pressure, and there is bubble phenomenon, which is different from that of glass-ceramic The suspension after mixing the frit particles cannot be stored for a long time. In addition, the addition of silica improves the thickening efficiency of the suspension. Silica has good thixotr...

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Abstract

The invention relates to a green brick of a monofired glass ceramic composite plate. The green brick comprises a green body layer and a glass ceramic frit layer from bottom to top, wherein the glass ceramic frit layer is formed in the way that a glass ceramic frit particle suspension liquid formed by mixing glass ceramic frit particles and a frit particle adhesive is applied to the surface of the green body layer; the frit particle adhesive comprises the following components by mass percent: 6.5-7.5 percent of a nonionic polyurethane associative thickener, 3.2-4.4 percent of silica, 1-1.5 percent of a defoamer, 0.3-1.3 percent of a dispersant and the balance of a solvent. The glass ceramic frit particles of the surface of the green brick structure are not taken away by a blower at a preheating zone during firing, so that waste is avoided and the defect rate of the glass ceramic composite plate product is reduced.

Description

technical field [0001] The invention relates to the technical field of architectural ceramics, in particular to a brick adobe made of a glass-ceramic composite plate fired once. Background technique [0002] Since the technology of glass-ceramic composite panel has been maturely applied, its technology has been continuously developed and innovated, and the product has become a high-grade decorative material in the market because of its transparent micro-crystalline frit particles and personalized decorative effect, and is well received by consumers. favorite. [0003] The adobe of the glass-ceramic composite board fired at one time includes a green body layer and a glass-ceramic frit layer from bottom to top, and the glass-ceramic frit layer is generally composed of glass-ceramic frit particles, specifically, ceramic powder The material is pressed to form an adobe, and then a layer of glass-ceramic frit particles is spread on the surface to form a glass-ceramic frit layer t...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B41/86
Inventor 朱培祺朱丽萍刘咏平麦晓君梁永健
Owner 张家港和智珅知识产权有限公司
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