A kind of uv-cured electrospun colored micro-nano fiber stranded wire and preparation method thereof

A technology of micro-nano fiber and color, applied in the preparation of spinning solution, nanotechnology for materials and surface science, nanotechnology, etc., can solve the problem of single white color, achieve good flexibility, and the phenomenon of oxygen inhibition is not obvious , Rich and full color effect

Active Publication Date: 2017-11-24
QINGDAO UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The object of the present invention overcomes the deficiency that the background color of the fiber is single white in the prior art, and provides a colored micro-nano fiber stranded wire of UV curing electrospinning and a preparation method thereof. The stranded wire has rich and full colors, and fast color Good strength, not easy to fade, good mechanical tensile properties, and no need to add organic solvents in the electrospinning preparation process, the preparation process is safer and more environmentally friendly, suitable for large-scale production

Method used

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  • A kind of uv-cured electrospun colored micro-nano fiber stranded wire and preparation method thereof
  • A kind of uv-cured electrospun colored micro-nano fiber stranded wire and preparation method thereof
  • A kind of uv-cured electrospun colored micro-nano fiber stranded wire and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] A kind of preparation method of the colored micro-nano fiber stranded wire of UV curing electrospinning, comprises the following steps:

[0037] 1) Configure the spinning precursor solution: add 8 grams of polyurethane acrylate (DR-U301, Changxing Chemical Industry Co., Ltd. (Taiwan)) and 0.4 grams of liquid photoinitiator (photoinitiator 1173, 2-hydroxy- 2-Methyl-1-phenyl-1-acetone, Aldrich) was carried out shading stirring with a magnetic stirrer, heated in a 40-degree water bath, and stirred for 2 hours to fully mix the photoinitiator and urethane acrylate, and stand at room temperature In 2 days, a certain degree of prepolymerization occurred to obtain the spinning precursor solution;

[0038] (2) Preparation of stranded wire: Pour the prepared spinning precursor solution into an aluminum spinneret with an inner diameter of 1.2 cm, the tip of the spinneret is 2 mm in size, and nitrogen is introduced into the airtight box at a nitrogen flow rate of 3 Cubic millimete...

Embodiment 2

[0043] Embodiment 2 white control group

[0044] A kind of preparation method of the colored micro-nano fiber stranded wire of UV curing electrospinning, comprises the following steps:

[0045] 1) Configure the spinning precursor solution: add 8 grams of polyurethane acrylate (DR-U301, Changxing Chemical Industry Co., Ltd. (Taiwan)) and 0.4 grams of liquid photoinitiator (photoinitiator 1173, 2-hydroxy- 2-Methyl-1-phenyl-1-acetone, Aldrich) carry out light-shielding stirring with a magnetic stirrer, adopt 40 degree of water bath heating, stir for 2 hours, make photoinitiator and polyurethane acrylate fully mix, in above-mentioned Erlenmeyer flask Then add 1.0 gram of red phototherapy glue (Maychao, A011) and stir for 4 hours with a magnetic stirrer in shading, so that the photoinitiator and urethane acrylate are fully mixed, and left to stand at room temperature for 2 days, a certain degree of prepolymerization occurs, and the obtained Spinning precursor;

[0046] (2) Prepar...

Embodiment 3

[0050] A kind of preparation method of the colored micro-nano fiber stranded wire of UV curing electrospinning, it is characterized in that, comprises the following steps:

[0051] (1) Configure the spinning precursor solution: add 8 grams of polyurethane acrylate (DR-U301, Changxing Chemical Industry Co., Ltd. (Taiwan)) and 0.8 grams of solid-state photoinitiator (184,1-hydroxy- Cyclohexyl-phenyl ketone, Aldrich) carried out shading stirring with a magnetic stirrer, heated in a 44-degree water bath, stirred for 3 hours, and then added 1.0 gram of red phototherapy glue (Maychao, A011) in the above-mentioned Erlenmeyer flask with a magnetic stirrer Shade and stir for 4 hours to fully mix the photoinitiator and urethane acrylate, and let it stand at room temperature for 1 day to mix the phototherapy glue and DR-U301 evenly and prepolymerize to a certain extent to obtain the spinning precursor;

[0052] (2) Preparation of stranded wire: Pour the prepared spinning precursor soluti...

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Abstract

The invention discloses a UV-curable electrospun colored micro-nanofiber stranded wire and its preparation method. Micro-nanofiber for being twisted into the stranded wire is colored. The micro-nanofiber contains a photo-curing polymer material and color phototherapy gel. The micro-nanofiber is prepared from a solvent-free electrospinning precursor solution. The electrospinning process is carried out in a mionectic UV-irradiation environment. The electrospinning precursor solution contains a liquid prepolymer of a photo-curing material, a photoinitiator and phototherapy gel, and contains no organic solvent. The stranded wire has rich and full colors, has good color fastness, is not easy to fade and has good tensile mechanical property. Meanwhile, there is no need to add an organic solvent during the electrospinning preparation process. The preparation process is safer and more environmentally-friendly. The preparation method is suitable for large-scale production.

Description

technical field [0001] The invention relates to a UV-cured electrospun colored micro-nano fiber stranded wire and a preparation method thereof, belonging to the field of nano-material preparation. Background technique [0002] All kinds of fibers, whether natural, man-made and synthetic, have their own advantages and disadvantages. Natural fibers are comfortable to wear, and it is relatively easy to print and dye various patterns and colors. However, except for cotton, like wool and silk, the output is not high and the price is relatively expensive; The strength in the state is low, so it is not durable without washing; synthetic fibers such as polyester are generally strong and wear-resistant, but they are not easy to dye and the price is relatively high. The fibers and fiber fabrics desired by people can be breathable, comfortable, washable and wearable, and satisfy the fancy colors. It is difficult for the existing technology to overcome the defect that the background c...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D01F6/70D01F8/16D01F8/10D01D5/00D01D1/02B82Y30/00B82Y40/00
CPCB82Y30/00B82Y40/00D01D1/02D01D5/0007D01F6/70D01F8/10D01F8/16
Inventor 龙云泽王乐闫旭贾宪生李金涛何宏伟于桂凤
Owner QINGDAO UNIV
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