Fully polymerized UV blocking silicone hydrogel lens
A siloxane hydrogel and ultraviolet technology, applied in glasses/goggles, instruments, and other household appliances, can solve the problems of difficult formation of ophthalmic devices and incomplete curing
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[0055] All solvents and reagents were obtained from commercial sources identified below and used as received.
[0056] NVP - distilled
Aldrich
CIX-4
Novasep
DMA - Distilled
Aldrich
Irg 819
Aldrich
Sigma Aldrich
nonanol
Aldrich
SA monomer
Aldrich
BTT
Aldrich
BPA-2
Polysciences Inc
BPM-2
Monomer-Polymer and Dajac Labs
BPA-1
Aldrich
Reactive Blue Tint = 1MVT
Arran
M1-EDS-6
Gelest
Ma1D20
Gelest
HEMA
Cyro Industries
[0057]
[0058] Methacryloxypropyltris(trimethylsiloxy)silane
[0059] TRIS
[0060]
[0061] Ma2D37
[0062]
[0063] N-vinylpyrrolidone
[0064] NVP
[0065]
[0066] Diethylene glycol bis(N-vinylbenzylcarbamate)
[0067] CIX-4
[0068]
[0069] N,N-Dimethacrylamide
[0070] DMA
[0071]
[0072] IRG819 (photoinitiator)
[0073]
[0074] SA monomer (UV blocker)...
Embodiment approach
[0192] 1(a). A method for making a substantially fully polymerized UV blocking hydrogel lens comprising:
[0193] A monomer mixture of at least NVP, one additional comonomer, and a free radically polymerizable bis-o-hydroxybenzophenone is polymerized to provide a hydrogel ophthalmic device having a wettable surface.
[0194] 1(b). A method for making a substantially fully polymerized UV blocking hydrogel lens comprising:
[0195] Polymerizing a monomer mixture of at least NVP, an additional comonomer, and a radically polymerizable di-ortho-hydroxybenzophenone to provide a UV-blocking compound having sufficient UV blocking to meet at least Class II specifications for UV blocking. Hydrogel Ophthalmic Devices.
[0196] 1(c). A method for preparing a substantially fully polymerized UV-blocking hydrogel lens comprising adding at least one monomer selected from the group consisting of monomers, at least one A monomer mixture of an additional comonomer and a free radically polymeri...
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