Pigment composition and color filter
A pigment composition and pigment technology, applied in the direction of pigment slurry, instruments, filters, etc., can solve the problems of low dispersibility and low stability over time, and achieve the effect of excellent brightness
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[0386]Hereinafter, although an Example is given and this invention is demonstrated concretely, this invention is not limited especially to an Example. In addition, in the Examples, "part" means "part by mass". In addition, Mn and Mw are number average molecular weight and weight average molecular weight, respectively.
[0387] (Average molecular weight of resin type dispersant (A) having aromatic carboxyl group)
[0388] The number-average molecular weight (Mn) and weight-average molecular weight (Mw) of the acrylic resin used as the resin of the pigment carrier were obtained by GPC (Tosoh Corporation) equipped with an RI detector using a TSKgel column (manufactured by Tosoh Corporation). manufactured, HLC-8120GPC), using THF as a developing solvent, the polystyrene-equivalent number average molecular weight (Mn) and weight average molecular weight (Mw) measured.
[0389] (Acid value of resin type dispersant (A) having an aromatic carboxyl group)
[0390] The acid value of ...
manufacture example 1
[0396] (Production Example 1 (A-1) of Resin-type Dispersant (A) Having Aromatic Carboxyl Group)
[0397] 62.6 parts of 1-dodecyl alcohol, 287.4 parts of ε-caprolactone, and 0.1 parts of monobutyl tin oxide (IV) as a catalyst were put into a reaction tank equipped with a gas inlet pipe, a condenser pipe, a stirring blade and a thermometer. After substituting with nitrogen, the mixture was heated and stirred at 120° C. for 4 hours. After confirming that 98% had reacted by solid content measurement, 36.6 parts of pyromellitic dianhydrides were added there, and it was made to react at 120 degreeC for 2 hours. By measuring the acid value, it was confirmed that 98% or more of the acid anhydride was half-esterified, and the reaction was completed to obtain a dispersant. Thus, a resin type dispersant (A-1) having an aromatic carboxyl group having an acid value per unit solid content of 49 mgKOH / g and a number average molecular weight (Mn) of 2,500 was obtained. Then, propylene glyco...
manufacture example 2
[0398] (Production Example 2 (A-2) of Resin-type Dispersant (A) Having Aromatic Carboxyl Group)
[0399] Put 60 parts of methoxypropyl acetate into a reaction tank equipped with a gas inlet tube, a condenser tube, a stirring blade and a thermometer, and raise the temperature to 110°C. 40 parts of methyl methacrylate, 28 parts of benzyl methacrylate, 20 parts of n-butyl acrylate, 12 parts of 2-hydroxyethyl methacrylate, 40 parts of methoxypropyl acetate and 6 parts of dimethyl-2,2'-azobis-diisobutyrate were homogeneously mixed in advance, and the mixture was stirred at the same temperature for 3 hours to complete the reaction. Thus, an intermediate having a number average molecular weight of 3,800 and an average number of hydroxyl groups in one molecule of 3.5 was obtained. 100 parts of the intermediate, 5.1 parts of trimellitic anhydride, and 0.1 part of dimethylbenzylamine were thrown in as a solid content, and it was made to react at 100 degreeC for 6 hours. Thus, a resin ...
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