The invention relates to a green brick of a single-firing glass ceramic composite board. The green brick comprises a green body layer, a ground coat layer and a glass ceramic frit layer from bottom to top, and further comprises a fixing layer arranged on the surface of the glass ceramic fruit layer, wherein the fixing layer is formed by spraying a glass ceramic frit particle fixing agent, the ground coat layer contains 3%-5% of pyrophyllite according to mass percent, and the glass ceramic frit particle fixing agent comprises the following components in percentage by weight: 3.8-4.8% of a nonionic polyurethane associated thickener, 1.8-2.4% of attapulgite clay, 0.6-1% of a defoamer, 0.6-1.6% of a dispersing agent and the balance of a solvent. When the green brick is used, a glass ceramic frit particle on the surface cannot be taken away by an air draught in a preheating zone in the firing, so that the waste is avoided, and the defect rate of a product of the glass ceramic composite board is reduced.