Preparation method of purified vanadium adsorption material

A technology of adsorption materials and porogens, which is applied in the field of preparation of purified vanadium adsorption materials, can solve the problems of long process route, complex components, and easy introduction of new impurities, etc., to achieve improved adsorption capacity, high adsorption capacity, and not easy to lose Effect

Inactive Publication Date: 2016-08-10
王金明
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The methods for purifying vanadium reported in the current literature have complex components, long process routes, and easy introduction of new impurities.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] Step 1. Preparation of water phase

[0021] In parts by weight, add 100 parts of pure water and 0.5 part of polyvinyl alcohol into the reactor, and stir evenly.

[0022] Step 2. Preparation of oil phase

[0023] Mix and stir the oil phase components in the following proportions evenly;

[0024] Component Parts by weight

[0025] Vinylidene chloride 100

[0026] Bis(cyclopentadiene)vanadium iodide 65

[0027] Octadecenedioic acid 33

[0028] 1-allyl-3-butylimidazolium tetrafluoroborate 0.3

[0029] Toluene 30

[0030] Benzoyl Peroxide 2

[0031] Step 3. Polymerization

[0032] Add the prepared oil phase solution in step 2 to the reaction kettle equipped with the prepared water phase in step 1, react at 90°C for 14 hours, discharge the material after the reaction is completed, and extract the toluene after drying to obtain the product. The number is W-1.

Embodiment 2

[0034] Step 1. Preparation of water phase

[0035] In parts by weight, add 100 parts of pure water and 1.5 parts of polyvinyl alcohol into the reactor, and stir evenly.

[0036] Step 2. Preparation of oil phase

[0037] Mix and stir the oil phase components in the following proportions evenly;

[0038] Component Parts by weight

[0039] Vinylidene chloride 100

[0040] Bis(cyclopentadiene)vanadium iodide 50

[0041] Octadecenedioic acid 20

[0042] 1-allyl-3-butylimidazolium tetrafluoroborate 0.1

[0043] white oil 40

[0044] Benzoyl Peroxide 0.5

[0045] Step 3. Polymerization

[0046] Add the prepared oil phase solution to the reaction kettle equipped with the prepared water phase in step 1, react at 80°C for 24 hours, discharge the material after the reaction is completed, and extract the porogen after drying to obtain the product, No. for W-2.

Embodiment 3

[0048] Step 1. Preparation of water phase

[0049] In parts by weight, add 100 parts of pure water and 2 parts of polyvinyl alcohol into the reactor, and stir evenly.

[0050] Step 2. Preparation of oil phase

[0051] Mix and stir the oil phase components in the following proportions evenly;

[0052] Component Parts by weight

[0053] Vinylidene chloride 100

[0054] Bis(cyclopentadiene)vanadium iodide 90

[0055] Octadecenedioic acid 50

[0056] 1-allyl-3-butylimidazolium tetrafluoroborate 0.5

[0057] Mineral spirits 20

[0058] Benzoyl Peroxide 3

[0059] Step 3. Polymerization

[0060] Add the prepared oil phase solution to the reaction kettle equipped with the prepared water phase in step 1, react at 110°C for 10 hours, discharge the material after the reaction is completed, and extract the porogen after drying to obtain the product, No. for W-3.

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PUM

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Abstract

The invention relates to a preparation method of a purified vanadium adsorption material. Bis(cyclopentadiene) vanadium iodide and octadecendioic acid are introduced in the polymerization process; 1-allyl-3-buthylimidazole tetrafluoroborate is used for polymerization and preparation.

Description

technical field [0001] The invention relates to the preparation of an adsorbent, in particular to the preparation of a purified vanadium adsorption material. Background technique [0002] In the process of leaching and extracting vanadium from vanadium-containing clinker, some impurities are also leached into the solution together with vanadium. The vanadium-containing leach solution usually contains impurity ions such as iron, manganese, chromium, silicon, phosphorus, aluminum, calcium, etc., which affect the precipitation. The quality of vanadium and products, these impurity ions are under the adjustment of the pH value of the leaching solution, most of the impurity ions undergo hydrolysis reaction and precipitate into the sedimentation residue, but phosphorus, silicon, calcium and aluminum still form soluble compounds after hydrolysis and remain in the leaching solution , Seriously affect Shen vanadium and product quality, must be removed. Therefore, special purification...

Claims

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Application Information

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IPC IPC(8): B01J20/30B01J20/26C08F259/06C08F232/08C08F222/02C08F226/06
CPCB01J20/264B01J2220/4812C08F222/02C08F226/06C08F232/08C08F259/06
Inventor 王琪宇
Owner 王金明
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