A kind of desulfurization catalyst and its preparation method and the method for hydrocarbon oil desulfurization

A desulfurization catalyst, alumina technology, applied in the direction of refined hydrocarbon oil, molecular sieve catalyst, chemical instruments and methods, etc., can solve the problem of reduced activity of adsorbents

Active Publication Date: 2016-08-24
CHINA PETROLEUM & CHEM CORP +1
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0014] The purpose of the present invention is to provide a desulfurization catalyst and its preparation method and a method for desulfurization of hydrocarbon oil in order to overcome the problem of reduced adsorbent activity in the prior art

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  • A kind of desulfurization catalyst and its preparation method and the method for hydrocarbon oil desulfurization
  • A kind of desulfurization catalyst and its preparation method and the method for hydrocarbon oil desulfurization
  • A kind of desulfurization catalyst and its preparation method and the method for hydrocarbon oil desulfurization

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preparation example Construction

[0044] The present invention also provides a method for preparing a desulfurization catalyst, the method comprising: (1) performing a precipitation reaction on a mixed solution obtained by mixing a lead-containing compound, a zinc-containing compound and water, and filtering, drying and Roasting to obtain a precipitated product; (2) contacting a silica source, an alumina source, a phosphorus-containing compound, a molecular sieve with a BEA structure and / or a molecular sieve with a FAU structure, water and an acid solution to form a slurry, and the step (1) The obtained precipitation product is mixed with the slurry to form a carrier mixture; then the carrier mixture is shaped, dried and calcined to form a carrier; (3) a compound containing an active metal is introduced into the carrier obtained in step (2) and dried, roasting to obtain a desulfurization catalyst precursor; the active metal is at least one of cobalt, nickel, iron and manganese; (4) reducing the desulfurization ...

Embodiment 1

[0088] This example is used to illustrate the preparation method of the desulfurization catalyst of the present invention.

[0089] (1) Precipitation product is prepared. Mix 10.9 kg of zinc acetate dihydrate powder (produced by Beijing Chemical Plant, analytically pure), 0.86 kg of lead acetate trihydrate (Sinopharm Chemical Reagent Company, analytically pure) and 18 kg of deionized water, and dissolve completely after stirring for 30 minutes. The precipitated product obtained by adding 1.8 kg of ammonia water was filtered, dried at 150° C. for 2 hours, and then calcined at 500° C. for 1 hour to obtain the precipitated product C1.

[0090] The precipitated product C1 was subjected to fluorescence analysis and XRD determination. In the XRD spectrum (see figure 1 ) has no diffraction peak of PbO, and the standard diffraction peak of ZnO shifts to the right, where A 100 -B 100 = 0.2°, A 002 -B 002 = 0.21°, A 101 -B 101 = 0.2°, indicating that PbO and ZnO in the precipita...

Embodiment 2

[0098] This example is used to illustrate the preparation method of the desulfurization catalyst of the present invention.

[0099] (1) Precipitation product is prepared. 14.0 kg of zinc nitrate hexahydrate (produced by Beijing Chemical Plant, analytically pure), 1.80 kg of lead nitrate powder (Sinopharm Chemical Reagent Company, analytically pure) and 18 kg of deionized water were mixed, and after stirring for 30 minutes, 2.0 kg of urea was added and heated to After treatment at 80°C for 2 hours, a white precipitate was obtained. After filtration, it was first dried at 150°C for 2 hours, and then calcined at 500°C for 1 hour to obtain the precipitated product C2.

[0100] The precipitated product C2 was subjected to fluorescence analysis and XRD determination. In the XRD spectrum (see figure 1 ) has no diffraction peak of PbO, and the standard diffraction peak of ZnO shifts to the right, where A 100 -B 100 = 0.25°, A 002 -B 002 = 0.24°, A 101 -B 101 =0.24°, indicating...

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Abstract

The invention discloses a desulfurization catalyst which includes following components, on the basis of the total weight of the desulfurization catalyst, by weight: 5-30% of a silicon oxide source, 5-30% of aluminum oxide, 30-70% of zinc oxide, 2-15% of lead oxide, 0.5-10% of a phosphorus oxide based on the weight of P2O5, 1-20% of a molecular sieve having a BEA structure and / or a molecular sieve having an FAU structure, and 5-30% of an active metal. At least partial lead oxide and the zinc oxide are formed into a zinc-lead solid solution with a general formula being Pb<x>Zn<1-x>O, wherein 0<x<=0.12 and the x refers to atom molar ratio. The active metal is at least one of cobalt, nickel, iron and manganese. The invention also provides a preparation method of the desulfurization catalyst and a hydrocarbon oil desulfurizing method. The desulfurization catalyst is better in desulfurization activity and activity stability.

Description

technical field [0001] The present invention relates to a kind of desulfurization catalyst and its preparation method and the method of hydrocarbon oil desulfurization, specifically, relate to a kind of desulfurization catalyst, a kind of preparation method of desulfurization catalyst and the desulfurization catalyst obtained by this method, and desulfurization catalyst in hydrocarbon oil desulfurization method applied in . Background technique [0002] As people pay more and more attention to environmental protection, environmental regulations are becoming stricter, and reducing the sulfur content of gasoline and diesel is considered to be one of the most important measures to improve air quality, because sulfur in fuel will affect the performance of automotive catalytic converters produce adverse effects. The sulfur present in the exhaust of automobile engines will inhibit the precious metals in the converter and cause irreversible poisoning, reducing the effect of the co...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J29/76B01J29/14C10G45/12
Inventor 林伟田辉平王振波徐志成王磊张萍
Owner CHINA PETROLEUM & CHEM CORP
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