The invention discloses an electrochemical preparation method of
tris (1, 1, 1, 3, 3, 3-hexafluoro-2-propyl) phosphite, and belongs to the technical field of
electrolysis processes for producing compounds. The method comprises the following steps: mixing
white phosphorus, hexafluoroisopropanol, an activation additive, an organic alkali, an
electrolyte and an
organic solvent to form an electrolytic reaction solution; the electrolytic reaction solution is electrolyzed under the action of
direct current,
white phosphorus is oxidized at an
anode and then subjected to nucleophilic
attack by hexafluoroisopropanol to generate tri (1, 1, 1, 3, 3, 3-hexafluoro-2-propyl) phosphite, and
hydrogen atoms are reduced at a
cathode to form
hydrogen. The method has the advantages of simplicity, convenience, rapidness, high safety, few byproducts, high utilization value and low cost; the method is high in atom
utilization rate and weak in
corrosion to devices, meets the requirements of green and safe production, and has a good industrial application prospect.