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Modified fly ash-based high-efficiency waste water treatment agent for landfill permeate and preparation method thereof

A wastewater treatment agent and garbage permeate technology, applied in the direction of adsorption water/sewage treatment, chemical instruments and methods, and other chemical processes, can solve the problems of non-reusable, difficult solid-liquid separation, small adsorption capacity, etc.

Active Publication Date: 2018-02-06
TIANJIN ZHONGKE CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Fly ash is a pozzolanic-like moderating material formed after coal powder is burned at high temperature. It is rich in alumina, and there are a large number of active points such as aluminum and silicon in it, which can be combined with adsorbate through chemical bonds. At the same time, the structure of fly ash is very strong. Control, the specific surface area is large, so it has a certain adsorption performance, and sometimes can even replace activated carbon, silica gel, etc. Small size, low treatment efficiency, difficult solid-liquid separation in the later stage, easy to form industrial sludge, troublesome post-processing, non-reusable, poor selectivity, etc.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] A modified fly ash-based landfill permeate wastewater treatment agent, the composition includes raw materials by the following weight (kg): fly ash fine powder 50, sodium bicarbonate 8, polydimethyldiallyl chloride Ammonium chloride 11, cationic polyacrylamide 9, hydroxymethyl chitosan 10, chitosan quaternary ammonium salt 10, montmorillonite powder 20, biological sludge 6, magnetized tourmaline powder 12, basic alumina 8, loofah 40, Right amount of ethanol, right amount of deionized water, right amount of water.

[0018] A kind of preparation method of the landfill permeate waste water treatment agent based on modified fly ash, comprises the following steps:

[0019] (1) Mix fly ash fine powder with sodium bicarbonate, stir at 100°C for 5 hours until uniform, and obtain modified fly ash for later use;

[0020] (2) Mix basic alumina, montmorillonite powder, magnetized tourmaline powder and 1.5 times the total weight of ethanol, heat and stir at 200°C for 2.5 hours, the...

Embodiment 2

[0025] A modified fly ash-based landfill permeate wastewater treatment agent, the composition includes raw materials by the following weight (kg): fly ash fine powder 55, sodium bicarbonate 9, polydimethyldiallyl chloride Ammonium chloride 14, cationic polyacrylamide 9.5, hydroxymethyl chitosan 15, chitosan quaternary ammonium salt 15, montmorillonite powder 22, biological sludge 8, magnetized tourmaline powder 13, basic alumina 9, loofah 45, Right amount of ethanol, right amount of deionized water, right amount of water.

[0026] A kind of preparation method of the landfill permeate waste water treatment agent based on modified fly ash, comprises the following steps:

[0027] (1) Mix fly ash fine powder with sodium bicarbonate, stir at 100°C for 5 hours until uniform, and obtain modified fly ash for later use;

[0028] (2) Mix basic alumina, montmorillonite powder, magnetized tourmaline powder and 1.5 times the total weight of ethanol, heat and stir at 200°C for 2.5 hours, t...

Embodiment 3

[0033] A modified fly ash-based landfill permeate wastewater treatment agent, the composition includes raw materials by the following weight (kg): fly ash fine powder 60, sodium bicarbonate 10, polydimethyldiallyl chloride Ammonium chloride 17, cationic polyacrylamide 10, hydroxymethyl chitosan 20, chitosan quaternary ammonium salt 20, montmorillonite powder 24, biological sludge 10, magnetized tourmaline powder 15, basic alumina 10, loofah 50, Right amount of ethanol, right amount of deionized water, right amount of water.

[0034] A kind of preparation method of the landfill permeate waste water treatment agent based on modified fly ash, comprises the following steps:

[0035] (1) Mix fly ash fine powder with sodium bicarbonate, stir at 100°C for 5 hours until uniform, and obtain modified fly ash for later use;

[0036] (2) Mix basic alumina, montmorillonite powder, magnetized tourmaline powder and 1.5 times the total weight of ethanol, heat and stir at 200°C for 2.5 hours,...

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Abstract

The invention discloses a garbage permeate wastewater treatment agent based on modified fly ash and a preparation method. The composition comprises the following raw materials in parts by weight: fly ash fine powder 50-60, sodium bicarbonate 8-10, Polydimethyldiallyl ammonium chloride 11‑17, cationic polyacrylamide 9‑10, hydroxymethyl chitosan 10‑20, chitosan quaternary ammonium salt 10‑20, montmorillonite powder 20‑24, biological Sludge 6-10, magnetized tourmaline powder 12-15, basic alumina 8-10, loofah 40-50, appropriate amount of ethanol, appropriate amount of deionized water, appropriate amount of water. The present invention uses sodium bicarbonate to pretreat the coal ash powder, which improves the pore size and surface area ratio of the coal ash powder, and then further composites and modifies the activated composite powder to improve the adsorption efficiency. The present invention also realizes the coal ash powder The advantages of high-capacity, easy-to-separate, and easy-to-recover adsorbents.

Description

technical field [0001] The invention belongs to the field of wastewater treatment, and in particular relates to a modified fly ash-based high-efficiency wastewater treatment agent for garbage permeate and a preparation method. Background technique [0002] With the rapid development of cities in our country, the output of garbage continues to increase. During the process of landfilling and stacking, due to the decomposition of organic matter inside the garbage or the combination of free water in the garbage, the garbage seepage is formed. The garbage seepage is a kind of high-concentration organic Wastewater, water quality and quantity are unstable, and the water contains a large amount of refractory substances, so the treatment of garbage permeate filtrate is very difficult. [0003] Fly ash is a pozzolanic-like moderating material formed after coal powder is burned at high temperature. It is rich in alumina, and there are a large number of active points such as aluminum an...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J20/26B01J20/30C02F1/28
Inventor 姜捷
Owner TIANJIN ZHONGKE CHEM
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