Zr-based amorphous alloy and manufacturing method thereof

A zirconium-based amorphous alloy and benchmark technology, applied in the field of zirconium-based amorphous alloy and its preparation, can solve the problems of high purity requirements of raw materials, achieve the effect of reducing material costs, reducing requirements, and improving the ability of amorphous formation

Inactive Publication Date: 2015-07-01
BYD CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The purpose of the present invention is to overcome the problem of high purity requirements for raw materials in the production of amorphous alloys in the prior art, and to provide a zirconium-based amorphous alloy and its preparation method

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  • Zr-based amorphous alloy and manufacturing method thereof

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Embodiment 1

[0035] This embodiment illustrates that the zirconium-based amorphous alloy Zr provided by the present invention 51.9 Cu 30 Al 10 Ni 7 (Er 0.91 Y 0.09 ) 1.1 method of preparation.

[0036] Put the raw materials of each component into the vacuum smelting furnace, and evacuate to 50Pa, then pass in argon gas with a purity of 99.99% by volume as a protective gas, and carry out alloy smelting. The melting temperature is 1100 ° C, and the melting time is 15 minutes. The alloy raw material is fully melted. Then remelt 3 times to make it fully alloyed. The smelting temperature in the smelting process is obtained by infrared temperature measurement.

[0037] Metal zirconium adopts elemental metal with a metal purity greater than 99% by weight, and Al, Cu, Ni, Er, Y adopts elemental metal with a purity greater than 99% by weight.

[0038] The molten alloy sample is cast into a metal mold by high pressure casting (the pressure is 20MPa, the mold material is SKD61), and cooled a...

Embodiment 2

[0044] This embodiment illustrates that the zirconium-based amorphous alloy Zr provided by the present invention 51 Cu 30 Al 10 Ni 7 f 1 (Er 0.8 Y 0.2 ) 1 method of preparation.

[0045] Put the raw materials of each component into the vacuum smelting furnace, and evacuate to 50Pa, then pass in argon gas with a purity of 99.99% by volume as a protective gas, and carry out alloy smelting. The melting temperature is 1100 ° C, and the melting time is 15 minutes. The alloy raw material is fully melted. Then remelt 3 times to make it fully alloyed. The smelting temperature in the smelting process is obtained by infrared temperature measurement.

[0046] Metal zirconium adopts industrial-grade HZr-1 zirconium material with a metal (Zr+Hf) purity greater than 99% by weight, Al, Cu, Ni, Hf, Er, and Y use elemental metals with a purity greater than 99% by weight, and Er and Y use AlErY intermediate alloy.

[0047] The molten alloy sample is cast into a metal mold by high pre...

Embodiment 3

[0053] This embodiment illustrates that the zirconium-based amorphous alloy Zr provided by the present invention 50 Cu 30 Al 10 Ni 6.5 f 1 Ti 0.5 (Er 0.75 Y 0.25 ) 2 method of preparation.

[0054] Put the raw materials of each component into the vacuum smelting furnace, and evacuate to 50Pa, then pass in argon gas with a purity of 99.99% by volume as a protective gas, and carry out alloy smelting. The melting temperature is 1100 ° C, and the melting time is 15 minutes. The alloy raw material is fully melted. Then remelt 3 times to make it fully alloyed. The smelting temperature in the smelting process is obtained by infrared temperature measurement.

[0055] Metal zirconium adopts industrial-grade HZr-1 zirconium material with a metal (Zr+Hf) purity greater than 99% by weight, Al, Cu, Ni, Hf, Er, and Y use elemental metals with a purity greater than 99% by weight, and Er and Y use AlErY intermediate Alloy, Ti adopts AlTi master alloy.

[0056] The molten alloy sam...

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Abstract

A zirconium-based amorphous alloy and a preparation method therefor. The composition of the amorphous alloy is ZraCubAlcMd(Er1-xYx)e, wherein M is at least one selected from Ni, Fe, Co, Mn, Cr, Ti, Hf and Ta, 40≤a≤70, 15≤b≤35, 5≤c≤15, 3≤d≤15, 0.2<e≤2.5, and 0<x<0.5, and the amorphous alloy is obtained by smelting and cooling molding under the protection of an inert gas or a vacuum condition.

Description

technical field [0001] The invention relates to a zirconium-based amorphous alloy and a preparation method thereof. Background technique [0002] Amorphous alloys appeared in the 1960s. The initial amorphous alloys are difficult to be practically applied because the critical size (the largest size for forming amorphous crystals) can only reach the micron level. However, the material properties of amorphous alloys such as high strength, high hardness, corrosion resistance, and excellent high-temperature fluidity have attracted numerous researchers to carry out continuous research, and have successively developed amorphous alloys with large critical sizes and suitable for industrial production. Crystalline alloys, whose critical size gradually develops from the micron level to the millimeter level and even to the centimeter level. Generally speaking, amorphous alloys whose critical cooling rate is less than 500°C / s and whose critical size is greater than 1 mm are called bulk...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C45/10
CPCC22C45/10C22C1/11
Inventor 张法亮
Owner BYD CO LTD
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