Diesel vehicle oxidized form catalyst having low temperature activity and preparation method thereof

A diesel vehicle, oxidation type technology, applied in the field of diesel vehicle oxidation catalyst and its preparation, can solve the problems of catalyst deactivation, reduction of catalyst conversion ability, etc., and achieve the effect of simple preparation method, good oxidation ability, and easy steps

Active Publication Date: 2016-07-27
WUXI WEIFU ENVIRONMENT PROTECTION CATALYST
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the high sulfur content in domestic oil products, the tail gas contains more sulfur dioxide (SO 2 ), and sulfur dioxide will be oxidized to sulfur trioxide (SO 3 ), further forming sulfate, causing catalyst deactivation and poisoning, reducing the catalyst’s ability to convert CO, HC and SOF in diesel vehicle exhaust, so DOC should have certain sulfur resistance properties

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] Example 1: An oxidation catalyst for diesel vehicles with low-temperature activity, the catalyst carrier is cordierite honeycomb ceramics, the volume is 1.101 liters, and the pore density is 400 mesh / square foot; the coating contains tungsten-silicon-aluminum composite oxide and Molecular sieve, the coating coating amount is 120 g / L; the noble metal is platinum, and the coating amount of the noble metal platinum is 3.1 g / L.

[0019] The preparation method comprises the following steps:

[0020] (1) Preparation of tungsten-silicon-aluminum composite oxide by equal-volume impregnation method: W-silicon-aluminum composite oxide is prepared by equal-volume impregnation method. The mass fraction of silicon dioxide in the silicon-aluminum composite oxide raw material used is 15%, and the rest is aluminum oxide. Weigh 990 grams of silicon-aluminum composite oxide, weigh 13.9 grams of ammonium tungstate to dissolve, prepare an aqueous solution with saturated adsorption capacit...

Embodiment 2

[0026] The specific preparation method is basically the same as that of Example 1, except that, in the tungsten-silicon-aluminum composite oxide used, the mass ratio of tungsten element to silicon-aluminum composite oxide is 1:39.

Embodiment 3

[0028] The specific preparation method is basically the same as that of Example 1, except that in the tungsten-silicon-aluminum composite oxide used, the mass ratio of tungsten element to silicon-aluminum composite oxide is 1:19.

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PUM

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Abstract

The invention relates to a diesel vehicle oxidized form catalyst having low temperature activity and a preparation method thereof.The catalyst comprises a carrier and a coating applied to the carrier, the coating is loaded with noble metal, the coating comprises tungsten-aluminum silicon composite oxide and molecular sieves, the noble metal is one of Pt and Pd or a mixture of the two types of substances, the coated weight of the coating is 80-180 grams/liter, and the coated weight of the noble metal is 0.5-4.5 grams/liter.The preparation method comprises the steps of firstly, preparing the tungsten-aluminum silicon composite oxide through an equivalent-volume impregnation method, then making slurry with the molecular sieves and the tungsten-aluminum silicon composite oxide according to the mass ratio of 1: (2-10), adding the noble metal Pt and Pd, finally immersing the carrier into the slurry, and conducting drying and sintering, so that the diesel vehicle oxidized form catalyst is obtained.The preparation method of the catalyst is simple, the steps are easy to operate, the prepared diesel vehicle oxidized form catalyst is low in combustion temperature, high in conversion rate and good in thermal stability, good capability for oxidizing HC and CO in tail gas of a diesel vehicle is achieved, and good sulfur resistance is achieved.

Description

technical field [0001] The invention relates to a diesel vehicle oxidation catalyst with low-temperature activity and a preparation method thereof, belonging to the technical field of catalyst preparation. Background technique [0002] With the rapid development of the economy and the continuous improvement of people's living standards, the transportation industry has achieved unprecedented development, and the output and number of motor vehicles have increased year by year. When fuel cell vehicles and hybrid vehicles are not yet popularized, diesel vehicles have higher fuel economy and relatively lower exhaust pollution compared with gasoline vehicles. The market demand in the 21st century is growing rapidly. With the continuous increase of the number of diesel vehicles, the atmospheric environmental pollution caused by diesel vehicle exhaust emissions has also attracted more and more widespread attention. The pollutants emitted by diesel vehicles are mainly carbon monoxid...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J29/78B01D53/94B01D53/62B01D53/72
CPCB01D53/62B01D53/72B01D53/944B01D2258/012B01J29/7815B01J2229/20Y02A50/20
Inventor 张元杨金季燕军王秀庭柯峰王刚孙亮张杰陈同同盛丽萍毛冰斌辛海峰何剑波张艮交胡芳芳贾莉伟
Owner WUXI WEIFU ENVIRONMENT PROTECTION CATALYST
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