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A kind of emulsified paraffin and its preparation method and application

A technology of emulsified paraffin and paraffin, which is applied in the field of emulsified paraffin and its preparation, which can solve the problems of small improvement, floating phenomenon of emulsified paraffin, delamination, etc., and achieves improved compressive strength, excellent water-reducing effect, and simple dispensing process Effect

Active Publication Date: 2021-12-24
CENT SOUTH UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At this stage, there are endless researches on the preparation of emulsified paraffin. Regarding the choice of emulsifier, most of them use a single emulsifier or a compound emulsifier prepared by two or three surfactants. Most of these emulsifiers can also produce emulsified paraffin solutions. , but among the many properties of emulsified paraffin (centrifugal stability, static stability, dispersibility, particle size and distribution, film-forming properties, etc.), there will always be one or more defects
For example, the composite emulsifier composed of Span-80 and Tween-80 has the best stability when the HLB value ranges from 9.8 to 10.0, but when the centrifugal speed is 12000r / min, stratification occurs
However, using Span-80 and AEO-9 as the compound emulsifier to prepare paraffin wax emulsion, with the increase of the mass ratio of emulsifier to paraffin wax, the concentration of the stable paraffin wax emulsion that can be prepared can be gradually increased, but the increase is not large, and all paraffin wax The overall stability of the emulsion is not very good
[0004] More importantly, when these emulsified paraffins are mixed into concrete, there will be problems of concrete incompatibility and affecting the hydration of concrete. The main manifestations are: freshly mixed concrete will have emulsified paraffin during the vibration process and before hardening The phenomenon of floating occurs; the addition of emulsified paraffin will slow down the hydration process of concrete, and the retardation phenomenon is serious

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  • A kind of emulsified paraffin and its preparation method and application
  • A kind of emulsified paraffin and its preparation method and application
  • A kind of emulsified paraffin and its preparation method and application

Examples

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preparation example Construction

[0047] The preparation method of emulsified paraffin is:

[0048] Put the paraffin wax and compound emulsifier prepared according to the designed ratio into the reaction vessel, keep stirring in a water bath at 75°C until the paraffin wax melts, and stir it with an electric mixer at a speed of 800r / min after melting, and divide it at intervals Add deionized water at a temperature of 75°C several times with an interval of 30s until the paraffin phase inversion, then add the remaining deionized water, adjust the stirring speed to 1000r / min, continue stirring for 40min, and then mix the obtained Cool the solution at 4°C to obtain the emulsified paraffin solution;

[0049] In terms of mass ratio, the total amount of water:paraffin=4:1.

Embodiment 1

[0051] The compounding agent in this example includes the following components in parts by weight: Span-80: 90 parts; Tween-80: 40 parts; Pingpingjia A-20: 10 parts; OP-10: 30 parts ; Triethanolamine: 10 parts; Stearic acid: 5 parts; Ethylene glycol, 37 parts. At this time, the HLB value of the composite emulsifier is 9.605, and the mass fraction of the composite emulsifier in the emulsified paraffin wax of this embodiment is 3%.

[0052] The emulsified paraffin wax obtained in Example 1 has good stability, no delamination after centrifugation, and a shelf life of about three months. The dispersion of the emulsion is first-grade, and after drying, a uniform, stable, and strong hydrophobic wax film can be formed. The particle size is Micron level, when mixed into concrete, it has good compatibility with concrete, has a weak effect on cement hydration, and can play a certain role in reducing water, with a water reducing rate of about 6.2%.

[0053] The emulsified paraffin is mi...

Embodiment 2

[0055] The compounding agent in this example includes the following components in parts by weight: Span-80: 92 parts; Tween-80: 42 parts; Pingpingjia A-20: 12 parts; OP-10: 32 parts parts; triethanolamine: 12 parts; stearic acid: 6 parts; ethylene glycol, 40 parts. At this time, the HLB value of the composite emulsifier is 9.769, and the mass fraction of the composite emulsifier in the emulsified paraffin wax of this embodiment is 3%.

[0056] The emulsified paraffin wax obtained in Example 2 has good stability, no delamination after centrifugation, and a shelf life of about three months. The dispersion of the emulsion is first-grade, and after drying, a uniform, stable, and strong hydrophobic wax film can be formed. The particle size is Micron level, when mixed into concrete, it has good compatibility with concrete, has a weak effect on cement hydration, and can play a certain role in reducing water, with a water reducing rate of about 7.7%.

[0057] The emulsified paraffin ...

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Abstract

The invention discloses an emulsified paraffin wax and its preparation method and application. It consists of paraffin wax, water for emulsification and a composite emulsifier; in the emulsified paraffin wax, the mass fraction of the composite emulsifier is 3-5%; the composite emulsifier, In terms of parts by weight, it includes the following components: Span-80: 90-100 parts; Tween-80: 40-50 parts; Pinpinga: 10-20 parts; OP-10: 30-40 parts; Ethanolamine: 10-20 parts; Stearic acid: 5-10 parts; Ethylene glycol, 37-48 parts. The emulsified paraffin wax provided by the invention has the characteristics of good emulsion dispersion, high stability, long shelf life, strong water solubility, and good film-forming performance. It is mixed into concrete as an additive, has good compatibility with concrete, and has a certain At the same time, it can also enhance the hydrophobicity of concrete, improve the durability properties such as impermeability and electric flux; in addition, it can also weaken the electrical conductivity of concrete and greatly increase its resistivity, which is used to prepare high-impedance concrete.

Description

technical field [0001] The invention discloses an emulsified paraffin, its preparation method and application, and belongs to the technical field of emulsified paraffin related chemical industry. Background technique [0002] In actual engineering, changes in the external environment will lead to a large loss of water in freshly mixed concrete. People usually use watering, watering, water storage and other methods to maintain concrete, but this measure requires a lot of water resources and causes a certain degree of waste. , and will increase construction costs. Using the film-forming properties of emulsified paraffin to keep the water in the newly poured concrete from evaporating instead of the traditional water supply and maintenance measures can not only achieve the purpose of water saving, but also simplify the maintenance process and achieve good economic benefits. In addition, with the increasing complexity of engineering, higher performance requirements are put forwa...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08J3/03C08L91/06C04B24/36
Inventor 曾晓辉凌晨博郑克仁谢友均龙广成马昆林马聪朱华胜刘海川潘璋
Owner CENT SOUTH UNIV
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