Gasoline surfactant named as Yixiangjing and preparation method thereof
A gasoline and cyclodextrin technology, applied in the petroleum industry, liquid carbon-containing fuels, fuel additives, etc., can solve problems such as increased deposits and incomplete combustion
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preparation example Construction
[0045] The preparation method of cyclodextrin modified polyether amine is as follows:
[0046] (1) Preparation of polyether
[0047] Put it into the reaction kettle, replace it with nitrogen twice, and then vacuumize while raising the temperature. When the temperature rises to 120°C, close the vacuum valve, and slowly add propylene oxide. At 130~150°C, after the reaction is complete, cool down Discharge at 80°C;: The molar ratio of propylene oxide feeding is 1.01:1.
[0048] (2) Condensation of polyether with acetyl ketone or acetoacetate
[0049] Add polyether, acetyl ketone or acetoacetate, DMAP, and toluene into a reaction kettle equipped with a water separator and a condenser, stir at 25°C for 4 hours, then slowly heat to reflux at 120~130°C, and the reaction product Water is azeotroped with toluene and discharged through the water separator. When anhydrous is formed, the temperature is lowered to 70°C; the molar ratio of polyether: acetyl ketone or acetoacetate: DMAP is...
Embodiment approach
[0055] As a preferred embodiment of the present invention, the weight-average molecular weight of the cyclodextrin-modified polyetheramine is 1800-4000; preferably, the weight-average molecular weight of the cyclodextrin-modified polyetheramine is 2000-3000.
[0056] As a preferred embodiment of the present invention, the cyclodextrin is selected from one or more of hydroxycyclodextrin and aminocyclodextrin.
[0057] As a preferred embodiment of the present invention, the cyclodextrin is aminocyclodextrin.
[0058] As a preferred embodiment of the present invention, the antioxidant is selected from one or a mixture of T501, T502, and T531.
[0059] As a preferred embodiment of the present invention, the antirust agent is selected from one or a mixture of T703, T706, SP-80, and SP-85.
[0060] As a preferred embodiment of the present invention, the preservative is selected from T551 or T561.
[0061] As a preferred embodiment of the present invention, the co-solvent is select...
Embodiment 1~8 and comparative example 1
[0080] A tank of gasoline is prepared according to the formula in Table 1, and the preparation method is as follows (the consumption of the following components are all percentages by weight):
[0081] Weigh according to the required component ratio, mix cyclodextrin-modified polyetheramine, antioxidant, rust inhibitor, preservative, co-solvent evenly at room temperature or not higher than 30°C, and stir until the solution is transparent.
[0082] Table 1 is the raw material formula and consumption (percentage by weight) of preparing a case of gasoline
[0083]
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