A kind of desulfurization catalyst and its preparation method and the method of hydrocarbon oil desulfurization

A desulfurization catalyst, alumina technology, applied in the direction of chemical instruments and methods, physical/chemical process catalysts, metal/metal oxide/metal hydroxide catalysts, etc., can solve the problem of reduced activity of adsorbents

Active Publication Date: 2017-01-11
CHINA PETROLEUM & CHEM CORP +1
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0014] The purpose of the present invention is to provide a desulfurization catalyst and its preparation method and a method for desulfurization of hydrocarbon oil in order to overcome the problem of reduced adsorbent activity in the prior art

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  • A kind of desulfurization catalyst and its preparation method and the method of hydrocarbon oil desulfurization
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  • A kind of desulfurization catalyst and its preparation method and the method of hydrocarbon oil desulfurization

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preparation example Construction

[0039] The present invention also provides a method for preparing a desulfurization catalyst, the method comprising: (1) performing a precipitation reaction on a mixed solution obtained by mixing a lead-containing compound, a zinc-containing compound and water, and filtering, drying and Roasting to obtain a precipitated product; (2) contacting a silicon oxide source, an alumina source, water and an acid solution to form a slurry, and mixing the precipitated product obtained in step (1) with the slurry to form a carrier mixture; Shaping the carrier mixture, drying and roasting to form a carrier; (3) introducing a compound containing an active metal to the carrier obtained in step (2) and drying and roasting to obtain a desulfurization catalyst precursor; the active metal is cobalt, nickel, iron and at least one of manganese; (4) reducing the desulfurization catalyst precursor obtained in step (3) under a hydrogen-containing atmosphere to obtain a desulfurization catalyst.

[00...

Embodiment 1

[0079] This example is used to illustrate the preparation method of the desulfurization catalyst of the present invention.

[0080] (1) Precipitation product is prepared. Mix 10.9 kg of zinc acetate dihydrate powder (produced by Beijing Chemical Plant, analytically pure), 0.86 kg of lead acetate trihydrate (Sinopharm Chemical Reagent Company, analytically pure) and 18 kg of deionized water, and dissolve completely after stirring for 30 minutes. The precipitated product obtained by adding 1.8 kg of ammonia water was filtered, dried at 150° C. for 2 hours, and then calcined at 500° C. for 1 hour to obtain the precipitated product C1.

[0081] The precipitated product C1 was subjected to fluorescence analysis and XRD determination. In the XRD spectrum (see figure 1) has no diffraction peak of PbO, and the standard diffraction peak of ZnO shifts to the right, where A 100 -B 100 = 0.2°, A 002 -B 002 = 0.21°, A 101 -B 101 = 0.2°, indicating that PbO and ZnO in the precipitat...

Embodiment 2

[0089] This example is used to illustrate the preparation method of the desulfurization catalyst of the present invention.

[0090] (1) Precipitation product is prepared. 14.0 kg of zinc nitrate hexahydrate (produced by Beijing Chemical Plant, analytically pure), 1.80 kg of lead nitrate powder (Sinopharm Chemical Reagent Company, analytically pure) and 18 kg of deionized water were mixed, and after stirring for 30 minutes, 2.0 kg of urea was added and heated to After treatment at 80°C for 2 hours, a white precipitate was obtained. After filtration, it was first dried at 150°C for 2 hours, and then calcined at 500°C for 1 hour to obtain the precipitated product C2.

[0091] The precipitated product C2 was subjected to fluorescence analysis and XRD determination. In the XRD spectrum (see figure 1 ) has no diffraction peak of PbO, and the standard diffraction peak of ZnO shifts to the right, where A 100 -B 100 = 0.25°, A 002 -B 002 = 0.24°, A 101 -B 101 =0.24°, indicating...

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Abstract

The present invention discloses a desulfurization catalyst, which contains, by weight, 5-35% of a silica source, 5-35% of alumina, 30-70% of zinc oxide, 2-15% of lead oxide, and 5-30% of an active metal, wherein at least part of the lead oxide exists in the form for forming the zinc lead solid solution represented by a general formula PbxZn1-xO with the zinc oxide, x is more than 0 and is less than or equal to 0.12, x represents an atomic molar ratio, and the active metal is at least one selected from cobalt, nickel, iron and manganese. The present invention further provides a desulfurization catalyst preparation method and a hydrocarbon oil desulfurization method. The desulfurization catalyst of the present invention has good desulfurization activity and good activity stability.

Description

technical field [0001] The present invention relates to a kind of desulfurization catalyst and its preparation method and the method of hydrocarbon oil desulfurization, specifically, relate to a kind of desulfurization catalyst, a kind of preparation method of desulfurization catalyst and the desulfurization catalyst obtained by this method, and desulfurization catalyst in hydrocarbon oil desulfurization method applied in . Background technique [0002] As people pay more and more attention to environmental protection, environmental regulations are becoming stricter, and reducing the sulfur content of gasoline and diesel is considered to be one of the most important measures to improve air quality, because sulfur in fuel will affect the performance of automotive catalytic converters produce adverse effects. The sulfur present in the exhaust of automobile engines will inhibit the precious metals in the converter and cause irreversible poisoning, reducing the effect of the co...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J23/835C10G45/06
Inventor 林伟田辉平郭瑶庆郭晓峰王鹏王磊
Owner CHINA PETROLEUM & CHEM CORP
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