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Method for producing laminate, and laminate

A manufacturing method and laminated body technology, applied in the direction of chemical instruments and methods, lamination, layered products, etc., can solve problems such as poor production efficiency, achieve the effects of preventing aggregation, low change in resistance value, and preventing white turbidity

Active Publication Date: 2015-09-09
FUJIMORI KOGYO CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the case of the adhesive composition described in Patent Document 5, there is no description of an adhesive composition that does not cause a cloudy adhesive layer under environmental conditions of 85° C. and 95% RH, and an adhesive using the composition. knot tape
In addition, since the alkyl (meth)acrylate monomer is excessively introduced, as shown in the example of Patent Document 5, after pouring the resin into the template, it is necessary to weaken the ultraviolet rays through glass and irradiate for a long time, etc., and the equipment must be repaired. improve
In addition, although it is described as an adhesive composition that does not cause cloudiness of the adhesive layer even under environmental conditions of 60°C and 90%RH, and an adhesive tape using the composition, it is necessary to irradiate weak ultraviolet rays for a long time. , so the production efficiency is poor
[0022] Thus, in the prior art, there is no known method for producing a laminated body and a laminated body in which a laminated film using a photocurable resin composition is bonded to an adherend having a step on the surface. Formed on the body, the laminated film can follow the steps between the front glass plate of the display as the adherend and the black frame of the light-shielding layer, and can prevent the generation of air bubbles during lamination. Moreover, even in very The adhesive layer (photocurable resin layer) does not become cloudy even under severe high-temperature and high-humidity environmental conditions, such as 85°C and 95%RH environmental conditions suitable for automotive displays

Method used

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  • Method for producing laminate, and laminate
  • Method for producing laminate, and laminate
  • Method for producing laminate, and laminate

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0139] (A) of the photocurable resin composition used "SK-Dyne 2094" (acid value 33, manufactured by Soken Chemical Co., Ltd.) as a main polymer polymer composed of an acrylic resin having an acid value of 0 to 33. The main ingredient polymer and (D) bifunctional crosslinking agent E-AX (curing agent, manufactured by Soken Chemical Co., Ltd.) were mixed at 100 g: 0.27 g, respectively, to obtain a main ingredient-crosslinking agent mixed solution . In the obtained main agent-crosslinking agent mixed solution, further add 10.0 g of 4-hydroxybutyl acrylate (4HBA, Osaka Organic Material Industry Co., Ltd. (manufactured) and 1.0 g of (C) alkylphenone (alkylphenone) photopolymerization initiator (product name is "Irgacure184", manufactured by Ciba Japan K.K.), formulated into a photocurable resin composition.

[0140] The photocurable resin composition was coated on a diaphragm (the product name is "125E-0010DG2.5AS" with a thickness of 125 μm; manufactured by Fujimori Industry Co...

Embodiment 2

[0143] (A) of the photocurable resin composition used "SK-Dyne 2147" (acid value 0, manufactured by Soken Chemical Co., Ltd.) as a main polymer polymer composed of an acrylic resin having an acid value of 0 to 33. This main ingredient polymer and (D) TD-75 (manufactured by Soken Chemical Co., Ltd.) as a bifunctional crosslinking agent were mixed at 100 g: 0.06 g, respectively, to obtain a main ingredient-crosslinking agent mixed solution. In the obtained main agent-crosslinking agent mixed solution, further add 5.0 g of 4-hydroxybutyl acrylate (4HBA, Osaka Organic Material Industry Co., Ltd. Manufacturing) and 0.50g of (D) alkyl phenone photopolymerization initiator (product name is " Irgacure184 ", Ciba Japan Co., Ltd. (Ciba Japan K.K.) manufacture), is formulated into photocurable resin composition, besides Otherwise, it carried out similarly to Example 1, and obtained the laminated film of Example 2.

Embodiment 3

[0145] (A) of the photocurable resin composition used "SK-Dyne 2147" (acid value 0, manufactured by Soken Chemical Co., Ltd.) as a main polymer polymer composed of an acrylic resin having an acid value of 0 to 33. This main ingredient polymer and (D) TD-75 (manufactured by Soken Chemical Co., Ltd.) as a bifunctional crosslinking agent were mixed at 100 g: 0.06 g, respectively, to obtain a main ingredient-crosslinking agent mixed solution. In the obtained main agent-crosslinking agent mixed solution, further add 10.0 g of 4-hydroxybutyl acrylate (4HBA, Osaka Organic Material Industry Co., Ltd. Manufacturing) and 1.0g of (C) alkyl phenone photopolymerization initiator (product name is "Irgacure184", Ciba Japan Co., Ltd. (Ciba Japan K.K.) manufacture), formulated into a photocurable resin composition, in addition Otherwise, it carried out similarly to Example 1, and obtained the laminated film of Example 3.

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Abstract

The invention provides a laminating body manufacturing method and a laminating body. The laminating body is formed by bonding a laminating film utilizing light-cured resin on a to-be-bonded body with steps. Bubbles and white turbidity can be prevented by bonding the laminating film on the to-be-bonded body provided with steps on the surface. The manufacturing method of the laminating body includes a working procedure of preparing the light-cured resin, wherein the light-cured resin has an energy storage volume that is greater than 1*104Pa and less than 9*104Pa below 24 DEG C and 1Hz and contains, by weight 5 to 10 parts (B) at least one among acrylate monomer with hydroxyl (methyl), 1.5 to 1 part of (C) optic polymerization initiator and 0.2 to 0.8 part of (D) bifunctional cross-linking agent relative to 100 parts of (A) host polymer composed of acrylic acid resin whose acid value is 0 to 33.

Description

[0001] This application is a divisional application of an application with a filing date of August 8, 2013, an application number of 201310342667.5, and an invention title of "Manufacturing Method of a Laminated Body and a Laminated Body". technical field [0002] This invention relates to the manufacturing method of the laminated body which used the photocurable resin composition, and a laminated body. More specifically, the present invention relates to a method for producing a laminate in which a laminate film using a photocurable resin composition is bonded to an adherend, and the laminate, wherein the laminate film can follow printing steps Etc. to prevent the generation of air bubbles, and after UV irradiation in the durability test under high-temperature and high-humidity environmental conditions, no white turbidity occurs. [0003] In addition, the "printing level" in this specification means the thickness of the printed layer calculated from the surface of the substrat...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J4/02C09J4/06C09J11/06B32B37/12
CPCB32B27/308B32B37/24B32B38/0036B32B38/164B32B2038/0076B32B2457/20
Inventor 新见洋人藤田志朗铃木淳史五十岚智美
Owner FUJIMORI KOGYO CO LTD