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Desulfurization catalyst and preparation method thereof, and hydrocarbon oil desulfurization method
ActiveCN104511282AOvercoming the problem of reduced activityMetal/metal-oxides/metal-hydroxide catalystsRefining to eliminate hetero atomsManganeseLead oxide
The present invention discloses a desulfurization catalyst, which contains, by weight, 5-35% of a silica source, 5-35% of alumina, 30-70% of zinc oxide, 2-15% of lead oxide, and 5-30% of an active metal, wherein at least part of the lead oxide exists in the form for forming the zinc lead solid solution represented by a general formula PbxZn1-xO with the zinc oxide, x is more than 0 and is less than or equal to 0.12, x represents an atomic molar ratio, and the active metal is at least one selected from cobalt, nickel, iron and manganese. The present invention further provides a desulfurization catalyst preparation method and a hydrocarbon oil desulfurization method. The desulfurization catalyst of the present invention has good desulfurization activity and good activity stability.
Owner:CHINA PETROLEUM & CHEM CORP +1
Desulfurization catalyst, preparation method thereof and hydrocarbon oil desulfurizing method
ActiveCN104511286AOvercoming the problem of reduced activityRefining with metal oxidesMetal/metal-oxides/metal-hydroxide catalystsTin dioxideManganese
The invention discloses a desulfurization catalyst which includes following components, on the basis of the total weight of the desulfurization catalyst, by weight: 5-35% of a silicon oxide source, 5-35% of a non-aluminum oxide, 30-70% of zinc oxide, 2-15% of lead oxide and 5-30% of an active metal. At least partial lead oxide and the zinc oxide are formed into a zinc-lead solid solution with a general formula being Pb<x>Zn<1-x>O, wherein 0<x<=0.12 and the x refers to atom molar ratio. The non-aluminum oxide is at least one of zirconium dioxide, titanium dioxide and stannic dioxide. The active metal is at least one of cobalt, nickel, iron and manganese. The invention also provides a preparation method of the desulfurization catalyst and a hydrocarbon oil desulfurizing method. The desulfurization catalyst is better in desulfurization activity and activity stability.
Owner:CHINA PETROLEUM & CHEM CORP +1
Desulfurization catalyst, preparation method thereof and hydrocarbon oil desulfurizing method
ActiveCN104511299AOvercoming the problem of reduced activityMolecular sieve catalystsHydrocarbon oils refiningMolecular sieveOxide
The invention discloses a desulfurization catalyst which includes following components, on the basis of the total weight of the desulfurization catalyst, by weight: 5-30% of a silicon oxide source, 5-30% of aluminum oxide, 30-70% of zinc oxide, 2-15% of lead oxide, 1-20% of a molecular sieve having a BEA structure and/or a molecular sieve having an FAU structure, and 5-30% of an active metal. At least partial lead oxide and the zinc oxide are formed into a zinc-lead solid solution with a general formula being Pb<x>Zn<1-x>O, wherein 0<x<=0.12 and the x refers to atom molar ratio. The active metal is at least one of cobalt, nickel, iron and manganese. The invention also provides a preparation method of the desulfurization catalyst and a hydrocarbon oil desulfurizing method. The desulfurization catalyst is better in desulfurization activity and activity stability.
Owner:CHINA PETROLEUM & CHEM CORP +1
Desulfurization catalyst, preparation method thereof and hydrocarbon oil desulfurizing method
ActiveCN104511285AOvercoming the problem of reduced activityMetal/metal-oxides/metal-hydroxide catalystsRefining to eliminate hetero atomsManganeseLead oxide
The invention discloses a desulfurization catalyst which includes following components, on the basis of the total weight of the desulfurization catalyst, by weight: 5-35% of pillared interlayered clay, 5-35% of aluminum oxide, 30-70% of zinc oxide, 2-15% of lead oxide and 5-30% of an active metal. At least partial lead oxide and the zinc oxide are formed into a zinc-lead solid solution with a general formula being Pb<x>Zn<1-x>O, wherein 0<x<=0.12 and the x refers to atom molar ratio. The active metal is at least one of cobalt, nickel, iron and manganese. The invention also provides a preparation method of the desulfurization catalyst and a hydrocarbon oil desulfurizing method. The desulfurization catalyst is better in desulfurization activity and activity stability.
Owner:CHINA PETROLEUM & CHEM CORP +1
Desulfurization catalyst, preparation method thereof and hydrocarbon oil desulfurizing method
ActiveCN104511302AOvercoming the problem of reduced activityMolecular sieve catalystsHydrocarbon oils refiningMolecular sievePtru catalyst
The invention discloses a desulfurization catalyst which includes following components, on the basis of the total weight of the desulfurization catalyst, by weight: 5-30% of a silicon oxide source, 5-30% of a non-aluminum oxide, 30-70% of zinc oxide, 2-15% of lead oxide, 1-20% of a molecular sieve having a BEA structure and / or a molecular sieve having an FAU structure, and 5-30% of an active metal. At least partial lead oxide and the zinc oxide are formed into a zinc-lead solid solution with a general formula being Pb<x>Zn<1-x>O, wherein 0<x<=0.12 and the x refers to atom molar ratio. The non-aluminum oxide is at least one of zirconium dioxide, titanium dioxide and stannic dioxide. The active metal is at least one of cobalt, nickel, iron and manganese. The invention also provides a preparation method of the desulfurization catalyst and a hydrocarbon oil desulfurizing method. The desulfurization catalyst is better in desulfurization activity and activity stability.
Owner:CHINA PETROLEUM & CHEM CORP +1
Desulfurization catalyst, preparation method thereof and hydrocarbon oil desulfurizing method
ActiveCN104511309AOvercoming the problem of reduced activityMolecular sieve catalystsHydrocarbon oils refiningManganeseSilicon oxide
The invention discloses a desulfurization catalyst which includes following components, on the basis of the total weight of the desulfurization catalyst, by weight: 5-30% of a silicon oxide source, 5-30% of aluminum oxide, 30-70% of zinc oxide, 2-15% of lead oxide, 1-20% of a phosphorus-aluminum molecular sieve, and 5-30% of an active metal. At least partial lead oxide and the zinc oxide are formed into a zinc-lead solid solution with a general formula being Pb<x>Zn<1-x>O, wherein 0<x<=0.12 and the x refers to atom molar ratio. The active metal is at least one of cobalt, nickel, iron and manganese. The invention also provides a preparation method of the desulfurization catalyst and a hydrocarbon oil desulfurizing method. The desulfurization catalyst is better in desulfurization activity and activity stability.
Owner:CHINA PETROLEUM & CHEM CORP +1
Desulfurization catalyst, preparation method thereof and hydrocarbon oil desulfurizing method
ActiveCN104511284AOvercoming the problem of reduced activityMolecular sieve catalystsMetal/metal-oxides/metal-hydroxide catalystsOxideZinc
The invention discloses a desulfurization catalyst which includes following components, on the basis of the total weight of the desulfurization catalyst, by weight: 5-35% of a silicon oxide source, 5-35% of aluminum oxide, 30-70% of zinc oxide, 2-15% of lead oxide, 0.5-10% of an alkaline-earth metal oxide and 5-30% of an active metal. At least partial lead oxide and the zinc oxide are formed into a zinc-lead solid solution with a general formula being Pb<x>Zn<1-x>O, wherein 0<x<=0.12 and the x refers to atom molar ratio. The active metal is at least one of cobalt, nickel, iron and manganese. The invention also provides a preparation method of the desulfurization catalyst and a hydrocarbon oil desulfurizing method. The desulfurization catalyst is better in desulfurization activity and activity stability.
Owner:CHINA PETROLEUM & CHEM CORP +1
Nanoporous copper/cu(oh)2 nanowire array sensor electrode material and preparation method thereof
ActiveCN106226382BThickness is easy to controlEasy to prepareMaterial nanotechnologyMaterial electrochemical variablesGlucose sensorsComposite electrode
The invention discloses a nano porous copper / Cu(OH)2 nanowire array sensor electrode material and a preparation method thereof, and belongs to the technical field of micro-sensation. The preparation method of the nano porous copper / Cu(OH)2 nanowire array sensor electrode material mainly comprises the following two steps: by taking Cu-Zr-Al amorphous alloy as a precursor, preparing a flexible nano porous copper film of a double-continuous through hole structure by using a chemical alloy removing method; performing controllable growth on a Cu(OH)2 nanowire array on a nano porous copper film substrate by using an alkali oxidation method. The nano composite electrode material disclosed by the invention is of a structure similar to 'sandwich', Cu(OH)2 nanowires are uniformly and densely distributed on the nano porous copper substrate, have directivity and are uniform in morphology, large in internal specific surface area and very high in electric catalytic activity, the nano composite material can be directly used as an electrode material of a non-enzyme glucose sensor, the linear response range for glucose is 0.2-9 mM, the detection sensitivity is 2.09 mA / cm<2>.mM, the detection limit is 200 nM (S / N=-3.6), and the current response time is less than 1 second.
Owner:UNIV OF SCI & TECH BEIJING
Desulfurization catalyst, preparation method thereof and hydrocarbon oil desulfurizing method
ActiveCN104511303AOvercoming the problem of reduced activityMolecular sieve catalystsHydrocarbon oils refiningMolecular sieveManganese
The invention discloses a desulfurization catalyst which includes following components, on the basis of the total weight of the desulfurization catalyst, by weight: 5-30% of pillared interlayered clay, 5-30% of aluminum oxide, 30-70% of zinc oxide, 2-15% of lead oxide, 1-20% of a molecular sieve having a BEA structure and/or a molecular sieve having an FAU structure, and 5-30% of an active metal. At least partial lead oxide and the zinc oxide are formed into a zinc-lead solid solution with a general formula being Pb<x>Zn<1-x>O, wherein 0<x<=0.12 and the x refers to atom molar ratio. The active metal is at least one of cobalt, nickel, iron and manganese. The invention also provides a preparation method of the desulfurization catalyst and a hydrocarbon oil desulfurizing method. The desulfurization catalyst is better in desulfurization activity and activity stability.
Owner:CHINA PETROLEUM & CHEM CORP +1
Desulfurization catalyst and preparation method thereof, and hydrocarbon oil desulfurization method
ActiveCN104511307AOvercoming the problem of reduced activityMolecular sieve catalystsHydrocarbon oils refiningManganeseCobalt
The present invention discloses a desulfurization catalyst, which contains, by weight, 5-30% of pillared clay, 5-30% of alumina, 30-70% of zinc oxide, 2-15% of lead oxide, 1-20% of a phosphorus-aluminum molecular sieve, and 5-30% of an active metal, wherein at least part of the lead oxide exists in the form for forming the zinc lead solid solution represented by a general formula PbxZn1-xO with the zinc oxide, x is more than 0 and is less than or equal to 0.12, x represents an atomic molar ratio, and the active metal is at least one selected from cobalt, nickel, iron and manganese. The present invention further provides a desulfurization catalyst preparation method and a hydrocarbon oil desulfurization method. The desulfurization catalyst of the present invention has good desulfurization activity and good activity stability.
Owner:CHINA PETROLEUM & CHEM CORP +1
Desulfurization catalyst, preparation method thereof and hydrocarbon oil desulfurizing method
ActiveCN104511308AOvercoming the problem of reduced activityMolecular sieve catalystsHydrocarbon oils refiningTin dioxideManganese
The invention discloses a desulfurization catalyst which includes following components, on the basis of the total weight of the desulfurization catalyst, by weight: 5-30% of a silicon oxide source, 5-30% of a non-aluminum oxide, 30-70% of zinc oxide, 2-15% of lead oxide, 1-20% of a phosphorus-aluminum molecular sieve, and 5-30% of an active metal. At least partial lead oxide and the zinc oxide are formed into a zinc-lead solid solution with a general formula being Pb<x>Zn<1-x>O, wherein 0<x<=0.12 and the x refers to atom molar ratio. The non-aluminum oxide is at least one of zirconium dioxide, titanium dioxide and stannic dioxide. The active metal is at least one of cobalt, nickel, iron and manganese. The invention also provides a preparation method of the desulfurization catalyst and a hydrocarbon oil desulfurizing method. The desulfurization catalyst is better in desulfurization activity and activity stability.
Owner:CHINA PETROLEUM & CHEM CORP +1
Desulfurization catalyst, preparation method thereof and hydrocarbon oil desulfurizing method
ActiveCN104511300AOvercoming the problem of reduced activityMolecular sieve catalystsHydrocarbon oils refiningMolecular sieveAlkali metal oxide
The invention discloses a desulfurization catalyst which includes following components, on the basis of the total weight of the desulfurization catalyst, by weight: 5-30% of a silicon oxide source, 5-30% of aluminum oxide, 30-70% of zinc oxide, 2-15% of lead oxide, 0.5-10% of an alkali metal oxide, 1-20% of a molecular sieve having a BEA structure and / or a molecular sieve having an FAU structure, and 5-30% of an active metal. At least partial lead oxide and the zinc oxide are formed into a zinc-lead solid solution with a general formula being Pb<x>Zn<1-x>O, wherein 0<x<=0.12 and the x refers to atom molar ratio. The active metal is at least one of cobalt, nickel, iron and manganese. The invention also provides a preparation method of the desulfurization catalyst and a hydrocarbon oil desulfurizing method. The desulfurization catalyst is better in desulfurization activity and activity stability.
Owner:CHINA PETROLEUM & CHEM CORP +1
Desulfurization catalyst, preparation method thereof and hydrocarbon oil desulfurizing method
ActiveCN104511301AOvercoming the problem of reduced activityMolecular sieve catalystsHydrocarbon oils refiningMolecular sieveManganese
The invention discloses a desulfurization catalyst which includes following components, on the basis of the total weight of the desulfurization catalyst, by weight: 5-30% of a silicon oxide source, 5-30% of aluminum oxide, 30-70% of zinc oxide, 2-15% of lead oxide, 0.5-10% of a phosphorus oxide based on the weight of P2O5, 1-20% of a molecular sieve having a BEA structure and / or a molecular sieve having an FAU structure, and 5-30% of an active metal. At least partial lead oxide and the zinc oxide are formed into a zinc-lead solid solution with a general formula being Pb<x>Zn<1-x>O, wherein 0<x<=0.12 and the x refers to atom molar ratio. The active metal is at least one of cobalt, nickel, iron and manganese. The invention also provides a preparation method of the desulfurization catalyst and a hydrocarbon oil desulfurizing method. The desulfurization catalyst is better in desulfurization activity and activity stability.
Owner:CHINA PETROLEUM & CHEM CORP +1
Desulfurization catalyst, preparation method thereof and hydrocarbon oil desulfurizing method
ActiveCN104511283AOvercoming the problem of reduced activityMetal/metal-oxides/metal-hydroxide catalystsRefining to eliminate hetero atomsNickelZinc
The invention discloses a desulfurization catalyst which includes following components, on the basis of the total weight of the desulfurization catalyst, by weight: 5-35% of a silicon oxide source, 5-35% of aluminum oxide, 30-70% of zinc oxide, 2-15% of lead oxide, 0.5-10% of an alkali metal oxide and 5-30% of an active metal. At least partial lead oxide and the zinc oxide are formed into a zinc-lead solid solution with a general formula being Pb<x>Zn<1-x>O, wherein 0<x<=0.12 and the x refers to atom molar ratio. The active metal is at least one of cobalt, nickel, iron and manganese. The invention also provides a preparation method of the desulfurization catalyst and a hydrocarbon oil desulfurizing method. The desulfurization catalyst is better in desulfurization activity and activity stability.
Owner:CHINA PETROLEUM & CHEM CORP +1
A kind of desulfurization catalyst and its preparation method and the method for hydrocarbon oil desulfurization
ActiveCN104511308BOvercoming the problem of reduced activityMolecular sieve catalystsHydrocarbon oils refiningManganeseSilicon oxide
The invention discloses a desulfurization catalyst which includes following components, on the basis of the total weight of the desulfurization catalyst, by weight: 5-30% of a silicon oxide source, 5-30% of a non-aluminum oxide, 30-70% of zinc oxide, 2-15% of lead oxide, 1-20% of a phosphorus-aluminum molecular sieve, and 5-30% of an active metal. At least partial lead oxide and the zinc oxide are formed into a zinc-lead solid solution with a general formula being Pb<x>Zn<1-x>O, wherein 0<x<=0.12 and the x refers to atom molar ratio. The non-aluminum oxide is at least one of zirconium dioxide, titanium dioxide and stannic dioxide. The active metal is at least one of cobalt, nickel, iron and manganese. The invention also provides a preparation method of the desulfurization catalyst and a hydrocarbon oil desulfurizing method. The desulfurization catalyst is better in desulfurization activity and activity stability.
Owner:CHINA PETROLEUM & CHEM CORP +1
A kind of desulfurization catalyst and its preparation method and the method for hydrocarbon oil desulfurization
ActiveCN104511294BOvercoming the problem of reduced activityPhysical/chemical process catalystsRefining to eliminate hetero atomsPtru catalystManganese
The invention discloses a desulfurization catalyst which includes following components, on the basis of the total weight of the desulfurization catalyst, by weight: 5-35% of a silicon oxide source, 5-35% of aluminum oxide, 30-70% of zinc oxide, 2-15% of lead oxide, 0.5-10% of a phosphorus oxide based on the weight of P2O5 and 5-30% of an active metal. At least partial lead oxide and the zinc oxide are formed into a zinc-lead solid solution with a general formula being Pb<x>Zn<1-x>O, wherein 0<x<=0.12 and the x refers to atom molar ratio. The active metal is at least one of cobalt, nickel, iron and manganese. The invention also provides a preparation method of the desulfurization catalyst and a hydrocarbon oil desulfurizing method. The desulfurization catalyst is better in desulfurization activity and activity stability.
Owner:CHINA PETROLEUM & CHEM CORP +1
Desulfurization catalyst, preparation method thereof and hydrocarbon oil desulfurizing method
ActiveCN104511306AOvercoming the problem of reduced activityMolecular sieve catalystsRefining with metal oxidesMolecular sieveManganese
The invention discloses a desulfurization catalyst which includes following components, on the basis of the total weight of the desulfurization catalyst, by weight: 5-30% of a silicon oxide source, 5-30% of aluminum oxide, 30-70% of zinc oxide, 2-15% of lead oxide, 0.5-10% of a phosphorus oxide based on the weight of P2O5, 1-20% of a phosphorus-aluminum molecular sieve, and 5-30% of an active metal. At least partial lead oxide and the zinc oxide are formed into a zinc-lead solid solution with a general formula being Pb<x>Zn<1-x>O, wherein 0<x<=0.12 and the x refers to atom molar ratio. The active metal is at least one of cobalt, nickel, iron and manganese. The invention also provides a preparation method of the desulfurization catalyst and a hydrocarbon oil desulfurizing method. The desulfurization catalyst is better in desulfurization activity and activity stability.
Owner:CHINA PETROLEUM & CHEM CORP +1
A kind of desulfurization catalyst and its preparation method and the method for hydrocarbon oil desulfurization
ActiveCN104511300BOvercoming the problem of reduced activityMolecular sieve catalystsHydrocarbon oils refiningMolecular sieveAlkali metal oxide
The invention discloses a desulfurization catalyst which includes following components, on the basis of the total weight of the desulfurization catalyst, by weight: 5-30% of a silicon oxide source, 5-30% of aluminum oxide, 30-70% of zinc oxide, 2-15% of lead oxide, 0.5-10% of an alkali metal oxide, 1-20% of a molecular sieve having a BEA structure and / or a molecular sieve having an FAU structure, and 5-30% of an active metal. At least partial lead oxide and the zinc oxide are formed into a zinc-lead solid solution with a general formula being Pb<x>Zn<1-x>O, wherein 0<x<=0.12 and the x refers to atom molar ratio. The active metal is at least one of cobalt, nickel, iron and manganese. The invention also provides a preparation method of the desulfurization catalyst and a hydrocarbon oil desulfurizing method. The desulfurization catalyst is better in desulfurization activity and activity stability.
Owner:CHINA PETROLEUM & CHEM CORP +1
A kind of desulfurization catalyst and its preparation method and the method for hydrocarbon oil desulfurization
ActiveCN104511306BOvercoming the problem of reduced activityMolecular sieve catalystsRefining with metal oxidesMolecular sievePtru catalyst
The invention discloses a desulfurization catalyst which includes following components, on the basis of the total weight of the desulfurization catalyst, by weight: 5-30% of a silicon oxide source, 5-30% of aluminum oxide, 30-70% of zinc oxide, 2-15% of lead oxide, 0.5-10% of a phosphorus oxide based on the weight of P2O5, 1-20% of a phosphorus-aluminum molecular sieve, and 5-30% of an active metal. At least partial lead oxide and the zinc oxide are formed into a zinc-lead solid solution with a general formula being Pb<x>Zn<1-x>O, wherein 0<x<=0.12 and the x refers to atom molar ratio. The active metal is at least one of cobalt, nickel, iron and manganese. The invention also provides a preparation method of the desulfurization catalyst and a hydrocarbon oil desulfurizing method. The desulfurization catalyst is better in desulfurization activity and activity stability.
Owner:CHINA PETROLEUM & CHEM CORP +1
A kind of desulfurization catalyst and its preparation method and the method for hydrocarbon oil desulfurization
ActiveCN104511302BOvercoming the problem of reduced activityMolecular sieve catalystsHydrocarbon oils refiningTin dioxideMolecular sieve
The invention discloses a desulfurization catalyst which includes following components, on the basis of the total weight of the desulfurization catalyst, by weight: 5-30% of a silicon oxide source, 5-30% of a non-aluminum oxide, 30-70% of zinc oxide, 2-15% of lead oxide, 1-20% of a molecular sieve having a BEA structure and / or a molecular sieve having an FAU structure, and 5-30% of an active metal. At least partial lead oxide and the zinc oxide are formed into a zinc-lead solid solution with a general formula being Pb<x>Zn<1-x>O, wherein 0<x<=0.12 and the x refers to atom molar ratio. The non-aluminum oxide is at least one of zirconium dioxide, titanium dioxide and stannic dioxide. The active metal is at least one of cobalt, nickel, iron and manganese. The invention also provides a preparation method of the desulfurization catalyst and a hydrocarbon oil desulfurizing method. The desulfurization catalyst is better in desulfurization activity and activity stability.
Owner:CHINA PETROLEUM & CHEM CORP +1
A kind of desulfurization catalyst and its preparation method and the method of hydrocarbon oil desulfurization
ActiveCN104511282BOvercoming the problem of reduced activityMetal/metal-oxides/metal-hydroxide catalystsRefining to eliminate hetero atomsManganeseLead oxide
The present invention discloses a desulfurization catalyst, which contains, by weight, 5-35% of a silica source, 5-35% of alumina, 30-70% of zinc oxide, 2-15% of lead oxide, and 5-30% of an active metal, wherein at least part of the lead oxide exists in the form for forming the zinc lead solid solution represented by a general formula PbxZn1-xO with the zinc oxide, x is more than 0 and is less than or equal to 0.12, x represents an atomic molar ratio, and the active metal is at least one selected from cobalt, nickel, iron and manganese. The present invention further provides a desulfurization catalyst preparation method and a hydrocarbon oil desulfurization method. The desulfurization catalyst of the present invention has good desulfurization activity and good activity stability.
Owner:CHINA PETROLEUM & CHEM CORP +1
A kind of desulfurization catalyst and its preparation method and the method of hydrocarbon oil desulfurization
ActiveCN104511286BOvercoming the problem of reduced activityRefining with metal oxidesMetal/metal-oxides/metal-hydroxide catalystsPtru catalystManganese
The invention discloses a desulfurization catalyst which includes following components, on the basis of the total weight of the desulfurization catalyst, by weight: 5-35% of a silicon oxide source, 5-35% of a non-aluminum oxide, 30-70% of zinc oxide, 2-15% of lead oxide and 5-30% of an active metal. At least partial lead oxide and the zinc oxide are formed into a zinc-lead solid solution with a general formula being Pb<x>Zn<1-x>O, wherein 0<x<=0.12 and the x refers to atom molar ratio. The non-aluminum oxide is at least one of zirconium dioxide, titanium dioxide and stannic dioxide. The active metal is at least one of cobalt, nickel, iron and manganese. The invention also provides a preparation method of the desulfurization catalyst and a hydrocarbon oil desulfurizing method. The desulfurization catalyst is better in desulfurization activity and activity stability.
Owner:CHINA PETROLEUM & CHEM CORP +1
A kind of desulfurization catalyst and its preparation method and the method for hydrocarbon oil desulfurization
ActiveCN104511283BOvercoming the problem of reduced activityMetal/metal-oxides/metal-hydroxide catalystsRefining to eliminate hetero atomsPtru catalystAlkali metal oxide
The invention discloses a desulfurization catalyst which includes following components, on the basis of the total weight of the desulfurization catalyst, by weight: 5-35% of a silicon oxide source, 5-35% of aluminum oxide, 30-70% of zinc oxide, 2-15% of lead oxide, 0.5-10% of an alkali metal oxide and 5-30% of an active metal. At least partial lead oxide and the zinc oxide are formed into a zinc-lead solid solution with a general formula being Pb<x>Zn<1-x>O, wherein 0<x<=0.12 and the x refers to atom molar ratio. The active metal is at least one of cobalt, nickel, iron and manganese. The invention also provides a preparation method of the desulfurization catalyst and a hydrocarbon oil desulfurizing method. The desulfurization catalyst is better in desulfurization activity and activity stability.
Owner:CHINA PETROLEUM & CHEM CORP +1
A kind of desulfurization catalyst and its preparation method and the method for hydrocarbon oil desulfurization
ActiveCN104511305BOvercoming the problem of reduced activityMolecular sieve catalystsRefining with metal oxidesMolecular sieveAlkali metal oxide
The present invention discloses a desulfurization catalyst, which contains, by weight, 5-30% of a silica source, 5-30% of alumina, 30-70% of zinc oxide, 2-15% of lead oxide, 0.5-10% of an alkali metal oxide, 1-20% of a phosphorus-aluminum molecular sieve, and 3-30% of an active metal, wherein at least part of the lead oxide exists in the form for forming the zinc lead solid solution represented by a general formula PbxZn1-xO with the zinc oxide, x is more than 0 and is less than or equal to 0.12, x represents an atomic molar ratio, and the active metal is at least one selected from cobalt, nickel, iron and manganese. The present invention further provides a desulfurization catalyst preparation method and a hydrocarbon oil desulfurization method. The desulfurization catalyst of the present invention has good desulfurization activity and good activity stability.
Owner:CHINA PETROLEUM & CHEM CORP +1
A kind of desulfurization catalyst and its preparation method and the method for hydrocarbon oil desulfurization
ActiveCN104511301BOvercoming the problem of reduced activityMolecular sieve catalystsHydrocarbon oils refiningMolecular sievePtru catalyst
The invention discloses a desulfurization catalyst which includes following components, on the basis of the total weight of the desulfurization catalyst, by weight: 5-30% of a silicon oxide source, 5-30% of aluminum oxide, 30-70% of zinc oxide, 2-15% of lead oxide, 0.5-10% of a phosphorus oxide based on the weight of P2O5, 1-20% of a molecular sieve having a BEA structure and / or a molecular sieve having an FAU structure, and 5-30% of an active metal. At least partial lead oxide and the zinc oxide are formed into a zinc-lead solid solution with a general formula being Pb<x>Zn<1-x>O, wherein 0<x<=0.12 and the x refers to atom molar ratio. The active metal is at least one of cobalt, nickel, iron and manganese. The invention also provides a preparation method of the desulfurization catalyst and a hydrocarbon oil desulfurizing method. The desulfurization catalyst is better in desulfurization activity and activity stability.
Owner:CHINA PETROLEUM & CHEM CORP +1
A kind of desulfurization catalyst and preparation method thereof and method for desulfurization of hydrocarbon oil
ActiveCN104511309BOvercoming the problem of reduced activityMolecular sieve catalystsHydrocarbon oils refiningMolecular sievePtru catalyst
The invention discloses a desulfurization catalyst which includes following components, on the basis of the total weight of the desulfurization catalyst, by weight: 5-30% of a silicon oxide source, 5-30% of aluminum oxide, 30-70% of zinc oxide, 2-15% of lead oxide, 1-20% of a phosphorus-aluminum molecular sieve, and 5-30% of an active metal. At least partial lead oxide and the zinc oxide are formed into a zinc-lead solid solution with a general formula being Pb<x>Zn<1-x>O, wherein 0<x<=0.12 and the x refers to atom molar ratio. The active metal is at least one of cobalt, nickel, iron and manganese. The invention also provides a preparation method of the desulfurization catalyst and a hydrocarbon oil desulfurizing method. The desulfurization catalyst is better in desulfurization activity and activity stability.
Owner:CHINA PETROLEUM & CHEM CORP +1
A kind of desulfurization catalyst and preparation method thereof and method for desulfurization of hydrocarbon oil
ActiveCN104511307BOvercoming the problem of reduced activityMolecular sieve catalystsHydrocarbon oils refiningMolecular sieveManganese
The present invention discloses a desulfurization catalyst, which contains, by weight, 5-30% of pillared clay, 5-30% of alumina, 30-70% of zinc oxide, 2-15% of lead oxide, 1-20% of a phosphorus-aluminum molecular sieve, and 5-30% of an active metal, wherein at least part of the lead oxide exists in the form for forming the zinc lead solid solution represented by a general formula PbxZn1-xO with the zinc oxide, x is more than 0 and is less than or equal to 0.12, x represents an atomic molar ratio, and the active metal is at least one selected from cobalt, nickel, iron and manganese. The present invention further provides a desulfurization catalyst preparation method and a hydrocarbon oil desulfurization method. The desulfurization catalyst of the present invention has good desulfurization activity and good activity stability.
Owner:CHINA PETROLEUM & CHEM CORP +1
A kind of desulfurization catalyst and its preparation method and the method for hydrocarbon oil desulfurization
ActiveCN104511303BOvercoming the problem of reduced activityMolecular sieve catalystsHydrocarbon oils refiningMolecular sievePtru catalyst
The invention discloses a desulfurization catalyst which includes following components, on the basis of the total weight of the desulfurization catalyst, by weight: 5-30% of pillared interlayered clay, 5-30% of aluminum oxide, 30-70% of zinc oxide, 2-15% of lead oxide, 1-20% of a molecular sieve having a BEA structure and / or a molecular sieve having an FAU structure, and 5-30% of an active metal. At least partial lead oxide and the zinc oxide are formed into a zinc-lead solid solution with a general formula being Pb<x>Zn<1-x>O, wherein 0<x<=0.12 and the x refers to atom molar ratio. The active metal is at least one of cobalt, nickel, iron and manganese. The invention also provides a preparation method of the desulfurization catalyst and a hydrocarbon oil desulfurizing method. The desulfurization catalyst is better in desulfurization activity and activity stability.
Owner:CHINA PETROLEUM & CHEM CORP +1
A kind of desulfurization catalyst and its preparation method and the method for hydrocarbon oil desulfurization
ActiveCN104511284BOvercoming the problem of reduced activityMolecular sieve catalystsMetal/metal-oxides/metal-hydroxide catalystsManganeseLead oxide
The invention discloses a desulfurization catalyst which includes following components, on the basis of the total weight of the desulfurization catalyst, by weight: 5-35% of a silicon oxide source, 5-35% of aluminum oxide, 30-70% of zinc oxide, 2-15% of lead oxide, 0.5-10% of an alkaline-earth metal oxide and 5-30% of an active metal. At least partial lead oxide and the zinc oxide are formed into a zinc-lead solid solution with a general formula being Pb<x>Zn<1-x>O, wherein 0<x<=0.12 and the x refers to atom molar ratio. The active metal is at least one of cobalt, nickel, iron and manganese. The invention also provides a preparation method of the desulfurization catalyst and a hydrocarbon oil desulfurizing method. The desulfurization catalyst is better in desulfurization activity and activity stability.
Owner:CHINA PETROLEUM & CHEM CORP +1
A kind of desulfurization catalyst and its preparation method and the method for hydrocarbon oil desulfurization
ActiveCN104511299BOvercoming the problem of reduced activityMolecular sieve catalystsHydrocarbon oils refiningMolecular sievePtru catalyst
The invention discloses a desulfurization catalyst which includes following components, on the basis of the total weight of the desulfurization catalyst, by weight: 5-30% of a silicon oxide source, 5-30% of aluminum oxide, 30-70% of zinc oxide, 2-15% of lead oxide, 1-20% of a molecular sieve having a BEA structure and / or a molecular sieve having an FAU structure, and 5-30% of an active metal. At least partial lead oxide and the zinc oxide are formed into a zinc-lead solid solution with a general formula being Pb<x>Zn<1-x>O, wherein 0<x<=0.12 and the x refers to atom molar ratio. The active metal is at least one of cobalt, nickel, iron and manganese. The invention also provides a preparation method of the desulfurization catalyst and a hydrocarbon oil desulfurizing method. The desulfurization catalyst is better in desulfurization activity and activity stability.
Owner:CHINA PETROLEUM & CHEM CORP +1
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